我将利用.NET 4.0+的优势，为最初接受的问题提供更新的答案：

foreach(var entry in MyDic)
{
    // do something with entry.Value or entry.Key
}

取决于你是在寻找关键点还是值。。。

来自MSDN Dictionary（TKey，TValue）类描述：

// When you use foreach to enumerate dictionary elements,
// the elements are retrieved as KeyValuePair objects.
Console.WriteLine();
foreach( KeyValuePair<string, string> kvp in openWith )
{
    Console.WriteLine("Key = {0}, Value = {1}", 
        kvp.Key, kvp.Value);
}

// To get the values alone, use the Values property.
Dictionary<string, string>.ValueCollection valueColl =
    openWith.Values;

// The elements of the ValueCollection are strongly typed
// with the type that was specified for dictionary values.
Console.WriteLine();
foreach( string s in valueColl )
{
    Console.WriteLine("Value = {0}", s);
}

// To get the keys alone, use the Keys property.
Dictionary<string, string>.KeyCollection keyColl =
    openWith.Keys;

// The elements of the KeyCollection are strongly typed
// with the type that was specified for dictionary keys.
Console.WriteLine();
foreach( string s in keyColl )
{
    Console.WriteLine("Key = {0}", s);
}

您也可以在用于多线程处理的大型字典上尝试此操作。

dictionary
.AsParallel()
.ForAll(pair => 
{ 
    // Process pair.Key and pair.Value here
});

C#7.0引入了解构器，如果您正在使用.NET Core 2.0+应用程序，那么结构KeyValuePair＜＞已经为您提供了一个解构器（）。因此，您可以做到：

var dic = new Dictionary<int, string>() { { 1, "One" }, { 2, "Two" }, { 3, "Three" } };
foreach (var (key, value) in dic) {
    Console.WriteLine($"Item [{key}] = {value}");
}
//Or
foreach (var (_, value) in dic) {
    Console.WriteLine($"Item [NO_ID] = {value}");
}
//Or
foreach ((int key, string value) in dic) {
    Console.WriteLine($"Item [{key}] = {value}");
}

我在MSDN上DictionaryBase类的文档中找到了此方法：

foreach (DictionaryEntry de in myDictionary)
{
     //Do some stuff with de.Value or de.Key
}

这是我唯一能够在从DictionaryBase继承的类中正确运行的一个。

从C#7开始，您可以将对象分解为变量。我认为这是遍历字典的最佳方式。

例子：

在KeyValuePair<TKey，TVal>上创建一个扩展方法，对其进行解构：

public static void Deconstruct<TKey, TVal>(this KeyValuePair<TKey, TVal> pair, out TKey key, out TVal value)
{
   key = pair.Key;
   value = pair.Value;
}

按以下方式遍历任何字典<TKey，TVal>

// Dictionary can be of any types, just using 'int' and 'string' as examples.
Dictionary<int, string> dict = new Dictionary<int, string>();

// Deconstructor gets called here.
foreach (var (key, value) in dict)
{
   Console.WriteLine($"{key} : {value}");
}