这里不想赘述很多答案，但我发现了一个十六进制字符串解析器的相当优化（比公认的好4.5倍）、简单的实现。首先，我的测试输出（第一批是我的实现）：

Give me that string:
04c63f7842740c77e545bb0b2ade90b384f119f6ab57b680b7aa575a2f40939f

Time to parse 100,000 times: 50.4192 ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

Accepted answer: (StringToByteArray)
Time to parse 100000 times: 233.1264ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With Mono's implementation:
Time to parse 100000 times: 777.2544ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With SoapHexBinary:
Time to parse 100000 times: 845.1456ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

base64和“BitConverter'd”行用于测试正确性。请注意，它们是相等的。

实施：

public static byte[] ToByteArrayFromHex(string hexString)
{
  if (hexString.Length % 2 != 0) throw new ArgumentException("String must have an even length");
  var array = new byte[hexString.Length / 2];
  for (int i = 0; i < hexString.Length; i += 2)
  {
    array[i/2] = ByteFromTwoChars(hexString[i], hexString[i + 1]);
  }
  return array;
}

private static byte ByteFromTwoChars(char p, char p_2)
{
  byte ret;
  if (p <= '9' && p >= '0')
  {
    ret = (byte) ((p - '0') << 4);
  }
  else if (p <= 'f' && p >= 'a')
  {
    ret = (byte) ((p - 'a' + 10) << 4);
  }
  else if (p <= 'F' && p >= 'A')
  {
    ret = (byte) ((p - 'A' + 10) << 4);
  } else throw new ArgumentException("Char is not a hex digit: " + p,"p");

  if (p_2 <= '9' && p_2 >= '0')
  {
    ret |= (byte) ((p_2 - '0'));
  }
  else if (p_2 <= 'f' && p_2 >= 'a')
  {
    ret |= (byte) ((p_2 - 'a' + 10));
  }
  else if (p_2 <= 'F' && p_2 >= 'A')
  {
    ret |= (byte) ((p_2 - 'A' + 10));
  } else throw new ArgumentException("Char is not a hex digit: " + p_2, "p_2");

  return ret;
}

我尝试了一些不安全的东西，并将（显然是冗余的）字符移动到另一个方法来蚕食if序列，但这是最快的。

（我承认这回答了一半的问题。我觉得字符串->字节[]转换不足，而字节[]->字符串角度似乎被很好地覆盖了。因此，这个答案。）

Dotnet 5更新

要从byte[]（字节数组）转换为十六进制字符串，请使用：

System.Convert.ToHexString

var myBytes = new byte[100];
var myString = System.Convert.ToHexString(myBytes);

要将十六进制字符串转换为字节[]，请使用：

System.Convert.FromHexString

var myString  = "E10B116E8530A340BCC7B3EAC208487B";
var myBytes = System.Convert.FromHexString(myString);

可以使用从.NET 5开始的Convert.ToHexString。还有一个用于反向操作的方法：Convert.FromHexString。

对于较旧版本的.NET，您可以使用：

public static string ByteArrayToString(byte[] ba)
{
  StringBuilder hex = new StringBuilder(ba.Length * 2);
  foreach (byte b in ba)
    hex.AppendFormat("{0:x2}", b);
  return hex.ToString();
}

or:

public static string ByteArrayToString(byte[] ba)
{
  return BitConverter.ToString(ba).Replace("-","");
}

举个例子，这里有更多的方法。

反向转换如下：

public static byte[] StringToByteArray(String hex)
{
  int NumberChars = hex.Length;
  byte[] bytes = new byte[NumberChars / 2];
  for (int i = 0; i < NumberChars; i += 2)
    bytes[i / 2] = Convert.ToByte(hex.Substring(i, 2), 16);
  return bytes;
}

使用Substring是与Convert.ToByte结合使用的最佳选项。有关详细信息，请参阅此答案。如果需要更好的性能，必须避免Convert.ToByte，然后才能删除SubString。

为什么要让它变得复杂？这在Visual Studio 2008中很简单：

C#:

string hex = BitConverter.ToString(YourByteArray).Replace("-", "");

VB:

Dim hex As String = BitConverter.ToString(YourByteArray).Replace("-", "")

这里不想赘述很多答案，但我发现了一个十六进制字符串解析器的相当优化（比公认的好4.5倍）、简单的实现。首先，我的测试输出（第一批是我的实现）：

Give me that string:
04c63f7842740c77e545bb0b2ade90b384f119f6ab57b680b7aa575a2f40939f

Time to parse 100,000 times: 50.4192 ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

Accepted answer: (StringToByteArray)
Time to parse 100000 times: 233.1264ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With Mono's implementation:
Time to parse 100000 times: 777.2544ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

With SoapHexBinary:
Time to parse 100000 times: 845.1456ms
Result as base64: BMY/eEJ0DHflRbsLKt6Qs4TxGfarV7aAt6pXWi9Ak58=
BitConverter'd: 04-C6-3F-78-42-74-0C-77-E5-45-BB-0B-2A-DE-90-B3-84-F1-19-F6-AB-5
7-B6-80-B7-AA-57-5A-2F-40-93-9F

base64和“BitConverter'd”行用于测试正确性。请注意，它们是相等的。

实施：

public static byte[] ToByteArrayFromHex(string hexString)
{
  if (hexString.Length % 2 != 0) throw new ArgumentException("String must have an even length");
  var array = new byte[hexString.Length / 2];
  for (int i = 0; i < hexString.Length; i += 2)
  {
    array[i/2] = ByteFromTwoChars(hexString[i], hexString[i + 1]);
  }
  return array;
}

private static byte ByteFromTwoChars(char p, char p_2)
{
  byte ret;
  if (p <= '9' && p >= '0')
  {
    ret = (byte) ((p - '0') << 4);
  }
  else if (p <= 'f' && p >= 'a')
  {
    ret = (byte) ((p - 'a' + 10) << 4);
  }
  else if (p <= 'F' && p >= 'A')
  {
    ret = (byte) ((p - 'A' + 10) << 4);
  } else throw new ArgumentException("Char is not a hex digit: " + p,"p");

  if (p_2 <= '9' && p_2 >= '0')
  {
    ret |= (byte) ((p_2 - '0'));
  }
  else if (p_2 <= 'f' && p_2 >= 'a')
  {
    ret |= (byte) ((p_2 - 'a' + 10));
  }
  else if (p_2 <= 'F' && p_2 >= 'A')
  {
    ret |= (byte) ((p_2 - 'A' + 10));
  } else throw new ArgumentException("Char is not a hex digit: " + p_2, "p_2");

  return ret;
}

我尝试了一些不安全的东西，并将（显然是冗余的）字符移动到另一个方法来蚕食if序列，但这是最快的。

（我承认这回答了一半的问题。我觉得字符串->字节[]转换不足，而字节[]->字符串角度似乎被很好地覆盖了。因此，这个答案。）

未针对速度进行优化，但比大多数答案（.NET 4.0）更LINQy：

<Extension()>
Public Function FromHexToByteArray(hex As String) As Byte()
    hex = If(hex, String.Empty)
    If hex.Length Mod 2 = 1 Then hex = "0" & hex
    Return Enumerable.Range(0, hex.Length \ 2).Select(Function(i) Convert.ToByte(hex.Substring(i * 2, 2), 16)).ToArray
End Function

<Extension()>
Public Function ToHexString(bytes As IEnumerable(Of Byte)) As String
    Return String.Concat(bytes.Select(Function(b) b.ToString("X2")))
End Function