.NET 5已添加Convert.ToHexString方法。

对于使用旧版本.NET的用户

internal static class ByteArrayExtensions
{
    
    public static string ToHexString(this byte[] bytes, Casing casing = Casing.Upper)
    {
        Span<char> result = stackalloc char[0];
        if (bytes.Length > 16)
        {
            var array = new char[bytes.Length * 2];
            result = array.AsSpan();
        }
        else
        {
            result = stackalloc char[bytes.Length * 2];
        }

        int pos = 0;
        foreach (byte b in bytes)
        {
            ToCharsBuffer(b, result, pos, casing);
            pos += 2;
        }

        return result.ToString();
    }

    private static void ToCharsBuffer(byte value, Span<char> buffer, int startingIndex = 0, Casing casing = Casing.Upper)
    {
        uint difference = (((uint)value & 0xF0U) << 4) + ((uint)value & 0x0FU) - 0x8989U;
        uint packedResult = ((((uint)(-(int)difference) & 0x7070U) >> 4) + difference + 0xB9B9U) | (uint)casing;

        buffer[startingIndex + 1] = (char)(packedResult & 0xFF);
        buffer[startingIndex] = (char)(packedResult >> 8);
    }
}

public enum Casing : uint
{
    // Output [ '0' .. '9' ] and [ 'A' .. 'F' ].
    Upper = 0,

    // Output [ '0' .. '9' ] and [ 'a' .. 'f' ].
    Lower = 0x2020U,
}

改编自.NET存储库https://github.com/dotnet/runtime/blob/v5.0.3/src/libraries/System.Private.CoreLib/src/System/Convert.cshttps://github.com/dotnet/runtime/blob/v5.0.3/src/libraries/Common/src/System/HexConverter.cs

为了方便以后复制和粘贴，将几个答案合并到一个类中：

/// <summary>
/// Extension methods to quickly convert byte array to string and back.
/// </summary>
public static class HexConverter
{
    /// <summary>
    /// Map values to hex digits
    /// </summary>
    private static readonly char[] HexDigits =
        {
            '0', '1', '2', '3', '4', '5', '6', '7', '8', '9', 'A', 'B', 'C', 'D', 'E', 'F'
        };

    /// <summary>
    /// Map 56 characters between ['0', 'F'] to their hex equivalents, and set invalid characters
    /// such that they will overflow byte to fail conversion.
    /// </summary>
    private static readonly ushort[] HexValues =
        {
            0x0000, 0x0001, 0x0002, 0x0003, 0x0004, 0x0005, 0x0006, 0x0007, 0x0008, 0x0009, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100,
            0x000A, 0x000B, 0x000C, 0x000D, 0x000E, 0x000F, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100,
            0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x0100, 0x000A, 0x000B,
            0x000C, 0x000D, 0x000E, 0x000F
        };

    /// <summary>
    /// Empty byte array 
    /// </summary>
    private static readonly byte[] Empty = new byte[0];

    /// <summary>
    /// Convert a byte array to a hexadecimal string.
    /// </summary>
    /// <param name="bytes">
    /// The input byte array.
    /// </param>
    /// <returns>
    /// A string of hexadecimal digits.
    /// </returns>
    public static string ToHexString(this byte[] bytes)
    {
        var c = new char[bytes.Length * 2];
        for (int i = 0, j = 0; i < bytes.Length; i++)
        {
            c[j++] = HexDigits[bytes[i] >> 4];
            c[j++] = HexDigits[bytes[i] & 0x0F];
        }

        return new string(c);
    }

    /// <summary>
    /// Parse a string of hexadecimal digits into a byte array.
    /// </summary>
    /// <param name="hexadecimalString">
    /// The hexadecimal string.
    /// </param>
    /// <returns>
    /// The parsed <see cref="byte[]"/> array.
    /// </returns>
    /// <exception cref="ArgumentException">
    /// The input string either contained invalid characters, or was of an odd length.
    /// </exception>
    public static byte[] ToByteArray(string hexadecimalString)
    {
        if (!TryParse(hexadecimalString, out var value))
        {
            throw new ArgumentException("Invalid hexadecimal string", nameof(hexadecimalString));
        }

        return value;
    }

    /// <summary>
    /// Parse a hexadecimal string to bytes
    /// </summary>
    /// <param name="hexadecimalString">
    /// The hexadecimal string, which must be an even number of characters.
    /// </param>
    /// <param name="value">
    /// The parsed value if successful.
    /// </param>
    /// <returns>
    /// True if successful.
    /// </returns>
    public static bool TryParse(string hexadecimalString, out byte[] value)
    {
        if (hexadecimalString.Length == 0)
        {
            value = Empty;
            return true;
        }

        if (hexadecimalString.Length % 2 != 0)
        {
            value = Empty;
            return false;
        }

        try
        {

            value = new byte[hexadecimalString.Length / 2];
            for (int i = 0, j = 0; j < hexadecimalString.Length; i++)
            {
                value[i] = (byte)((HexValues[hexadecimalString[j++] - '0'] << 4)
                                  | HexValues[hexadecimalString[j++] - '0']);
            }

            return true;
        }
        catch (OverflowException)
        {
            value = Empty;
            return false;
        }
    }
}

如果性能很重要，这里有一个优化的解决方案：

    static readonly char[] _hexDigits = "0123456789abcdef".ToCharArray();
    public static string ToHexString(this byte[] bytes)
    {
        char[] digits = new char[bytes.Length * 2];
        for (int i = 0; i < bytes.Length; i++)
        {
            int d1, d2;
            d1 = Math.DivRem(bytes[i], 16, out d2);
            digits[2 * i] = _hexDigits[d1];
            digits[2 * i + 1] = _hexDigits[d2];
        }
        return new string(digits);
    }

它比BitConverter.ToString快2.5倍，比BitConverter.ToString+删除“-”字符快7倍。

    // a safe version of the lookup solution:       

    public static string ByteArrayToHexViaLookup32Safe(byte[] bytes, bool withZeroX)
    {
        if (bytes.Length == 0)
        {
            return withZeroX ? "0x" : "";
        }

        int length = bytes.Length * 2 + (withZeroX ? 2 : 0);
        StateSmall stateToPass = new StateSmall(bytes, withZeroX);
        return string.Create(length, stateToPass, (chars, state) =>
        {
            int offset0x = 0;
            if (state.WithZeroX)
            {
                chars[0] = '0';
                chars[1] = 'x';
                offset0x += 2;
            }

            Span<uint> charsAsInts = MemoryMarshal.Cast<char, uint>(chars.Slice(offset0x));
            int targetLength = state.Bytes.Length;
            for (int i = 0; i < targetLength; i += 1)
            {
                uint val = Lookup32[state.Bytes[i]];
                charsAsInts[i] = val;
            }
        });
    }

    private struct StateSmall
    {
        public StateSmall(byte[] bytes, bool withZeroX)
        {
            Bytes = bytes;
            WithZeroX = withZeroX;
        }

        public byte[] Bytes;
        public bool WithZeroX;
    }

对老年人来说最快的方法。。。想念你的指针

    static public byte[] HexStrToByteArray(string str)
    {
        byte[] res = new byte[(str.Length % 2 != 0 ? 0 : str.Length / 2)]; //check and allocate memory
        for (int i = 0, j = 0; j < res.Length; i += 2, j++) //convert loop
            res[j] = (byte)((str[i] % 32 + 9) % 25 * 16 + (str[i + 1] % 32 + 9) % 25);
        return res;
    }

支持最短路径和.net核心：

    public static string BytesToString(byte[] ba) =>
        ba.Aggregate(new StringBuilder(32), (sb, b) => sb.Append(b.ToString("X2"))).ToString();