在Visual Studio项目属性(“Build”页面，如果我没记错的话)中有一个选项显示“生成序列化程序集”。尝试为生成[包含MyType的程序集]的项目打开该选项。

要序列化的自定义类:

[Serializable]
public class TestClass
{
    int x = 2;
    int y = 4;
    public TestClass(){}
    public TestClass(int x, int y)
    {
        this.x = x;
        this.y = y;
    }

    public int TestFunction()
    {
        return x + y;
    }
}

我已经附上了代码片段。也许这个能帮到你。

static void Main(string[] args)
{
    XmlSerializer xmlSerializer = new XmlSerializer(typeof(TestClass));

    MemoryStream memoryStream = new MemoryStream();
    XmlTextWriter xmlWriter = new XmlTextWriter(memoryStream, Encoding.UTF8);

    TestClass domain = new TestClass(10, 3);
    xmlSerializer.Serialize(xmlWriter, domain);
    memoryStream = (MemoryStream)xmlWriter.BaseStream;
    string xmlSerializedString = ConvertByteArray2Str(memoryStream.ToArray());

    TestClass xmlDomain = (TestClass)DeserializeObject(xmlSerializedString);

    Console.WriteLine(xmlDomain.TestFunction().ToString());
    Console.ReadLine();
}

另一方面，对编译错误进行故障排除是非常复杂的。这些问题在FileNotFoundException异常中显示，并显示如下信息:

File or assembly name abcdef.dll, or one of its dependencies, was not found. File name: "abcdef.dll"
   at System.Reflection.Assembly.nLoad( ... )
   at System.Reflection.Assembly.InternalLoad( ... )
   at System.Reflection.Assembly.Load(...)
   at System.CodeDom.Compiler.CompilerResults.get_CompiledAssembly() 

You may wonder what a file not found exception has to do with instantiating a serializer object, but remember: the constructor writes C# files and tries to compile them. The call stack of this exception provides some good information to support that suspicion. The exception occurred while the XmlSerializer attempted to load an assembly generated by CodeDOM calling the System.Reflection.Assembly.Load method. The exception does not provide an explanation as to why the assembly that the XmlSerializer was supposed to create was not present. In general, the assembly is not present because the compilation failed, which may happen because, under rare circumstances, the serialization attributes produce code that the C# compiler fails to compile.

请注意 当XmlSerializer在不能访问临时目录的帐户或安全环境下运行时，也会发生此错误。

来源: http://msdn.microsoft.com/en-us/library/aa302290.aspx

在Visual Studio项目属性(“Build”页面，如果我没记错的话)中有一个选项显示“生成序列化程序集”。尝试为生成[包含MyType的程序集]的项目打开该选项。

我得到了同样的错误，这是由于我试图反序列化的类型没有默认的无参数构造函数。我添加了一个构造函数，它开始工作了。

此异常也可以由名为BindingFailure的托管调试助手(MDA)捕获。

如果您的应用程序被设计为附带预构建序列化程序集，则此MDA非常有用。这样做是为了提高应用程序的性能。它允许我们确保预先构建的序列化程序集由构建过程正确构建，并由应用程序加载，而无需动态重新构建。

除了在这种情况下，它实际上没什么用，因为正如其他帖子所说，当绑定错误被Serializer构造函数捕获时，序列化程序集将在运行时重新构建。所以你可以把它关掉。