首先去https://myaccount.google.com/lesssecureapps，并允许不太安全的应用程序为真。

然后使用下面的代码。这下面的代码只会工作，如果你的电子邮件地址是从gmail。

static void SendEmail()
    {
        string mailBodyhtml =
            "<p>some text here</p>";
        var msg = new MailMessage("from@gmail.com", "to1@gmail.com", "Hello", mailBodyhtml);
        msg.To.Add("to2@gmail.com");
        msg.IsBodyHtml = true;
        var smtpClient = new SmtpClient("smtp.gmail.com", 587); //**if your from email address is "from@hotmail.com" then host should be "smtp.hotmail.com"**
        smtpClient.UseDefaultCredentials = true;
        smtpClient.Credentials = new NetworkCredential("from@gmail.com", "password");
        smtpClient.EnableSsl = true;
        smtpClient.Send(msg);
        Console.WriteLine("Email Sent Successfully");
    }

这样的:

mail.To = "user@hotmail.com";

应该是:

mail.To.Add(new MailAddress("user@hotmail.com"));

这也可以…

string your_id = "your_id@gmail.com";
string your_password = "password";
try
{
   SmtpClient client = new SmtpClient
   {
     Host = "smtp.gmail.com",
     Port = 587,
     EnableSsl = true,
     DeliveryMethod = SmtpDeliveryMethod.Network,
     Credentials = new System.Net.NetworkCredential(your_id, your_password),
     Timeout = 10000,
   };
   MailMessage mm = new MailMessage(your_iD, "recepient@gmail.com", "subject", "body");
   client.Send(mm);
   Console.WriteLine("Email Sent");
 }
 catch (Exception e)
 {
   Console.WriteLine("Could not end email\n\n"+e.ToString());
 }

邮件。寄和寄。From是只读的。将它们移动到构造函数中。

using System.Net.Mail;

...

MailMessage mail = new MailMessage("you@yourcompany.example", "user@hotmail.com");
SmtpClient client = new SmtpClient();
client.Port = 25;
client.DeliveryMethod = SmtpDeliveryMethod.Network;
client.UseDefaultCredentials = false;
client.Host = "smtp.gmail.com";
mail.Subject = "this is a test email.";
mail.Body = "this is my test email body";
client.Send(mail);

通过SMTP发送电子邮件

public void EmailSend(string subject, string host, string from, string to, string body, int port, string username, string password, bool enableSsl)
    {
        try
        {
            MailMessage mail = new MailMessage();
            SmtpClient smtpServer = new SmtpClient(host);
            mail.Subject = subject;
            mail.From = new MailAddress(from);
            mail.To.Add(to);
            mail.Body = body;
            smtpServer.Port = port;
            smtpServer.Credentials = new NetworkCredential(username, password);
            smtpServer.EnableSsl = enableSsl;
            smtpServer.Send(mail);
        }
        catch (Exception ex)
        {
            throw new Exception(ex.Message);
        }
    }

使用发件人和收件人的电子邮件地址初始化MailMessage。应该是这样的

string from = "codeforwin@gmail.com";  //Senders email   
string to = "reciever@gmail.com";  //Receiver's email  
MailMessage msg = new MailMessage(from, to); 

阅读如何用c#发送电子邮件的完整代码片段