试试这个,

    private void button1_Click(object sender, EventArgs e)
    {
        try
        {
            MailMessage mail = new MailMessage();
            SmtpClient SmtpServer = new SmtpClient("smtp.gmail.com");

            mail.From = new MailAddress("your_email_address@gmail.com");
            mail.To.Add("to_address");
            mail.Subject = "Test Mail";
            mail.Body = "This is for testing SMTP mail from GMAIL";

            SmtpServer.Port = 587;
            SmtpServer.Credentials = new System.Net.NetworkCredential("username", "password");
            SmtpServer.EnableSsl = true;

            SmtpServer.Send(mail);
            MessageBox.Show("mail Send");
        }
        catch (Exception ex)
        {
            MessageBox.Show(ex.ToString());
        }
    }

为了避免Gmail的安全问题，你应该先从Gmail的设置中生成一个应用程序密码，即使你使用两步验证，你也可以使用这个密码而不是真实密码来发送电子邮件。

这是发送邮件的附件。简单而简短。

来源:http://coding-issues.blogspot.in/2012/11/sending-email-with-attachments-from-c.html

using System.Net;
using System.Net.Mail;

public void email_send()
{
    MailMessage mail = new MailMessage();
    SmtpClient SmtpServer = new SmtpClient("smtp.gmail.com");
    mail.From = new MailAddress("your mail@gmail.com");
    mail.To.Add("to_mail@gmail.com");
    mail.Subject = "Test Mail - 1";
    mail.Body = "mail with attachment";

    System.Net.Mail.Attachment attachment;
    attachment = new System.Net.Mail.Attachment("c:/textfile.txt");
    mail.Attachments.Add(attachment);

    SmtpServer.Port = 587;
    SmtpServer.Credentials = new System.Net.NetworkCredential("your mail@gmail.com", "your password");
    SmtpServer.EnableSsl = true;

    SmtpServer.Send(mail);

}

从另一个答案复制，上述方法工作，但gmail总是替换“从”和“回复”电子邮件与实际发送gmail帐户。然而，显然有一种方法:

http://karmic-development.blogspot.in/2013/10/send-email-from-aspnet-using-gmail-as.html

“3。在帐户选项卡，点击链接“添加另一个电子邮件地址你自己的”，然后验证它

或者可能是这个

更新3:读者德里克·贝内特说:“解决办法是进入你的gmail设置:账户，并“默认”一个gmail账户以外的账户。这将导致gmail用默认帐户的电子邮件地址重写From字段。”

下面是一个从web.config发送邮件和获取凭证的方法:

public static string SendEmail(string To, string Subject, string Msg, bool bodyHtml = false, bool test = false, Stream AttachmentStream = null, string AttachmentType = null, string AttachmentFileName = null)
{
    try
    {
        System.Net.Mail.MailMessage newMsg = new System.Net.Mail.MailMessage(System.Configuration.ConfigurationManager.AppSettings["mailCfg"], To, Subject, Msg);
        newMsg.BodyEncoding = System.Text.Encoding.UTF8;
        newMsg.HeadersEncoding = System.Text.Encoding.UTF8;
        newMsg.SubjectEncoding = System.Text.Encoding.UTF8;

        System.Net.Mail.SmtpClient smtpClient = new System.Net.Mail.SmtpClient();
        if (AttachmentStream != null && AttachmentType != null && AttachmentFileName != null)
        {
            System.Net.Mail.Attachment attachment = new System.Net.Mail.Attachment(AttachmentStream, AttachmentFileName);
            System.Net.Mime.ContentDisposition disposition = attachment.ContentDisposition;
            disposition.FileName = AttachmentFileName;
            disposition.DispositionType = System.Net.Mime.DispositionTypeNames.Attachment;

            newMsg.Attachments.Add(attachment);
        }
        if (test)
        {
            smtpClient.PickupDirectoryLocation = "C:\\TestEmail";
            smtpClient.DeliveryMethod = System.Net.Mail.SmtpDeliveryMethod.SpecifiedPickupDirectory;
        }
        else
        {
            //smtpClient.EnableSsl = true;
        }

        newMsg.IsBodyHtml = bodyHtml;
        smtpClient.Send(newMsg);
        return SENT_OK;
    }
    catch (Exception ex)
    {

        return "Error: " + ex.Message
             + "<br/><br/>Inner Exception: "
             + ex.InnerException;
    }

}

以及web.config中相应的部分:

<appSettings>
    <add key="mailCfg" value="yourmail@example.com"/>
</appSettings>
<system.net>
  <mailSettings>
    <smtp deliveryMethod="Network" from="yourmail@example.com">
      <network defaultCredentials="false" host="mail.exapmple.com" userName="yourmail@example.com" password="your_password" port="25"/>
    </smtp>
  </mailSettings>
</system.net>

我也遇到了同样的问题，但通过gmail的安全设置和允许不太安全的应用程序解决了。 Domenic & Donny的代码有效，但前提是你启用了该设置

如果您已登录(到谷歌)，您可以按照此链接并切换“打开”以“访问不太安全的应用程序”