受@sdfor注释的启发，这里有一个bash脚本可以完成这项工作

#!/bin/bash

printf "### Converting MySQL character set ###\n\n"

printf "Enter the encoding you want to set: "
read -r CHARSET

# Get the MySQL username
printf "Enter mysql username: "
read -r USERNAME

# Get the MySQL password
printf "Enter mysql password for user %s:" "$USERNAME"
read -rs PASSWORD

DBLIST=( mydatabase1 mydatabase2 )

printf "\n"


for DB in "${DBLIST[@]}"
do
(
    echo 'ALTER DATABASE `'"$DB"'` CHARACTER SET utf8 COLLATE `'"$CHARSET"'`;'
    mysql "$DB" -u"$USERNAME" -p"$PASSWORD" -e "SHOW TABLES" --batch --skip-column-names \
    | xargs -I{} echo 'ALTER TABLE `'{}'` CONVERT TO CHARACTER SET utf8 COLLATE `'"$CHARSET"'`;'
) \
| mysql "$DB" -u"$USERNAME" -p"$PASSWORD"

echo "$DB database done..."
done

echo "### DONE ###"
exit

使用ALTER DATABASE和ALTER TABLE命令。

ALTER DATABASE databasename CHARACTER SET utf8mb4 COLLATE utf8mb4_unicode_ci;
ALTER TABLE tablename CONVERT TO CHARACTER SET utf8mb4 COLLATE utf8mb4_unicode_ci;

或者如果你仍然使用MySQL 5.5.2或更早的版本，不支持4字节UTF-8，使用utf8而不是utf8mb4:

ALTER DATABASE databasename CHARACTER SET utf8 COLLATE utf8_unicode_ci;
ALTER TABLE tablename CONVERT TO CHARACTER SET utf8 COLLATE utf8_unicode_ci;

最安全的方法是先将列修改为二进制类型，然后使用所需的字符集将其修改回二进制类型。

每种列类型都有其各自的二进制类型，如下所示:

>二进制 文本=> BLOB 丁文字=> TINYBLOB 文本=> memblob LONGTEXT => LONGBLOB VARCHAR => VARBINARY

Eg.:

ALTER TABLE [TABLE_SCHEMA].[TABLE_NAME] MODIFY [COLUMN_NAME] VARBINARY;

ALTER TABLE [TABLE_SCHEMA].[TABLE_NAME] MODIFY [COLUMN_NAME] VARCHAR(140) CHARACTER SET utf8mb4;

我尝试了几个拉丁表，它保留了所有的变音符。

你可以为所有列提取这个查询:

SELECT
CONCAT('ALTER TABLE ', TABLE_SCHEMA,'.', TABLE_NAME,' MODIFY ', COLUMN_NAME,' VARBINARY;'),
CONCAT('ALTER TABLE ', TABLE_SCHEMA,'.', TABLE_NAME,' MODIFY ', COLUMN_NAME,' ', COLUMN_TYPE,' CHARACTER SET utf8mb4 COLLATE utf8mb4_general_ci;')
FROM information_schema.columns
WHERE TABLE_SCHEMA IN ('[TABLE_SCHEMA]')
AND COLUMN_TYPE LIKE 'varchar%'
AND (COLLATION_NAME IS NOT NULL AND COLLATION_NAME NOT LIKE 'utf%');

在所有列上执行此操作后，再对所有表执行此操作:

ALTER TABLE [TABLE_SCHEMA].[TABLE_NAME] CONVERT TO CHARACTER SET utf8mb4 COLLATE utf8mb4_general_ci;

要为你所有的表生成这个查询，使用下面的查询:

SELECT
CONCAT('ALTER TABLE ', TABLE_SCHEMA, '.', TABLE_NAME, ' CONVERT TO CHARACTER SET utf8mb4 COLLATE utf8mb4_general_ci;')
FROM INFORMATION_SCHEMA.TABLES
WHERE TABLE_COLLATION NOT LIKE 'utf8%'
and TABLE_SCHEMA in ('[TABLE_SCHEMA]');

现在你修改了所有的列和表，在数据库上做同样的事情:

ALTER DATABASE [DATA_BASE_NAME] CHARSET = utf8mb4 COLLATE = utf8mb4_general_ci;

在命令行shell上

如果你是一个命令行shell，你可以非常快地做到这一点。只需填写“dbname”:D

DB="dbname"
(
    echo 'ALTER DATABASE `'"$DB"'` CHARACTER SET utf8 COLLATE utf8_general_ci;'
    mysql "$DB" -e "SHOW TABLES" --batch --skip-column-names \
    | xargs -I{} echo 'ALTER TABLE `'{}'` CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;'
) \
| mysql "$DB"

简单复制/粘贴的一行程序

DB="dbname"; ( echo 'ALTER DATABASE `'"$DB"'` CHARACTER SET utf8 COLLATE utf8_general_ci;'; mysql "$DB" -e "SHOW TABLES" --batch --skip-column-names | xargs -I{} echo 'ALTER TABLE `'{}'` CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;' ) | mysql "$DB"

如果数据不在相同的字符集中，您可以考虑http://dev.mysql.com/doc/refman/5.0/en/charset-conversion.html中的这个片段

如果列具有非二进制数据类型(CHAR、VARCHAR、TEXT)，则其 内容应该在列字符集中编码，而不是其他字符集 字符集。如果内容用不同的字符编码 设置后，您可以先将列转换为使用二进制数据类型，然后 然后转换到具有所需字符集的非二进制列。

这里有一个例子:

 ALTER TABLE t1 CHANGE c1 c1 BLOB;
 ALTER TABLE t1 CHANGE c1 c1 VARCHAR(100) CHARACTER SET utf8;

确保选择正确的排序规则，否则可能会得到唯一的键冲突。如。 Éleanore和Eleanore在某些排序中可能被认为是相同的。

旁白:

我曾遇到过这样的情况，电子邮件中的某些字符“坏了”，尽管它们在数据库中以UTF-8格式存储。如果您使用utf8数据发送电子邮件，您可能还需要将电子邮件转换为utf8发送。

在phpailer中，只需更新这一行:public $CharSet = 'utf-8';

在继续之前，请确保您:已完成完全数据库备份!

步骤1:数据库级别更改

标识数据库的排序规则和字符集 选择default_character_set_name, default_collation_name from information_schema。图式年代 WHERE schema_name = 'your_database_name' 和 (DEFAULT_CHARACTER_SET_NAME != 'utf8' 或 DEFAULT_COLLATION_NAME不像'utf8%'); 修复数据库的排序规则 ALTER DATABASE DATABASE utf8 COLLATE utf8_unicode_ci;

步骤2:表级别更改

Identifying Database Tables with the incorrect character set or collation SELECT CONCAT( 'ALTER TABLE ', table_name, ' CHARACTER SET utf8 COLLATE utf8_general_ci; ', 'ALTER TABLE ', table_name, ' CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci; ') FROM information_schema.TABLES AS T, information_schema.`COLLATION_CHARACTER_SET_APPLICABILITY` AS C WHERE C.collation_name = T.table_collation AND T.table_schema = 'your_database_name' AND (C.CHARACTER_SET_NAME != 'utf8' OR C.COLLATION_NAME not like 'utf8%') Adjusting table columns' collation and character set

捕获上层sql输出并运行它。(如后)

ALTER TABLE rma CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_history CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_history CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_products CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_products CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_report_period CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_report_period CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_reservation CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_reservation CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_supplier_return CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_supplier_return CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_supplier_return_history CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_supplier_return_history CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci;  
ALTER TABLE rma_supplier_return_product CHARACTER SET utf8 COLLATE utf8_general_ci;ALTER TABLE rma_supplier_return_product CONVERT TO CHARACTER SET utf8 COLLATE utf8_general_ci; 

参考网址:https://confluence.atlassian.com/display/CONFKB/How+to+Fix+the+Collation+and+Character+Set+of+a+MySQL+Database