我非常喜欢马克·布兰克特的回答，所以我自己做了一个快速的执行。如果还有人急着要的话，这是:

public class NetworkConnection : IDisposable
{
    string _networkName;

    public NetworkConnection(string networkName, 
        NetworkCredential credentials)
    {
        _networkName = networkName;

        var netResource = new NetResource()
        {
            Scope = ResourceScope.GlobalNetwork,
            ResourceType = ResourceType.Disk,
            DisplayType = ResourceDisplaytype.Share,
            RemoteName = networkName
        };

        var userName = string.IsNullOrEmpty(credentials.Domain)
            ? credentials.UserName
            : string.Format(@"{0}\{1}", credentials.Domain, credentials.UserName);

        var result = WNetAddConnection2(
            netResource, 
            credentials.Password,
            userName,
            0);
            
        if (result != 0)
        {
            throw new Win32Exception(result);
        }   
    }

    ~NetworkConnection()
    {
        Dispose(false);
    }

    public void Dispose()
    {
        Dispose(true);
        GC.SuppressFinalize(this);
    }

    protected virtual void Dispose(bool disposing)
    {
        WNetCancelConnection2(_networkName, 0, true);
    }

    [DllImport("mpr.dll")]
    private static extern int WNetAddConnection2(NetResource netResource, 
        string password, string username, int flags);

    [DllImport("mpr.dll")]
    private static extern int WNetCancelConnection2(string name, int flags,
        bool force);
}

[StructLayout(LayoutKind.Sequential)]
public class NetResource
{
    public ResourceScope Scope;
    public ResourceType ResourceType;
    public ResourceDisplaytype DisplayType;
    public int Usage;
    [MarshalAs(UnmanagedType.LPWStr)]
    public string LocalName;
    [MarshalAs(UnmanagedType.LPWStr)]
    public string RemoteName;
    [MarshalAs(UnmanagedType.LPWStr)]
    public string Comment;
    [MarshalAs(UnmanagedType.LPWStr)]
    public string Provider;
}

public enum ResourceScope : int
{
    Connected = 1,
    GlobalNetwork,
    Remembered,
    Recent,
    Context
};

public enum ResourceType : int
{
    Any = 0,
    Disk = 1,
    Print = 2,
    Reserved = 8,
}

public enum ResourceDisplaytype : int
{
    Generic = 0x0,
    Domain = 0x01,
    Server = 0x02,
    Share = 0x03,
    File = 0x04,
    Group = 0x05,
    Network = 0x06,
    Root = 0x07,
    Shareadmin = 0x08,
    Directory = 0x09,
    Tree = 0x0a,
    Ndscontainer = 0x0b
}

VB。热爱VB。NET等价的Luke Quinane的代码(谢谢Luke!)

Imports System
Imports System.Net
Imports System.Runtime.InteropServices
Imports System.ComponentModel

Public Class NetworkConnection
    Implements IDisposable

    Private _networkName As String

    Public Sub New(networkName As String, credentials As NetworkCredential)
        _networkName = networkName

        Dim netResource = New NetResource() With {
             .Scope = ResourceScope.GlobalNetwork,
             .ResourceType = ResourceType.Disk,
             .DisplayType = ResourceDisplaytype.Share,
             .RemoteName = networkName
        }

        Dim userName = If(String.IsNullOrEmpty(credentials.Domain), credentials.UserName, String.Format("{0}\{1}", credentials.Domain, credentials.UserName))

        Dim result = WNetAddConnection2(NetResource, credentials.Password, userName, 0)

        If result <> 0 Then
            Throw New Win32Exception(result, "Error connecting to remote share")
        End If
    End Sub

    Protected Overrides Sub Finalize()
        Try
            Dispose (False)
        Finally
            MyBase.Finalize()
        End Try
    End Sub

    Public Sub Dispose() Implements IDisposable.Dispose
        Dispose (True)
        GC.SuppressFinalize (Me)
    End Sub

    Protected Overridable Sub Dispose(disposing As Boolean)
        WNetCancelConnection2(_networkName, 0, True)
    End Sub

    <DllImport("mpr.dll")> _
    Private Shared Function WNetAddConnection2(netResource As NetResource, password As String, username As String, flags As Integer) As Integer
    End Function

    <DllImport("mpr.dll")> _
    Private Shared Function WNetCancelConnection2(name As String, flags As Integer, force As Boolean) As Integer
    End Function

End Class

<StructLayout(LayoutKind.Sequential)> _
Public Class NetResource
    Public Scope As ResourceScope
    Public ResourceType As ResourceType
    Public DisplayType As ResourceDisplaytype
    Public Usage As Integer
    Public LocalName As String
    Public RemoteName As String
    Public Comment As String
    Public Provider As String
End Class

Public Enum ResourceScope As Integer
    Connected = 1
    GlobalNetwork
    Remembered
    Recent
    Context
End Enum

Public Enum ResourceType As Integer
    Any = 0
    Disk = 1
    Print = 2
    Reserved = 8
End Enum

Public Enum ResourceDisplaytype As Integer
    Generic = &H0
    Domain = &H1
    Server = &H2
    Share = &H3
    File = &H4
    Group = &H5
    Network = &H6
    Root = &H7
    Shareadmin = &H8
    Directory = &H9
    Tree = &HA
    Ndscontainer = &HB
End Enum

你应该像这样添加一行:

<identity impersonate="true" userName="domain\user" password="****" />

在你的web.config中。

更多的信息。

一种可行的方法是使用WindowsIdentity。模拟(并更改线程主体)成为所需的用户，如下所示。回到p/invoke，不过，恐怕……

另一个厚脸皮的(同样不理想的)选择可能是生成一个流程来完成这项工作……ProcessStartInfo接受. username， . password和. domain。

最后-也许在一个有权限的专用帐户中运行服务?(删除，因为你已经澄清这不是一个选项)。

您可以更改线程标识，或者P/Invoke WNetAddConnection2。我更喜欢后者，因为我有时需要为不同的位置维护多个凭证。我把它包装成一个IDisposable，然后调用WNetCancelConnection2来删除信用(避免多个用户名错误):

using (new NetworkConnection(@"\\server\read", readCredentials))
using (new NetworkConnection(@"\\server2\write", writeCredentials)) {
   File.Copy(@"\\server\read\file", @"\\server2\write\file");
}

如果你不能创建一个本地有效的安全令牌，似乎你已经排除了所有选项栏Win32 API和WNetAddConnection*。

MSDN上关于WNet - PInvoke信息和连接到UNC路径的示例代码的大量信息:

http://www.pinvoke.net/default.aspx/mpr/WNetAddConnection2.html#

MSDN参考:

http://msdn.microsoft.com/en-us/library/aa385391 (VS.85) . aspx