安全版本：

public static class HexHelper
{
    [System.Diagnostics.Contracts.Pure]
    public static string ToHex(this byte[] value)
    {
        if (value == null)
            throw new ArgumentNullException("value");

        const string hexAlphabet = @"0123456789ABCDEF";

        var chars = new char[checked(value.Length * 2)];
        unchecked
        {
            for (int i = 0; i < value.Length; i++)
            {
                chars[i * 2] = hexAlphabet[value[i] >> 4];
                chars[i * 2 + 1] = hexAlphabet[value[i] & 0xF];
            }
        }
        return new string(chars);
    }

    [System.Diagnostics.Contracts.Pure]
    public static byte[] FromHex(this string value)
    {
        if (value == null)
            throw new ArgumentNullException("value");
        if (value.Length % 2 != 0)
            throw new ArgumentException("Hexadecimal value length must be even.", "value");

        unchecked
        {
            byte[] result = new byte[value.Length / 2];
            for (int i = 0; i < result.Length; i++)
            {
                // 0(48) - 9(57) -> 0 - 9
                // A(65) - F(70) -> 10 - 15
                int b = value[i * 2]; // High 4 bits.
                int val = ((b - '0') + ((('9' - b) >> 31) & -7)) << 4;
                b = value[i * 2 + 1]; // Low 4 bits.
                val += (b - '0') + ((('9' - b) >> 31) & -7);
                result[i] = checked((byte)val);
            }
            return result;
        }
    }
}

不安全版本适用于那些喜欢性能且不怕不安全的人。ToHex快35%，FromHex快10%。

public static class HexUnsafeHelper
{
    [System.Diagnostics.Contracts.Pure]
    public static unsafe string ToHex(this byte[] value)
    {
        if (value == null)
            throw new ArgumentNullException("value");

        const string alphabet = @"0123456789ABCDEF";

        string result = new string(' ', checked(value.Length * 2));
        fixed (char* alphabetPtr = alphabet)
        fixed (char* resultPtr = result)
        {
            char* ptr = resultPtr;
            unchecked
            {
                for (int i = 0; i < value.Length; i++)
                {
                    *ptr++ = *(alphabetPtr + (value[i] >> 4));
                    *ptr++ = *(alphabetPtr + (value[i] & 0xF));
                }
            }
        }
        return result;
    }

    [System.Diagnostics.Contracts.Pure]
    public static unsafe byte[] FromHex(this string value)
    {
        if (value == null)
            throw new ArgumentNullException("value");
        if (value.Length % 2 != 0)
            throw new ArgumentException("Hexadecimal value length must be even.", "value");

        unchecked
        {
            byte[] result = new byte[value.Length / 2];
            fixed (char* valuePtr = value)
            {
                char* valPtr = valuePtr;
                for (int i = 0; i < result.Length; i++)
                {
                    // 0(48) - 9(57) -> 0 - 9
                    // A(65) - F(70) -> 10 - 15
                    int b = *valPtr++; // High 4 bits.
                    int val = ((b - '0') + ((('9' - b) >> 31) & -7)) << 4;
                    b = *valPtr++; // Low 4 bits.
                    val += (b - '0') + ((('9' - b) >> 31) & -7);
                    result[i] = checked((byte)val);
                }
            }
            return result;
        }
    }
}

顺便提一下对于每次调用的转换函数错误时初始化字母表的基准测试，字母表必须是常量（对于字符串）或静态只读（对于字符[]）。然后，基于字母表的字节[]到字符串的转换变得和字节操作版本一样快。

当然，测试必须在Release中编译（带有优化），并关闭调试选项“抑制JIT优化”（如果代码必须可调试，则“仅启用我的代码”也是如此）。

另一种基于查找表的方法。该方法只为每个字节使用一个查找表，而不是为每个半字节使用查找表。

private static readonly uint[] _lookup32 = CreateLookup32();

private static uint[] CreateLookup32()
{
    var result = new uint[256];
    for (int i = 0; i < 256; i++)
    {
        string s=i.ToString("X2");
        result[i] = ((uint)s[0]) + ((uint)s[1] << 16);
    }
    return result;
}

private static string ByteArrayToHexViaLookup32(byte[] bytes)
{
    var lookup32 = _lookup32;
    var result = new char[bytes.Length * 2];
    for (int i = 0; i < bytes.Length; i++)
    {
        var val = lookup32[bytes[i]];
        result[2*i] = (char)val;
        result[2*i + 1] = (char) (val >> 16);
    }
    return new string(result);
}

我还使用查找表中的ushort、struct｛char X1，X2｝、struct{byte X1，X2}测试了这个变体。

根据编译目标（x86、X64）的不同，它们要么具有大致相同的性能，要么稍慢于此变体。

为了获得更高的性能，其不安全的兄弟：

private static readonly uint[] _lookup32Unsafe = CreateLookup32Unsafe();
private static readonly uint* _lookup32UnsafeP = (uint*)GCHandle.Alloc(_lookup32Unsafe,GCHandleType.Pinned).AddrOfPinnedObject();

private static uint[] CreateLookup32Unsafe()
{
    var result = new uint[256];
    for (int i = 0; i < 256; i++)
    {
        string s=i.ToString("X2");
        if(BitConverter.IsLittleEndian)
            result[i] = ((uint)s[0]) + ((uint)s[1] << 16);
        else
            result[i] = ((uint)s[1]) + ((uint)s[0] << 16);
    }
    return result;
}

public static string ByteArrayToHexViaLookup32Unsafe(byte[] bytes)
{
    var lookupP = _lookup32UnsafeP;
    var result = new char[bytes.Length * 2];
    fixed(byte* bytesP = bytes)
    fixed (char* resultP = result)
    {
        uint* resultP2 = (uint*)resultP;
        for (int i = 0; i < bytes.Length; i++)
        {
            resultP2[i] = lookupP[bytesP[i]];
        }
    }
    return new string(result);
}

或者如果您认为可以直接写入字符串：

public static string ByteArrayToHexViaLookup32UnsafeDirect(byte[] bytes)
{
    var lookupP = _lookup32UnsafeP;
    var result = new string((char)0, bytes.Length * 2);
    fixed (byte* bytesP = bytes)
    fixed (char* resultP = result)
    {
        uint* resultP2 = (uint*)resultP;
        for (int i = 0; i < bytes.Length; i++)
        {
            resultP2[i] = lookupP[bytesP[i]];
        }
    }
    return result;
}

下面还通过允许本机小写选项扩展了这里的优秀答案，并且还处理null或空输入，并使其成为扩展方法。

    /// <summary>
    /// Converts the byte array to a hex string very fast. Excellent job
    /// with code lightly adapted from 'community wiki' here: https://stackoverflow.com/a/14333437/264031
    /// (the function was originally named: ByteToHexBitFiddle). Now allows a native lowerCase option
    /// to be input and allows null or empty inputs (null returns null, empty returns empty).
    /// </summary>
    public static string ToHexString(this byte[] bytes, bool lowerCase = false)
    {
        if (bytes == null)
            return null;
        else if (bytes.Length == 0)
            return "";

        char[] c = new char[bytes.Length * 2];

        int b;
        int xAddToAlpha = lowerCase ? 87 : 55;
        int xAddToDigit = lowerCase ? -39 : -7;

        for (int i = 0; i < bytes.Length; i++) {

            b = bytes[i] >> 4;
            c[i * 2] = (char)(xAddToAlpha + b + (((b - 10) >> 31) & xAddToDigit));

            b = bytes[i] & 0xF;
            c[i * 2 + 1] = (char)(xAddToAlpha + b + (((b - 10) >> 31) & xAddToDigit));
        }

        string val = new string(c);
        return val;
    }

    public static string ToHexString(this IEnumerable<byte> bytes, bool lowerCase = false)
    {
        if (bytes == null)
            return null;
        byte[] arr = bytes.ToArray();
        return arr.ToHexString(lowerCase);
    }

有一个简单的一行解决方案尚未提及，它将十六进制字符串转换为字节数组（我们不在乎这里的否定解释，因为这无关紧要）：

BigInteger.Parse(str, System.Globalization.NumberStyles.HexNumber).ToByteArray().Reverse().ToArray();

    // a safe version of the lookup solution:       

    public static string ByteArrayToHexViaLookup32Safe(byte[] bytes, bool withZeroX)
    {
        if (bytes.Length == 0)
        {
            return withZeroX ? "0x" : "";
        }

        int length = bytes.Length * 2 + (withZeroX ? 2 : 0);
        StateSmall stateToPass = new StateSmall(bytes, withZeroX);
        return string.Create(length, stateToPass, (chars, state) =>
        {
            int offset0x = 0;
            if (state.WithZeroX)
            {
                chars[0] = '0';
                chars[1] = 'x';
                offset0x += 2;
            }

            Span<uint> charsAsInts = MemoryMarshal.Cast<char, uint>(chars.Slice(offset0x));
            int targetLength = state.Bytes.Length;
            for (int i = 0; i < targetLength; i += 1)
            {
                uint val = Lookup32[state.Bytes[i]];
                charsAsInts[i] = val;
            }
        });
    }

    private struct StateSmall
    {
        public StateSmall(byte[] bytes, bool withZeroX)
        {
            Bytes = bytes;
            WithZeroX = withZeroX;
        }

        public byte[] Bytes;
        public bool WithZeroX;
    }

我今天遇到了同样的问题，我遇到了以下代码：

private static string ByteArrayToHex(byte[] barray)
{
    char[] c = new char[barray.Length * 2];
    byte b;
    for (int i = 0; i < barray.Length; ++i)
    {
        b = ((byte)(barray[i] >> 4));
        c[i * 2] = (char)(b > 9 ? b + 0x37 : b + 0x30);
        b = ((byte)(barray[i] & 0xF));
        c[i * 2 + 1] = (char)(b > 9 ? b + 0x37 : b + 0x30);
    }
    return new string(c);
}

来源：论坛帖子byte[]数组到十六进制字符串（见PZahra的帖子）。我稍微修改了一下代码，删除了0x前缀。

我对代码进行了一些性能测试，它几乎比使用BitConverter.ToString（）快八倍（根据patridge的帖子，速度最快）。