为便于阅读而重写：

# 2D array/ matrix

# 5 rows, 5 cols
rows_count = 5
cols_count = 5

# create
#     creation looks reverse
#     create an array of "cols_count" cols, for each of the "rows_count" rows
#        all elements are initialized to 0
two_d_array = [[0 for j in range(cols_count)] for i in range(rows_count)]

# index is from 0 to 4
#     for both rows & cols
#     since 5 rows, 5 cols

# use
two_d_array[0][0] = 1
print two_d_array[0][0]  # prints 1   # 1st row, 1st col (top-left element of matrix)

two_d_array[1][0] = 2
print two_d_array[1][0]  # prints 2   # 2nd row, 1st col

two_d_array[1][4] = 3
print two_d_array[1][4]  # prints 3   # 2nd row, last col

two_d_array[4][4] = 4
print two_d_array[4][4]  # prints 4   # last row, last col (right, bottom element of matrix)

为便于阅读而重写：

# 2D array/ matrix

# 5 rows, 5 cols
rows_count = 5
cols_count = 5

# create
#     creation looks reverse
#     create an array of "cols_count" cols, for each of the "rows_count" rows
#        all elements are initialized to 0
two_d_array = [[0 for j in range(cols_count)] for i in range(rows_count)]

# index is from 0 to 4
#     for both rows & cols
#     since 5 rows, 5 cols

# use
two_d_array[0][0] = 1
print two_d_array[0][0]  # prints 1   # 1st row, 1st col (top-left element of matrix)

two_d_array[1][0] = 2
print two_d_array[1][0]  # prints 2   # 2nd row, 1st col

two_d_array[1][4] = 3
print two_d_array[1][4]  # prints 3   # 2nd row, last col

two_d_array[4][4] = 4
print two_d_array[4][4]  # prints 4   # last row, last col (right, bottom element of matrix)

你应该列出一个列表，最好的方法是使用嵌套的理解：

>>> matrix = [[0 for i in range(5)] for j in range(5)]
>>> pprint.pprint(matrix)
[[0, 0, 0, 0, 0],
 [0, 0, 0, 0, 0],
 [0, 0, 0, 0, 0],
 [0, 0, 0, 0, 0],
 [0, 0, 0, 0, 0]]

在您的[5][5]示例中，您正在创建一个包含整数“5”的列表，并尝试访问其第5项，这自然会引发IndexError，因为没有第5项：

>>> l = [5]
>>> l[5]
Traceback (most recent call last):
  File "<stdin>", line 1, in <module>
IndexError: list index out of range

l=[[0]*(L) for _ in range(W)]

将快于：

l = [[0 for x in range(L)] for y in range(W)] 

要声明一个零（1）矩阵：

numpy.zeros((x, y))

e.g.

>>> numpy.zeros((3, 5))
    array([[ 0.,  0.,  0.,  0.,  0.],
   [ 0.,  0.,  0.,  0.,  0.],
   [ 0.,  0.,  0.,  0.,  0.]])

或numpy.ones（（x，y））例如

>>> np.ones((3, 5))
array([[ 1.,  1.,  1.,  1.,  1.],
   [ 1.,  1.,  1.,  1.,  1.],
   [ 1.,  1.,  1.,  1.,  1.]])

甚至三维都是可能的。(http://www.astro.ufl.edu/~warner/prog/python.html请参见-->多维数组）

使用NumPy，可以如下初始化空矩阵：

import numpy as np
mm = np.matrix([])

然后像这样附加数据：

mm = np.append(mm, [[1,2]], axis=1)