static string ByteArrayToHexViaLookupPerByte2(byte[] bytes)
{                
        var result3 = new uint[bytes.Length];
        for (int i = 0; i < bytes.Length; i++)
                result3[i] = _Lookup32[bytes[i]];
        var handle = GCHandle.Alloc(result3, GCHandleType.Pinned);
        try
        {
                var result = Marshal.PtrToStringUni(handle.AddrOfPinnedObject(), bytes.Length * 2);
                return result;
        }
        finally
        {
                handle.Free();
        }
}

在我的测试中，这个函数总是不安全实现之后的第二个条目。

不幸的是，测试台不太可靠。。。如果你多次运行它，列表会被打乱，以至于谁知道在不安全之后哪个才是最快的！它没有考虑预热、jit编译时间和GC性能影响。我很想重写它以获得更多信息，但我真的没有时间。

还有XmlWriter.WriteBinHex（请参见MSDN页面）。如果需要将十六进制字符串放入XML流中，这非常有用。

下面是一个独立的方法来了解它的工作原理：

    public static string ToBinHex(byte[] bytes)
    {
        XmlWriterSettings xmlWriterSettings = new XmlWriterSettings();
        xmlWriterSettings.ConformanceLevel = ConformanceLevel.Fragment;
        xmlWriterSettings.CheckCharacters = false;
        xmlWriterSettings.Encoding = ASCIIEncoding.ASCII;
        MemoryStream memoryStream = new MemoryStream();
        using (XmlWriter xmlWriter = XmlWriter.Create(memoryStream, xmlWriterSettings))
        {
            xmlWriter.WriteBinHex(bytes, 0, bytes.Length);
        }
        return Encoding.ASCII.GetString(memoryStream.ToArray());
    }

    // a safe version of the lookup solution:       

    public static string ByteArrayToHexViaLookup32Safe(byte[] bytes, bool withZeroX)
    {
        if (bytes.Length == 0)
        {
            return withZeroX ? "0x" : "";
        }

        int length = bytes.Length * 2 + (withZeroX ? 2 : 0);
        StateSmall stateToPass = new StateSmall(bytes, withZeroX);
        return string.Create(length, stateToPass, (chars, state) =>
        {
            int offset0x = 0;
            if (state.WithZeroX)
            {
                chars[0] = '0';
                chars[1] = 'x';
                offset0x += 2;
            }

            Span<uint> charsAsInts = MemoryMarshal.Cast<char, uint>(chars.Slice(offset0x));
            int targetLength = state.Bytes.Length;
            for (int i = 0; i < targetLength; i += 1)
            {
                uint val = Lookup32[state.Bytes[i]];
                charsAsInts[i] = val;
            }
        });
    }

    private struct StateSmall
    {
        public StateSmall(byte[] bytes, bool withZeroX)
        {
            Bytes = bytes;
            WithZeroX = withZeroX;
        }

        public byte[] Bytes;
        public bool WithZeroX;
    }

Waleed Eissa代码的逆函数（十六进制字符串到字节数组）：

    public static byte[] HexToBytes(this string hexString)        
    {
        byte[] b = new byte[hexString.Length / 2];            
        char c;
        for (int i = 0; i < hexString.Length / 2; i++)
        {
            c = hexString[i * 2];
            b[i] = (byte)((c < 0x40 ? c - 0x30 : (c < 0x47 ? c - 0x37 : c - 0x57)) << 4);
            c = hexString[i * 2 + 1];
            b[i] += (byte)(c < 0x40 ? c - 0x30 : (c < 0x47 ? c - 0x37 : c - 0x57));
        }

        return b;
    }

Waleed Eissa功能，支持小写：

    public static string BytesToHex(this byte[] barray, bool toLowerCase = true)
    {
        byte addByte = 0x37;
        if (toLowerCase) addByte = 0x57;
        char[] c = new char[barray.Length * 2];
        byte b;
        for (int i = 0; i < barray.Length; ++i)
        {
            b = ((byte)(barray[i] >> 4));
            c[i * 2] = (char)(b > 9 ? b + addByte : b + 0x30);
            b = ((byte)(barray[i] & 0xF));
            c[i * 2 + 1] = (char)(b > 9 ? b + addByte : b + 0x30);
        }

        return new string(c);
    }

可以使用从.NET 5开始的Convert.ToHexString。还有一个用于反向操作的方法：Convert.FromHexString。

对于较旧版本的.NET，您可以使用：

public static string ByteArrayToString(byte[] ba)
{
  StringBuilder hex = new StringBuilder(ba.Length * 2);
  foreach (byte b in ba)
    hex.AppendFormat("{0:x2}", b);
  return hex.ToString();
}

or:

public static string ByteArrayToString(byte[] ba)
{
  return BitConverter.ToString(ba).Replace("-","");
}

举个例子，这里有更多的方法。

反向转换如下：

public static byte[] StringToByteArray(String hex)
{
  int NumberChars = hex.Length;
  byte[] bytes = new byte[NumberChars / 2];
  for (int i = 0; i < NumberChars; i += 2)
    bytes[i / 2] = Convert.ToByte(hex.Substring(i, 2), 16);
  return bytes;
}

使用Substring是与Convert.ToByte结合使用的最佳选项。有关详细信息，请参阅此答案。如果需要更好的性能，必须避免Convert.ToByte，然后才能删除SubString。

未针对速度进行优化，但比大多数答案（.NET 4.0）更LINQy：

<Extension()>
Public Function FromHexToByteArray(hex As String) As Byte()
    hex = If(hex, String.Empty)
    If hex.Length Mod 2 = 1 Then hex = "0" & hex
    Return Enumerable.Range(0, hex.Length \ 2).Select(Function(i) Convert.ToByte(hex.Substring(i * 2, 2), 16)).ToArray
End Function

<Extension()>
Public Function ToHexString(bytes As IEnumerable(Of Byte)) As String
    Return String.Concat(bytes.Select(Function(b) b.ToString("X2")))
End Function