熊猫>=1.3（2022年编辑）：

df.insert(0, 'mean', df.pop('mean'))

怎么样（对于熊猫<1.3，原始答案）

df.insert(0, 'mean', df['mean'])

https://pandas.pydata.org/pandas-docs/stable/user_guide/dsintro.html#column-选择添加删除

这里有一个非常简单的答案（只有一行）。

在将“n”列添加到df中之后，可以执行以下操作。

import numpy as np
import pandas as pd

df = pd.DataFrame(np.random.rand(10, 5))
df['mean'] = df.mean(1)
df
           0           1           2           3           4        mean
0   0.929616    0.316376    0.183919    0.204560    0.567725    0.440439
1   0.595545    0.964515    0.653177    0.748907    0.653570    0.723143
2   0.747715    0.961307    0.008388    0.106444    0.298704    0.424512
3   0.656411    0.809813    0.872176    0.964648    0.723685    0.805347
4   0.642475    0.717454    0.467599    0.325585    0.439645    0.518551
5   0.729689    0.994015    0.676874    0.790823    0.170914    0.672463
6   0.026849    0.800370    0.903723    0.024676    0.491747    0.449473
7   0.526255    0.596366    0.051958    0.895090    0.728266    0.559587
8   0.818350    0.500223    0.810189    0.095969    0.218950    0.488736
9   0.258719    0.468106    0.459373    0.709510    0.178053    0.414752


### here you can add below line and it should work 
# Don't forget the two (()) 'brackets' around columns names.Otherwise, it'll give you an error.

df = df[list(('mean',0, 1, 2,3,4))]
df

        mean           0           1           2           3           4
0   0.440439    0.929616    0.316376    0.183919    0.204560    0.567725
1   0.723143    0.595545    0.964515    0.653177    0.748907    0.653570
2   0.424512    0.747715    0.961307    0.008388    0.106444    0.298704
3   0.805347    0.656411    0.809813    0.872176    0.964648    0.723685
4   0.518551    0.642475    0.717454    0.467599    0.325585    0.439645
5   0.672463    0.729689    0.994015    0.676874    0.790823    0.170914
6   0.449473    0.026849    0.800370    0.903723    0.024676    0.491747
7   0.559587    0.526255    0.596366    0.051958    0.895090    0.728266
8   0.488736    0.818350    0.500223    0.810189    0.095969    0.218950
9   0.414752    0.258719    0.468106    0.459373    0.709510    0.178053

您可以使用以下名称列表对数据帧列进行重新排序：

df=df.filter（list_of_col_name）

我认为这个函数更简单。您只需在开始或结束处或同时指定列的子集：

def reorder_df_columns(df, start=None, end=None):
    """
        This function reorder columns of a DataFrame.
        It takes columns given in the list `start` and move them to the left.
        Its also takes columns in `end` and move them to the right.
    """
    if start is None:
        start = []
    if end is None:
        end = []
    assert isinstance(start, list) and isinstance(end, list)
    cols = list(df.columns)
    for c in start:
        if c not in cols:
            start.remove(c)
    for c in end:
        if c not in cols or c in start:
            end.remove(c)
    for c in start + end:
        cols.remove(c)
    cols = start + cols + end
    return df[cols]

熊猫>=1.3（2022年编辑）：

df.insert(0, 'mean', df.pop('mean'))

怎么样（对于熊猫<1.3，原始答案）

df.insert(0, 'mean', df['mean'])

https://pandas.pydata.org/pandas-docs/stable/user_guide/dsintro.html#column-选择添加删除

这里有一种移动一个现有列的方法，它将修改现有的数据帧。

my_column = df.pop('column name')
df.insert(3, my_column.name, my_column)  # Is in-place