try:
    statements # statements that can raise exceptions
except:
    statements # statements that will be executed to handle exceptions
else:
    statements # statements that will be executed if there is no exception

例子:

try:
    age=int(input('Enter your age: '))
except:
    print ('You have entered an invalid value.')
else:
    if age <= 21:
        print('You are not allowed to enter, you are too young.')
    else:
        print('Welcome, you are old enough.')

输出:

>>> 
Enter your age: a
You have entered an invalid value.
>>> RESTART
>>> 
Enter your age: 25
Welcome, you are old enough.
>>> RESTART
>>> 
Enter your age: 13
You are not allowed to enter, you are too young.
>>> 

复制自:https://geek-university.com/python/the-try-except-else-statements/

错误和异常#处理异常- docs.python.org

The try ... except statement has an optional else clause, which, when present, must follow all except clauses. It is useful for code that must be executed if the try clause does not raise an exception. For example: for arg in sys.argv[1:]: try: f = open(arg, 'r') except IOError: print 'cannot open', arg else: print arg, 'has', len(f.readlines()), 'lines' f.close() The use of the else clause is better than adding additional code to the try clause because it avoids accidentally catching an exception that wasn’t raised by the code being protected by the try ... except statement.

else块通常可以用来补充出现在每个except块中的功能。

try:
    test_consistency(valuable_data)
except Except1:
    inconsistency_type = 1
except Except2:
    inconsistency_type = 2
except:
    # Something else is wrong
    raise
else:
    inconsistency_type = 0

"""
Process each individual inconsistency down here instead of
inside the except blocks. Use 0 to mean no inconsistency.
"""

在这种情况下，在每个except块中设置inconsistency_type，以便在无错误情况下在else中补充行为。

当然，我将此描述为某一天可能会出现在您自己的代码中的模式。在这个特定的情况下，您只要在try块之前将inconsistency_type设置为0即可。

PEP 380中有一个很好的try-else示例。基本上，它归结为在算法的不同部分做不同的异常处理。

大概是这样的:

try:
    do_init_stuff()
except:
    handle_init_suff_execption()
else:
    try:
        do_middle_stuff()
    except:
        handle_middle_stuff_exception()

这允许您在异常发生的地方编写异常处理代码。

即使你现在想不出它的用途，你可以打赌它一定会有用处的。下面是一个没有想象力的例子:

其他:

a = [1,2,3]
try:
    something = a[2]
except IndexError:
    print("out of bounds")
else:
    print(something)

没有其他的:

try:
    something = a[2]
except IndexError:
    print("out of bounds")

if "something" in locals():
    print(something)

在这里，如果没有抛出错误，则定义了变量something。您可以在try块之外删除它，但如果定义了变量，则需要进行一些混乱的检测。

查看Python引用，当没有异常时，else似乎在try之后执行。 当控制流出try子句的末尾时，执行可选的else子句。else子句中的异常不由前面的except子句处理。

Dive into python有一个例子，如果我理解正确的话，在try块中他们尝试导入一个模块，当失败时，你会得到异常并绑定默认值，但当它工作时，你可以选择进入else块并绑定所需的内容(参见示例和解释链接)。

如果你试图在catch块中工作，它可能会抛出另一个异常——我想这就是else块派上用场的地方。