只需要执行:\d table_name

但是我不确定你说没有列的信息是什么意思。

例如:

# \d pg_class
       Table "pg_catalog.pg_class"
     Column      |   Type    | Modifiers
-----------------+-----------+-----------
 relname         | name      | not null
 relnamespace    | oid       | not null
 reltype         | oid       | not null
 reloftype       | oid       | not null
 relowner        | oid       | not null
 relam           | oid       | not null
 relfilenode     | oid       | not null
 reltablespace   | oid       | not null
 relpages        | integer   | not null
 reltuples       | real      | not null
 reltoastrelid   | oid       | not null
 reltoastidxid   | oid       | not null
 relhasindex     | boolean   | not null
 relisshared     | boolean   | not null
 relistemp       | boolean   | not null
 relkind         | "char"    | not null
 relnatts        | smallint  | not null
 relchecks       | smallint  | not null
 relhasoids      | boolean   | not null
 relhaspkey      | boolean   | not null
 relhasexclusion | boolean   | not null
 relhasrules     | boolean   | not null
 relhastriggers  | boolean   | not null
 relhassubclass  | boolean   | not null
 relfrozenxid    | xid       | not null
 relacl          | aclitem[] |
 reloptions      | text[]    |
Indexes:
    "pg_class_oid_index" UNIQUE, btree (oid)
    "pg_class_relname_nsp_index" UNIQUE, btree (relname, relnamespace)

它清楚地显示给定索引在该表上的列。

稍微修改一下@cope360的回答:

create table test (a int, b int, c int, constraint pk_test primary key(c, a, b));
select i.relname as index_name,
       ix.indisunique as is_unique,
       a.attname as column_name,
from pg_class c
       inner join pg_index ix on c.oid=ix.indrelid
       inner join pg_class i on ix.indexrelid=i.oid
       inner join pg_attribute a on a.attrelid=c.oid and a.attnum=any(ix.indkey)
where c.oid='public.test'::regclass::oid
order by array_position(ix.indkey, a.attnum) asc;

这将显示索引列的正确顺序:

index_name      is_unique  column_name
pk_test         true       c
pk_test         true       a
pk_test         true       b

一些样本数据…

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c), constraint uk_test3ab unique (a, b));

使用pg_get_indexdef函数:

select pg_get_indexdef(indexrelid) from pg_index where indrelid = 'test'::regclass;

                    pg_get_indexdef
--------------------------------------------------------
 CREATE UNIQUE INDEX pk_test ON test USING btree (a, b)
(1 row)


select pg_get_indexdef(indexrelid) from pg_index where indrelid = 'test2'::regclass;
                     pg_get_indexdef
----------------------------------------------------------
 CREATE UNIQUE INDEX uk_test2 ON test2 USING btree (b, c)
(1 row)


select pg_get_indexdef(indexrelid) from pg_index where indrelid ='test3'::regclass;
                      pg_get_indexdef
------------------------------------------------------------
 CREATE UNIQUE INDEX uk_test3b ON test3 USING btree (b)
 CREATE UNIQUE INDEX uk_test3c ON test3 USING btree (c)
 CREATE UNIQUE INDEX uk_test3ab ON test3 USING btree (a, b)
(3 rows)

下面是一个包装cope360答案的函数:

CREATE OR REPLACE FUNCTION getIndices(_table_name varchar)
  RETURNS TABLE(table_name varchar, index_name varchar, column_name varchar) AS $$
  BEGIN
    RETURN QUERY
    select
    t.relname::varchar as table_name,
    i.relname::varchar as index_name,
    a.attname::varchar as column_name
from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    and t.relname = _table_name
order by
    t.relname,
    i.relname;
  END;
  $$ LANGUAGE plpgsql;

用法:

select * from getIndices('<my_table>')

select t.relname as table_name, 
       i.relname as index_name, 
       array_position(ix.indkey,a.attnum) pos, 
       a.attname as column_name
from pg_class t
join pg_index ix on t.oid = ix.indrelid
join pg_class i on i.oid = ix.indexrelid
join pg_attribute a on a.attrelid = t.oid and a.attnum = ANY(ix.indkey)
where t.relkind = 'r'
and t.relname like 'orders'
order by t.relname, i.relname, array_position(ix.indkey,a.attnum)

原始信息在pg_index中。