select t.relname as table_name, 
       i.relname as index_name, 
       array_position(ix.indkey,a.attnum) pos, 
       a.attname as column_name
from pg_class t
join pg_index ix on t.oid = ix.indrelid
join pg_class i on i.oid = ix.indexrelid
join pg_attribute a on a.attrelid = t.oid and a.attnum = ANY(ix.indkey)
where t.relkind = 'r'
and t.relname like 'orders'
order by t.relname, i.relname, array_position(ix.indkey,a.attnum)

\d table_name显示了来自psql的这些信息，但是如果你想使用SQL从数据库中获取这些信息，那么可以看看从PostgreSQL中提取META信息。

我在我的实用程序中使用这些信息来报告来自db schema的一些信息，以比较测试和生产环境中的PostgreSQL数据库。

类似于接受的答案，但有左连接pg_attribute作为正常连接或查询pg_attribute不给出索引，如: 为用户创建唯一索引unique_user_name_index (lower(name))

select 
    row_number() over (order by c.relname),
    c.relname as index, 
    t.relname as table, 
    array_to_string(array_agg(a.attname), ', ') as column_names 
from pg_class c
join pg_index i on c.oid = i.indexrelid and c.relkind='i' and c.relname not like 'pg_%' 
join pg_class t on t.oid = i.indrelid
left join pg_attribute a on a.attrelid = t.oid and a.attnum = ANY(i.indkey) 
group by t.relname, c.relname order by c.relname;

创建一些测试数据…

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c),constraint uk_test3ab unique (a, b));

列出索引的索引和列:

select
    t.relname as table_name,
    i.relname as index_name,
    a.attname as column_name
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
order by
    t.relname,
    i.relname;

 table_name | index_name | column_name
------------+------------+-------------
 test       | pk_test    | a
 test       | pk_test    | b
 test2      | uk_test2   | b
 test2      | uk_test2   | c
 test3      | uk_test3ab | a
 test3      | uk_test3ab | b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

卷起列名:

select
    t.relname as table_name,
    i.relname as index_name,
    array_to_string(array_agg(a.attname), ', ') as column_names
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
group by
    t.relname,
    i.relname
order by
    t.relname,
    i.relname;

 table_name | index_name | column_names
------------+------------+--------------
 test       | pk_test    | a, b
 test2      | uk_test2   | b, c
 test3      | uk_test3ab | a, b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

原始信息在pg_index中。

请尝试下面的查询以深入到所需的索引

查询如下-我亲自尝试过，并经常使用它。

SELECT n.nspname as "Schema",
  c.relname as "Name",
  CASE c.relkind WHEN 'r' THEN 'table' WHEN 'v' THEN 'view' WHEN 'i' 
THEN 'index' WHEN 'S' THEN 'sequence' WHEN 's' THEN 'special' END as "Type",
  u.usename as "Owner",
 c2.relname as "Table"
FROM pg_catalog.pg_class c
     JOIN pg_catalog.pg_index i ON i.indexrelid = c.oid
     JOIN pg_catalog.pg_class c2 ON i.indrelid = c2.oid
     LEFT JOIN pg_catalog.pg_user u ON u.usesysid = c.relowner
     LEFT JOIN pg_catalog.pg_namespace n ON n.oid = c.relnamespace
WHERE c.relkind IN ('i','')
      AND n.nspname NOT IN ('pg_catalog', 'pg_toast')
      AND pg_catalog.pg_table_is_visible(c.oid)
      AND c2.relname like '%agg_transaction%' --table name
      AND nspname = 'edjus' -- schema name 
ORDER BY 1,2;