有一个名为SoapHexBinary的类，它完全符合您的需要。

using System.Runtime.Remoting.Metadata.W3cXsd2001;

public static byte[] GetStringToBytes(string value)
{
    SoapHexBinary shb = SoapHexBinary.Parse(value);
    return shb.Value;
}

public static string GetBytesToString(byte[] value)
{
    SoapHexBinary shb = new SoapHexBinary(value);
    return shb.ToString();
}

还有XmlWriter.WriteBinHex（请参见MSDN页面）。如果需要将十六进制字符串放入XML流中，这非常有用。

下面是一个独立的方法来了解它的工作原理：

    public static string ToBinHex(byte[] bytes)
    {
        XmlWriterSettings xmlWriterSettings = new XmlWriterSettings();
        xmlWriterSettings.ConformanceLevel = ConformanceLevel.Fragment;
        xmlWriterSettings.CheckCharacters = false;
        xmlWriterSettings.Encoding = ASCIIEncoding.ASCII;
        MemoryStream memoryStream = new MemoryStream();
        using (XmlWriter xmlWriter = XmlWriter.Create(memoryStream, xmlWriterSettings))
        {
            xmlWriter.WriteBinHex(bytes, 0, bytes.Length);
        }
        return Encoding.ASCII.GetString(memoryStream.ToArray());
    }

如果您希望比BitConverter更灵活，但不希望使用那些笨重的90年代风格的显式循环，那么您可以这样做：

String.Join(String.Empty, Array.ConvertAll(bytes, x => x.ToString("X2")));

或者，如果您使用的是.NET 4.0：

String.Concat(Array.ConvertAll(bytes, x => x.ToString("X2")));

（后者来自对原帖子的评论。）

为了方便以后复制和粘贴，将几个答案合并到一个类中：

/// <summary>
/// Extension methods to quickly convert byte array to string and back.
/// </summary>
public static class HexConverter
{
    /// <summary>
    /// Map values to hex digits
    /// </summary>
    private static readonly char[] HexDigits =
        {
            '0', '1', '2', '3', '4', '5', '6', '7', '8', '9', 'A', 'B', 'C', 'D', 'E', 'F'
        };

    /// <summary>
    /// Map 56 characters between ['0', 'F'] to their hex equivalents, and set invalid characters
    /// such that they will overflow byte to fail conversion.
    /// </summary>
    private static readonly ushort[] HexValues =
        {
            0x0000, 0x0001, 0x0002, 0x0003, 0x0004, 0x0005, 0x0006, 0x0007, 0x0008, 0x0009, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100,
            0x000A, 0x000B, 0x000C, 0x000D, 0x000E, 0x000F, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100,
            0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x000A, 0x000B,
            0x000C, 0x000D, 0x000E, 0x000F
        };

    /// <summary>
    /// Empty byte array 
    /// </summary>
    private static readonly byte[] Empty = new byte[0];

    /// <summary>
    /// Convert a byte array to a hexadecimal string.
    /// </summary>
    /// <param name="bytes">
    /// The input byte array.
    /// </param>
    /// <returns>
    /// A string of hexadecimal digits.
    /// </returns>
    public static string ToHexString(this byte[] bytes)
    {
        var c = new char[bytes.Length * 2];
        for (int i = 0, j = 0; i < bytes.Length; i++)
        {
            c[j++] = HexDigits[bytes[i] >> 4];
            c[j++] = HexDigits[bytes[i] & 0x0F];
        }

        return new string(c);
    }

    /// <summary>
    /// Parse a string of hexadecimal digits into a byte array.
    /// </summary>
    /// <param name="hexadecimalString">
    /// The hexadecimal string.
    /// </param>
    /// <returns>
    /// The parsed <see cref="byte[]"/> array.
    /// </returns>
    /// <exception cref="ArgumentException">
    /// The input string either contained invalid characters, or was of an odd length.
    /// </exception>
    public static byte[] ToByteArray(string hexadecimalString)
    {
        if (!TryParse(hexadecimalString, out var value))
        {
            throw new ArgumentException("Invalid hexadecimal string", nameof(hexadecimalString));
        }

        return value;
    }

    /// <summary>
    /// Parse a hexadecimal string to bytes
    /// </summary>
    /// <param name="hexadecimalString">
    /// The hexadecimal string, which must be an even number of characters.
    /// </param>
    /// <param name="value">
    /// The parsed value if successful.
    /// </param>
    /// <returns>
    /// True if successful.
    /// </returns>
    public static bool TryParse(string hexadecimalString, out byte[] value)
    {
        if (hexadecimalString.Length == 0)
        {
            value = Empty;
            return true;
        }

        if (hexadecimalString.Length % 2 != 0)
        {
            value = Empty;
            return false;
        }

        try
        {

            value = new byte[hexadecimalString.Length / 2];
            for (int i = 0, j = 0; j < hexadecimalString.Length; i++)
            {
                value[i] = (byte)((HexValues[hexadecimalString[j++] - '0'] << 4)
                                  | HexValues[hexadecimalString[j++] - '0']);
            }

            return true;
        }
        catch (OverflowException)
        {
            value = Empty;
            return false;
        }
    }
}

如果你想得到wcoenen报告的“4倍速度增长”，那么如果不明显：用hex[i]+hex[i+1]替换hex.Substring（i，2）

您还可以再进一步，通过在两个地方使用i++来消除i+=2。

另一种基于查找表的方法。该方法只为每个字节使用一个查找表，而不是为每个半字节使用查找表。

private static readonly uint[] _lookup32 = CreateLookup32();

private static uint[] CreateLookup32()
{
    var result = new uint[256];
    for (int i = 0; i < 256; i++)
    {
        string s=i.ToString("X2");
        result[i] = ((uint)s[0]) + ((uint)s[1] << 16);
    }
    return result;
}

private static string ByteArrayToHexViaLookup32(byte[] bytes)
{
    var lookup32 = _lookup32;
    var result = new char[bytes.Length * 2];
    for (int i = 0; i < bytes.Length; i++)
    {
        var val = lookup32[bytes[i]];
        result[2*i] = (char)val;
        result[2*i + 1] = (char) (val >> 16);
    }
    return new string(result);
}

我还使用查找表中的ushort、struct｛char X1，X2｝、struct{byte X1，X2}测试了这个变体。

根据编译目标（x86、X64）的不同，它们要么具有大致相同的性能，要么稍慢于此变体。

为了获得更高的性能，其不安全的兄弟：

private static readonly uint[] _lookup32Unsafe = CreateLookup32Unsafe();
private static readonly uint* _lookup32UnsafeP = (uint*)GCHandle.Alloc(_lookup32Unsafe,GCHandleType.Pinned).AddrOfPinnedObject();

private static uint[] CreateLookup32Unsafe()
{
    var result = new uint[256];
    for (int i = 0; i < 256; i++)
    {
        string s=i.ToString("X2");
        if(BitConverter.IsLittleEndian)
            result[i] = ((uint)s[0]) + ((uint)s[1] << 16);
        else
            result[i] = ((uint)s[1]) + ((uint)s[0] << 16);
    }
    return result;
}

public static string ByteArrayToHexViaLookup32Unsafe(byte[] bytes)
{
    var lookupP = _lookup32UnsafeP;
    var result = new char[bytes.Length * 2];
    fixed(byte* bytesP = bytes)
    fixed (char* resultP = result)
    {
        uint* resultP2 = (uint*)resultP;
        for (int i = 0; i < bytes.Length; i++)
        {
            resultP2[i] = lookupP[bytesP[i]];
        }
    }
    return new string(result);
}

或者如果您认为可以直接写入字符串：

public static string ByteArrayToHexViaLookup32UnsafeDirect(byte[] bytes)
{
    var lookupP = _lookup32UnsafeP;
    var result = new string((char)0, bytes.Length * 2);
    fixed (byte* bytesP = bytes)
    fixed (char* resultP = result)
    {
        uint* resultP2 = (uint*)resultP;
        for (int i = 0; i < bytes.Length; i++)
        {
            resultP2[i] = lookupP[bytesP[i]];
        }
    }
    return result;
}