对我来说，这两个下面的工作，确保你的域名是LDAP://在开始

//"LDAP://" + domainName
private void btnValidate_Click(object sender, RoutedEventArgs e)
{
    try
    {
        DirectoryEntry de = new DirectoryEntry(txtDomainName.Text, txtUsername.Text, txtPassword.Text);
        DirectorySearcher dsearch = new DirectorySearcher(de);
        SearchResult results = null;

        results = dsearch.FindOne();

        MessageBox.Show("Validation Success.");
    }
    catch (LdapException ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
    catch (Exception ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
}

private void btnValidate2_Click(object sender, RoutedEventArgs e)
{
    try
    {
        LdapConnection lcon = new LdapConnection(new LdapDirectoryIdentifier((string)null, false, false));
        NetworkCredential nc = new NetworkCredential(txtUsername.Text,
                               txtPassword.Text, txtDomainName.Text);
        lcon.Credential = nc;
        lcon.AuthType = AuthType.Negotiate;
        lcon.Bind(nc);

        MessageBox.Show("Validation Success.");
    }
    catch (LdapException ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
    catch (Exception ex)
    {
        MessageBox.Show($"Validation Failure. {ex.GetBaseException().Message}");
    }
}

可能最简单的方法是PInvoke LogonUser Win32 api。

http://www.pinvoke.net/default.aspx/advapi32/LogonUser.html

MSDN参考在这里…

http://msdn.microsoft.com/en-us/library/aa378184.aspx

绝对要使用登录类型

LOGON32_LOGON_NETWORK (3)

这只创建了一个轻量级的令牌-完美的认证检查。(其他类型可用于构建交互式会话等)

试试这段代码 (注意:报告不能在windows server 2000上工作)

#region NTLogonUser
#region Direct OS LogonUser Code
[DllImport( "advapi32.dll")]
private static extern bool LogonUser(String lpszUsername, 
    String lpszDomain, String lpszPassword, int dwLogonType, 
    int dwLogonProvider, out int phToken);

[DllImport("Kernel32.dll")]
private static extern int GetLastError();

public static bool LogOnXP(String sDomain, String sUser, String sPassword)
{
   int token1, ret;
   int attmpts = 0;

   bool LoggedOn = false;

   while (!LoggedOn && attmpts < 2)
   {
      LoggedOn= LogonUser(sUser, sDomain, sPassword, 3, 0, out token1);
      if (LoggedOn) return (true);
      else
      {
         switch (ret = GetLastError())
         {
            case (126): ; 
               if (attmpts++ > 2)
                  throw new LogonException(
                      "Specified module could not be found. error code: " + 
                      ret.ToString());
               break;

            case (1314): 
               throw new LogonException(
                  "Specified module could not be found. error code: " + 
                      ret.ToString());

            case (1326): 
               // edited out based on comment
               //  throw new LogonException(
               //   "Unknown user name or bad password.");
            return false;

            default: 
               throw new LogonException(
                  "Unexpected Logon Failure. Contact Administrator");
              }
          }
       }
   return(false);
}
#endregion Direct Logon Code
#endregion NTLogonUser

除非你需要为“LogonException”创建自己的自定义异常

Windows身份验证失败的原因有很多:用户名或密码不正确、帐户被锁定、密码过期等等。为了区分这些错误，通过P/Invoke调用LogonUser API函数，如果函数返回false，检查错误代码:

using System;
using System.ComponentModel;
using System.Runtime.InteropServices;

using Microsoft.Win32.SafeHandles;

public static class Win32Authentication
{
    private class SafeTokenHandle : SafeHandleZeroOrMinusOneIsInvalid
    {
        private SafeTokenHandle() // called by P/Invoke
            : base(true)
        {
        }

        protected override bool ReleaseHandle()
        {
            return CloseHandle(this.handle);
        }
    }

    private enum LogonType : uint
    {
        Network = 3, // LOGON32_LOGON_NETWORK
    }

    private enum LogonProvider : uint
    {
        WinNT50 = 3, // LOGON32_PROVIDER_WINNT50
    }

    [DllImport("kernel32.dll", SetLastError = true)]
    private static extern bool CloseHandle(IntPtr handle);

    [DllImport("advapi32.dll", SetLastError = true)]
    private static extern bool LogonUser(
        string userName, string domain, string password,
        LogonType logonType, LogonProvider logonProvider,
        out SafeTokenHandle token);

    public static void AuthenticateUser(string userName, string password)
    {
        string domain = null;
        string[] parts = userName.Split('\\');
        if (parts.Length == 2)
        {
            domain = parts[0];
            userName = parts[1];
        }

        SafeTokenHandle token;
        if (LogonUser(userName, domain, password, LogonType.Network, LogonProvider.WinNT50, out token))
            token.Dispose();
        else
            throw new Win32Exception(); // calls Marshal.GetLastWin32Error()
    }
}

示例用法:

try
{
    Win32Authentication.AuthenticateUser("EXAMPLE\\user", "P@ssw0rd");
    // Or: Win32Authentication.AuthenticateUser("user@example.com", "P@ssw0rd");
}
catch (Win32Exception ex)
{
    switch (ex.NativeErrorCode)
    {
        case 1326: // ERROR_LOGON_FAILURE (incorrect user name or password)
            // ...
        case 1327: // ERROR_ACCOUNT_RESTRICTION
            // ...
        case 1330: // ERROR_PASSWORD_EXPIRED
            // ...
        case 1331: // ERROR_ACCOUNT_DISABLED
            // ...
        case 1907: // ERROR_PASSWORD_MUST_CHANGE
            // ...
        case 1909: // ERROR_ACCOUNT_LOCKED_OUT
            // ...
        default: // Other
            break;
    }
}

注意:LogonUser需要与您验证的域建立信任关系。

我的简单功能

 private bool IsValidActiveDirectoryUser(string activeDirectoryServerDomain, string username, string password)
    {
        try
        {
            DirectoryEntry de = new DirectoryEntry("LDAP://" + activeDirectoryServerDomain, username + "@" + activeDirectoryServerDomain, password, AuthenticationTypes.Secure);
            DirectorySearcher ds = new DirectorySearcher(de);
            ds.FindOne();
            return true;
        }
        catch //(Exception ex)
        {
            return false;
        }
    }

另一个.NET调用用于快速验证LDAP凭据:

using System.DirectoryServices;

using(var DE = new DirectoryEntry(path, username, password)
{
    try
    {
        DE.RefreshCache(); // This will force credentials validation
    }
    catch (COMException ex)
    {
        // Validation failed - handle how you want
    }
}