创建一些测试数据…

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c),constraint uk_test3ab unique (a, b));

列出索引的索引和列:

select
    t.relname as table_name,
    i.relname as index_name,
    a.attname as column_name
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
order by
    t.relname,
    i.relname;

 table_name | index_name | column_name
------------+------------+-------------
 test       | pk_test    | a
 test       | pk_test    | b
 test2      | uk_test2   | b
 test2      | uk_test2   | c
 test3      | uk_test3ab | a
 test3      | uk_test3ab | b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

卷起列名:

select
    t.relname as table_name,
    i.relname as index_name,
    array_to_string(array_agg(a.attname), ', ') as column_names
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
group by
    t.relname,
    i.relname
order by
    t.relname,
    i.relname;

 table_name | index_name | column_names
------------+------------+--------------
 test       | pk_test    | a, b
 test2      | uk_test2   | b, c
 test3      | uk_test3ab | a, b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

@cope360接受的答案很好，但我想要一些更像Oracle的DBA_IND_COLUMNS, ALL_IND_COLUMNS和USER_IND_COLUMNS(例如，报告表/索引模式和索引在多列索引中的位置)，所以我把接受的答案改编成这样:

with
 ind_cols as (
select
    n.nspname as schema_name,
    t.relname as table_name,
    i.relname as index_name,
    a.attname as column_name,
    1 + array_position(ix.indkey, a.attnum) as column_position
from
     pg_catalog.pg_class t
join pg_catalog.pg_attribute a on t.oid    =      a.attrelid 
join pg_catalog.pg_index ix    on t.oid    =     ix.indrelid
join pg_catalog.pg_class i     on a.attnum = any(ix.indkey)
                              and i.oid    =     ix.indexrelid
join pg_catalog.pg_namespace n on n.oid    =      t.relnamespace
where t.relkind = 'r'
order by
    t.relname,
    i.relname,
    array_position(ix.indkey, a.attnum)
)
select * 
from ind_cols
where schema_name = 'test'
  and table_name  = 'indextest'
order by schema_name, table_name
;

这将给出如下输出:

 schema_name | table_name | index_name | column_name | column_position 
-------------+------------+------------+-------------+-----------------
 test        | indextest  | testind1   | singleindex |               1
 test        | indextest  | testind2   | firstoftwo  |               1
 test        | indextest  | testind2   | secondoftwo |               2
(3 rows)

该命令还显示了表变量、索引和约束的视图

=# \d table_name;

例子:

testannie=# \d dv.l_customer_account;

类似于接受的答案，但有左连接pg_attribute作为正常连接或查询pg_attribute不给出索引，如: 为用户创建唯一索引unique_user_name_index (lower(name))

select 
    row_number() over (order by c.relname),
    c.relname as index, 
    t.relname as table, 
    array_to_string(array_agg(a.attname), ', ') as column_names 
from pg_class c
join pg_index i on c.oid = i.indexrelid and c.relkind='i' and c.relname not like 'pg_%' 
join pg_class t on t.oid = i.indrelid
left join pg_attribute a on a.attrelid = t.oid and a.attnum = ANY(i.indkey) 
group by t.relname, c.relname order by c.relname;

\d table_name显示了来自psql的这些信息，但是如果你想使用SQL从数据库中获取这些信息，那么可以看看从PostgreSQL中提取META信息。

我在我的实用程序中使用这些信息来报告来自db schema的一些信息，以比较测试和生产环境中的PostgreSQL数据库。

@cope360的精彩回答，转换为使用连接语法。

select t.relname as table_name
     , i.relname as index_name
     , array_to_string(array_agg(a.attname), ', ') as column_names
from pg_class t
join pg_index ix
on t.oid = ix.indrelid
join pg_class i
on i.oid = ix.indexrelid
join pg_attribute a
on a.attrelid = t.oid
and a.attnum = ANY(ix.indkey)
where t.relkind = 'r'
and t.relname like 'test%'
group by t.relname
       , i.relname
order by t.relname
       , i.relname
;