您应该在运行时使用动态对象来解析组合框项。

comboBox.DisplayMember = "Text";
comboBox.ValueMember = "Value";

comboBox.Items.Add(new { Text = "Text", Value = "Value" });

(comboBox.SelectedItem as dynamic).Value

using (SqlConnection con = new SqlConnection(insertClass.dbPath))
{
    con.Open();
    using (SqlDataAdapter sda = new SqlDataAdapter(
    "SELECT CategoryID, Category FROM Category WHERE Status='Active' ", con))
    {
        //Fill the DataTable with records from Table.
        DataTable dt = new DataTable();
        sda.Fill(dt);
        //Insert the Default Item to DataTable.
        DataRow row = dt.NewRow();
        row[0] = 0;
        row[1] = "(Selecione)";
        dt.Rows.InsertAt(row, 0);
        //Assign DataTable as DataSource.
        cboProductTypeName.DataSource = dt;
        cboProductTypeName.DisplayMember = "Category";
        cboProductTypeName.ValueMember = "CategoryID";
    }
}             
con.Close();

您可以使用字典对象，而不是创建自定义类来在组合框中添加文本和值。

在Dictionary对象中添加键和值:

Dictionary<string, string> comboSource = new Dictionary<string, string>();
comboSource.Add("1", "Sunday");
comboSource.Add("2", "Monday");

将源Dictionary对象绑定到Combobox:

comboBox1.DataSource = new BindingSource(comboSource, null);
comboBox1.DisplayMember = "Value";
comboBox1.ValueMember = "Key";

检索键和值:

string key = ((KeyValuePair<string,string>)comboBox1.SelectedItem).Key;
string value = ((KeyValuePair<string,string>)comboBox1.SelectedItem).Value;

完整来源:组合框文本和值

不知道这是否适用于原始帖子中给出的情况(不要介意这是两年后的事实)，但这个例子对我来说是适用的:

Hashtable htImageTypes = new Hashtable();
htImageTypes.Add("JPEG", "*.jpg");
htImageTypes.Add("GIF", "*.gif");
htImageTypes.Add("BMP", "*.bmp");

foreach (DictionaryEntry ImageType in htImageTypes)
{
    cmbImageType.Items.Add(ImageType);
}
cmbImageType.DisplayMember = "key";
cmbImageType.ValueMember = "value";

要读取回值，必须将SelectedItem属性转换为DictionaryEntry对象，然后可以计算该对象的Key和value属性。例如:

DictionaryEntry deImgType = (DictionaryEntry)cmbImageType.SelectedItem;
MessageBox.Show(deImgType.Key + ": " + deImgType.Value);

类创造:

namespace WindowsFormsApplication1
{
    class select
    {
        public string Text { get; set; }
        public string Value { get; set; }
    }
}

Form1代码:

namespace WindowsFormsApplication1
{
    public partial class Form1 : Form
    {
        public Form1()
        {
            InitializeComponent();
            List<select> sl = new List<select>();
            sl.Add(new select() { Text = "", Value = "" });
            sl.Add(new select() { Text = "AAA", Value = "aa" });
            sl.Add(new select() { Text = "BBB", Value = "bb" });
            comboBox1.DataSource = sl;
            comboBox1.DisplayMember = "Text";
        }

        private void comboBox1_SelectedIndexChanged(object sender, EventArgs e)
        {

            select sl1 = comboBox1.SelectedItem as select;
            t1.Text = Convert.ToString(sl1.Value);

        }

    }
}

这是一个非常简单的解决方案为windows窗体，如果所有需要的是最终值(字符串)。项目的名称将显示在组合框上，选择的值可以很容易地进行比较。

List<string> items = new List<string>();

// populate list with test strings
for (int i = 0; i < 100; i++)
            items.Add(i.ToString());

// set data source
testComboBox.DataSource = items;

并在事件处理程序上获取所选值的值(字符串)

string test = testComboBox.SelectedValue.ToString();