创建一些测试数据…

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c),constraint uk_test3ab unique (a, b));

列出索引的索引和列:

select
    t.relname as table_name,
    i.relname as index_name,
    a.attname as column_name
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
order by
    t.relname,
    i.relname;

 table_name | index_name | column_name
------------+------------+-------------
 test       | pk_test    | a
 test       | pk_test    | b
 test2      | uk_test2   | b
 test2      | uk_test2   | c
 test3      | uk_test3ab | a
 test3      | uk_test3ab | b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

卷起列名:

select
    t.relname as table_name,
    i.relname as index_name,
    array_to_string(array_agg(a.attname), ', ') as column_names
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname like 'test%'
group by
    t.relname,
    i.relname
order by
    t.relname,
    i.relname;

 table_name | index_name | column_names
------------+------------+--------------
 test       | pk_test    | a, b
 test2      | uk_test2   | b, c
 test3      | uk_test3ab | a, b
 test3      | uk_test3b  | b
 test3      | uk_test3c  | c

该命令还显示了表变量、索引和约束的视图

=# \d table_name;

例子:

testannie=# \d dv.l_customer_account;

在处理索引时，索引中构造列的顺序与列本身同样重要。

下面的查询以排序的方式列出给定表的所有索引及其所有列。

SELECT
  table_name,
  index_name,
  string_agg(column_name, ',')
FROM (
       SELECT
         t.relname AS table_name,
         i.relname AS index_name,
         a.attname AS column_name,
         (SELECT i
          FROM (SELECT
                  *,
                  row_number()
                  OVER () i
                FROM unnest(indkey) WITH ORDINALITY AS a(v)) a
          WHERE v = attnum)
       FROM
         pg_class t,
         pg_class i,
         pg_index ix,
         pg_attribute a
       WHERE
         t.oid = ix.indrelid
         AND i.oid = ix.indexrelid
         AND a.attrelid = t.oid
         AND a.attnum = ANY (ix.indkey)
         AND t.relkind = 'r'
         AND t.relname LIKE 'tablename'
       ORDER BY table_name, index_name, i
     ) raw
GROUP BY table_name, index_name

如果你想保持索引中的列顺序，这里有一个(非常丑陋的)方法:

select table_name,
    index_name,
    array_agg(column_name)
from (
    select
        t.relname as table_name,
        i.relname as index_name,
        a.attname as column_name,
        unnest(ix.indkey) as unn,
        a.attnum
    from
        pg_class t,
        pg_class i,
        pg_index ix,
        pg_attribute a
    where
        t.oid = ix.indrelid
        and i.oid = ix.indexrelid
        and a.attrelid = t.oid
        and a.attnum = ANY(ix.indkey)
        and t.relkind = 'r'
        and t.relnamespace = <oid of the schema you're interested in>
    order by
        t.relname,
        i.relname,
        generate_subscripts(ix.indkey,1)) sb
where unn = attnum
group by table_name, index_name

列顺序存储在pg_index中。indkey列，我是根据这个数组的下标排序的。

类似于接受的答案，但有左连接pg_attribute作为正常连接或查询pg_attribute不给出索引，如: 为用户创建唯一索引unique_user_name_index (lower(name))

select 
    row_number() over (order by c.relname),
    c.relname as index, 
    t.relname as table, 
    array_to_string(array_agg(a.attname), ', ') as column_names 
from pg_class c
join pg_index i on c.oid = i.indexrelid and c.relkind='i' and c.relname not like 'pg_%' 
join pg_class t on t.oid = i.indrelid
left join pg_attribute a on a.attrelid = t.oid and a.attnum = ANY(i.indkey) 
group by t.relname, c.relname order by c.relname;

原始信息在pg_index中。