稍微修改一下@cope360的回答:

create table test (a int, b int, c int, constraint pk_test primary key(c, a, b));
select i.relname as index_name,
       ix.indisunique as is_unique,
       a.attname as column_name,
from pg_class c
       inner join pg_index ix on c.oid=ix.indrelid
       inner join pg_class i on ix.indexrelid=i.oid
       inner join pg_attribute a on a.attrelid=c.oid and a.attnum=any(ix.indkey)
where c.oid='public.test'::regclass::oid
order by array_position(ix.indkey, a.attnum) asc;

这将显示索引列的正确顺序:

index_name      is_unique  column_name
pk_test         true       c
pk_test         true       a
pk_test         true       b

原始信息在pg_index中。

只需要执行:\d table_name

但是我不确定你说没有列的信息是什么意思。

例如:

# \d pg_class
       Table "pg_catalog.pg_class"
     Column      |   Type    | Modifiers
-----------------+-----------+-----------
 relname         | name      | not null
 relnamespace    | oid       | not null
 reltype         | oid       | not null
 reloftype       | oid       | not null
 relowner        | oid       | not null
 relam           | oid       | not null
 relfilenode     | oid       | not null
 reltablespace   | oid       | not null
 relpages        | integer   | not null
 reltuples       | real      | not null
 reltoastrelid   | oid       | not null
 reltoastidxid   | oid       | not null
 relhasindex     | boolean   | not null
 relisshared     | boolean   | not null
 relistemp       | boolean   | not null
 relkind         | "char"    | not null
 relnatts        | smallint  | not null
 relchecks       | smallint  | not null
 relhasoids      | boolean   | not null
 relhaspkey      | boolean   | not null
 relhasexclusion | boolean   | not null
 relhasrules     | boolean   | not null
 relhastriggers  | boolean   | not null
 relhassubclass  | boolean   | not null
 relfrozenxid    | xid       | not null
 relacl          | aclitem[] |
 reloptions      | text[]    |
Indexes:
    "pg_class_oid_index" UNIQUE, btree (oid)
    "pg_class_relname_nsp_index" UNIQUE, btree (relname, relnamespace)

它清楚地显示给定索引在该表上的列。

一些样本数据…

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c), constraint uk_test3ab unique (a, b));

使用pg_get_indexdef函数:

select pg_get_indexdef(indexrelid) from pg_index where indrelid = 'test'::regclass;

                    pg_get_indexdef
--------------------------------------------------------
 CREATE UNIQUE INDEX pk_test ON test USING btree (a, b)
(1 row)


select pg_get_indexdef(indexrelid) from pg_index where indrelid = 'test2'::regclass;
                     pg_get_indexdef
----------------------------------------------------------
 CREATE UNIQUE INDEX uk_test2 ON test2 USING btree (b, c)
(1 row)


select pg_get_indexdef(indexrelid) from pg_index where indrelid ='test3'::regclass;
                      pg_get_indexdef
------------------------------------------------------------
 CREATE UNIQUE INDEX uk_test3b ON test3 USING btree (b)
 CREATE UNIQUE INDEX uk_test3c ON test3 USING btree (c)
 CREATE UNIQUE INDEX uk_test3ab ON test3 USING btree (a, b)
(3 rows)

延伸到@Cope360的好答案。要获取某个表(如果它们是相同的表名但不同的模式)，只需使用表OID。

select
     t.relname as table_name
    ,i.relname as index_name
    ,a.attname as column_name
    ,a.attrelid tableid

from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    -- and t.relname like 'tbassettype'
    and a.attrelid = '"dbLegal".tbassettype'::regclass
order by
    t.relname,
    i.relname;

解释:我有表名'tbassettype'在两个模式'dbAsset'和'dbLegal'。要在dbLegal上只获取表，只需让a.attrelid =它的OID。

请尝试下面的查询以深入到所需的索引

查询如下-我亲自尝试过，并经常使用它。

SELECT n.nspname as "Schema",
  c.relname as "Name",
  CASE c.relkind WHEN 'r' THEN 'table' WHEN 'v' THEN 'view' WHEN 'i' 
THEN 'index' WHEN 'S' THEN 'sequence' WHEN 's' THEN 'special' END as "Type",
  u.usename as "Owner",
 c2.relname as "Table"
FROM pg_catalog.pg_class c
     JOIN pg_catalog.pg_index i ON i.indexrelid = c.oid
     JOIN pg_catalog.pg_class c2 ON i.indrelid = c2.oid
     LEFT JOIN pg_catalog.pg_user u ON u.usesysid = c.relowner
     LEFT JOIN pg_catalog.pg_namespace n ON n.oid = c.relnamespace
WHERE c.relkind IN ('i','')
      AND n.nspname NOT IN ('pg_catalog', 'pg_toast')
      AND pg_catalog.pg_table_is_visible(c.oid)
      AND c2.relname like '%agg_transaction%' --table name
      AND nspname = 'edjus' -- schema name 
ORDER BY 1,2;