这里是我完整的认证解决方案，供您参考。

首先，添加以下四个引用

 using System.DirectoryServices;
 using System.DirectoryServices.Protocols;
 using System.DirectoryServices.AccountManagement;
 using System.Net; 

private void AuthUser() { 


      try{
            string Uid = "USER_NAME";
            string Pass = "PASSWORD";
            if (Uid == "")
            {
                MessageBox.Show("Username cannot be null");
            }
            else if (Pass == "")
            {
                MessageBox.Show("Password cannot be null");
            }
            else
            {
                LdapConnection connection = new LdapConnection("YOUR DOMAIN");
                NetworkCredential credential = new NetworkCredential(Uid, Pass);
                connection.Credential = credential;
                connection.Bind();

                // after authenticate Loading user details to data table
                PrincipalContext ctx = new PrincipalContext(ContextType.Domain);
                UserPrincipal user = UserPrincipal.FindByIdentity(ctx, Uid);
                DirectoryEntry up_User = (DirectoryEntry)user.GetUnderlyingObject();
                DirectorySearcher deSearch = new DirectorySearcher(up_User);
                SearchResultCollection results = deSearch.FindAll();
                ResultPropertyCollection rpc = results[0].Properties;
                DataTable dt = new DataTable();
                DataRow toInsert = dt.NewRow();
                dt.Rows.InsertAt(toInsert, 0);

                foreach (string rp in rpc.PropertyNames)
                {
                    if (rpc[rp][0].ToString() != "System.Byte[]")
                    {
                        dt.Columns.Add(rp.ToString(), typeof(System.String));

                        foreach (DataRow row in dt.Rows)
                        {
                            row[rp.ToString()] = rpc[rp][0].ToString();
                        }

                    }  
                }
             //You can load data to grid view and see for reference only
                 dataGridView1.DataSource = dt;


            }
        } //Error Handling part
        catch (LdapException lexc)
        {
            String error = lexc.ServerErrorMessage;
            string pp = error.Substring(76, 4);
            string ppp = pp.Trim();

            if ("52e" == ppp)
            {
                MessageBox.Show("Invalid Username or password, contact ADA Team");
            }
            if ("775​" == ppp)
            {
                MessageBox.Show("User account locked, contact ADA Team");
            }
            if ("525​" == ppp)
            {
                MessageBox.Show("User not found, contact ADA Team");
            }
            if ("530" == ppp)
            {
                MessageBox.Show("Not permitted to logon at this time, contact ADA Team");
            }
            if ("531" == ppp)
            {
                MessageBox.Show("Not permitted to logon at this workstation, contact ADA Team");
            }
            if ("532" == ppp)
            {
                MessageBox.Show("Password expired, contact ADA Team");
            }
            if ("533​" == ppp)
            {
                MessageBox.Show("Account disabled, contact ADA Team");
            }
            if ("533​" == ppp)
            {
                MessageBox.Show("Account disabled, contact ADA Team");
            }



        } //common error handling
        catch (Exception exc)
        {
            MessageBox.Show("Invalid Username or password, contact ADA Team");

        }

        finally {
            tbUID.Text = "";
            tbPass.Text = "";

        }
    }

对我来说，这两个下面的工作，确保你的域名是LDAP://在开始

//"LDAP://" + domainName
private void btnValidate_Click(object sender, RoutedEventArgs e)
{
    try
    {
        DirectoryEntry de = new DirectoryEntry(txtDomainName.Text, txtUsername.Text, txtPassword.Text);
        DirectorySearcher dsearch = new DirectorySearcher(de);
        SearchResult results = null;

        results = dsearch.FindOne();

        MessageBox.Show("Validation Success.");
    }
    catch (LdapException ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
    catch (Exception ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
}

private void btnValidate2_Click(object sender, RoutedEventArgs e)
{
    try
    {
        LdapConnection lcon = new LdapConnection(new LdapDirectoryIdentifier((string)null, false, false));
        NetworkCredential nc = new NetworkCredential(txtUsername.Text,
                               txtPassword.Text, txtDomainName.Text);
        lcon.Credential = nc;
        lcon.AuthType = AuthType.Negotiate;
        lcon.Bind(nc);

        MessageBox.Show("Validation Success.");
    }
    catch (LdapException ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
    catch (Exception ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
}

不幸的是，没有“简单”的方法来检查AD上的用户凭据。

使用到目前为止所介绍的每一种方法，你可能会得到一个假阴性:用户的信用将是有效的，但AD在某些情况下将返回false:

用户需要在下次登录时更改密码。 用户密码已过期。

ActiveDirectory不允许您使用LDAP来确定密码是否由于用户必须更改密码或密码是否过期而无效。

要确定密码更改或密码过期，您可以调用Win32:LogonUser()，并检查以下2个常量的windows错误码:

Error_password_must_change = 1907 Error_password_expired = 1330

试试这段代码 (注意:报告不能在windows server 2000上工作)

#region NTLogonUser
#region Direct OS LogonUser Code
[DllImport( "advapi32.dll")]
private static extern bool LogonUser(String lpszUsername, 
    String lpszDomain, String lpszPassword, int dwLogonType, 
    int dwLogonProvider, out int phToken);

[DllImport("Kernel32.dll")]
private static extern int GetLastError();

public static bool LogOnXP(String sDomain, String sUser, String sPassword)
{
   int token1, ret;
   int attmpts = 0;

   bool LoggedOn = false;

   while (!LoggedOn && attmpts < 2)
   {
      LoggedOn= LogonUser(sUser, sDomain, sPassword, 3, 0, out token1);
      if (LoggedOn) return (true);
      else
      {
         switch (ret = GetLastError())
         {
            case (126): ; 
               if (attmpts++ > 2)
                  throw new LogonException(
                      "Specified module could not be found. error code: " + 
                      ret.ToString());
               break;

            case (1314): 
               throw new LogonException(
                  "Specified module could not be found. error code: " + 
                      ret.ToString());

            case (1326): 
               // edited out based on comment
               //  throw new LogonException(
               //   "Unknown user name or bad password.");
            return false;

            default: 
               throw new LogonException(
                  "Unexpected Logon Failure. Contact Administrator");
              }
          }
       }
   return(false);
}
#endregion Direct Logon Code
#endregion NTLogonUser

除非你需要为“LogonException”创建自己的自定义异常

可能最简单的方法是PInvoke LogonUser Win32 api。

http://www.pinvoke.net/default.aspx/advapi32/LogonUser.html

MSDN参考在这里…

http://msdn.microsoft.com/en-us/library/aa378184.aspx

绝对要使用登录类型

LOGON32_LOGON_NETWORK (3)

这只创建了一个轻量级的令牌-完美的认证检查。(其他类型可用于构建交互式会话等)

我的简单功能

 private bool IsValidActiveDirectoryUser(string activeDirectoryServerDomain, string username, string password)
    {
        try
        {
            DirectoryEntry de = new DirectoryEntry("LDAP://" + activeDirectoryServerDomain, username + "@" + activeDirectoryServerDomain, password, AuthenticationTypes.Secure);
            DirectorySearcher ds = new DirectorySearcher(de);
            ds.FindOne();
            return true;
        }
        catch //(Exception ex)
        {
            return false;
        }
    }