你可以像这样使用匿名类:

comboBox.DisplayMember = "Text";
comboBox.ValueMember = "Value";

comboBox.Items.Add(new { Text = "report A", Value = "reportA" });
comboBox.Items.Add(new { Text = "report B", Value = "reportB" });
comboBox.Items.Add(new { Text = "report C", Value = "reportC" });
comboBox.Items.Add(new { Text = "report D", Value = "reportD" });
comboBox.Items.Add(new { Text = "report E", Value = "reportE" });

更新:虽然上面的代码将正确显示在组合框中，你将不能使用组合框的SelectedValue或SelectedText属性。为了能够使用这些，绑定组合框如下:

comboBox.DisplayMember = "Text";
comboBox.ValueMember = "Value";

var items = new[] { 
    new { Text = "report A", Value = "reportA" }, 
    new { Text = "report B", Value = "reportB" }, 
    new { Text = "report C", Value = "reportC" },
    new { Text = "report D", Value = "reportD" },
    new { Text = "report E", Value = "reportE" }
};

comboBox.DataSource = items;

类创造:

namespace WindowsFormsApplication1
{
    class select
    {
        public string Text { get; set; }
        public string Value { get; set; }
    }
}

Form1代码:

namespace WindowsFormsApplication1
{
    public partial class Form1 : Form
    {
        public Form1()
        {
            InitializeComponent();
            List<select> sl = new List<select>();
            sl.Add(new select() { Text = "", Value = "" });
            sl.Add(new select() { Text = "AAA", Value = "aa" });
            sl.Add(new select() { Text = "BBB", Value = "bb" });
            comboBox1.DataSource = sl;
            comboBox1.DisplayMember = "Text";
        }

        private void comboBox1_SelectedIndexChanged(object sender, EventArgs e)
        {

            select sl1 = comboBox1.SelectedItem as select;
            t1.Text = Convert.ToString(sl1.Value);

        }

    }
}

不知道这是否适用于原始帖子中给出的情况(不要介意这是两年后的事实)，但这个例子对我来说是适用的:

Hashtable htImageTypes = new Hashtable();
htImageTypes.Add("JPEG", "*.jpg");
htImageTypes.Add("GIF", "*.gif");
htImageTypes.Add("BMP", "*.bmp");

foreach (DictionaryEntry ImageType in htImageTypes)
{
    cmbImageType.Items.Add(ImageType);
}
cmbImageType.DisplayMember = "key";
cmbImageType.ValueMember = "value";

要读取回值，必须将SelectedItem属性转换为DictionaryEntry对象，然后可以计算该对象的Key和value属性。例如:

DictionaryEntry deImgType = (DictionaryEntry)cmbImageType.SelectedItem;
MessageBox.Show(deImgType.Key + ": " + deImgType.Value);

// Bind combobox to dictionary
Dictionary<string, string>test = new Dictionary<string, string>();
        test.Add("1", "dfdfdf");
        test.Add("2", "dfdfdf");
        test.Add("3", "dfdfdf");
        comboBox1.DataSource = new BindingSource(test, null);
        comboBox1.DisplayMember = "Value";
        comboBox1.ValueMember = "Key";

// Get combobox selection (in handler)
string value = ((KeyValuePair<string, string>)comboBox1.SelectedItem).Value;

你可以使用泛型类型:

public class ComboBoxItem<T>
{
    private string Text { get; set; }
    public T Value { get; set; }

    public override string ToString()
    {
        return Text;
    }

    public ComboBoxItem(string text, T value)
    {
        Text = text;
        Value = value;
    }
}

使用简单int-Type的示例:

private void Fill(ComboBox comboBox)
    {
        comboBox.Items.Clear();
        object[] list =
            {
                new ComboBoxItem<int>("Architekt", 1),
                new ComboBoxItem<int>("Bauträger", 2),
                new ComboBoxItem<int>("Fachbetrieb/Installateur", 3),
                new ComboBoxItem<int>("GC-Haus", 5),
                new ComboBoxItem<int>("Ingenieur-/Planungsbüro", 9),
                new ComboBoxItem<int>("Wowi", 17),
                new ComboBoxItem<int>("Endverbraucher", 19)
            };

        comboBox.Items.AddRange(list);
    }

我喜欢fab的答案，但不想为我的情况使用字典，所以我替换了一个元组列表。

// set up your data
public static List<Tuple<string, string>> List = new List<Tuple<string, string>>
{
  new Tuple<string, string>("Item1", "Item2")
}

// bind to the combo box
comboBox.DataSource = new BindingSource(List, null);
comboBox.ValueMember = "Item1";
comboBox.DisplayMember = "Item2";

//Get selected value
string value = ((Tuple<string, string>)queryList.SelectedItem).Item1;