你可以试试Mailkit。它为发送邮件提供了更好、更先进的功能。这里有一个例子

    MimeMessage message = new MimeMessage();
    message.From.Add(new MailboxAddress("FromName", "YOU_FROM_ADDRESS@gmail.com"));
    message.To.Add(new MailboxAddress("ToName", "YOU_TO_ADDRESS@gmail.com"));
    message.Subject = "MyEmailSubject";

    message.Body = new TextPart("plain")
    {
        Text = @"MyEmailBodyOnlyTextPart"
    };

    using (var client = new SmtpClient())
    {
        client.Connect("SERVER", 25); // 25 is port you can change accordingly

        // Note: since we don't have an OAuth2 token, disable
        // the XOAUTH2 authentication mechanism.
        client.AuthenticationMechanisms.Remove("XOAUTH2");

        // Note: only needed if the SMTP server requires authentication
        client.Authenticate("YOUR_USER_NAME", "YOUR_PASSWORD");

        client.Send(message);
        client.Disconnect(true);
    }

谷歌已经从我们的谷歌帐户中删除了不太安全的应用程序设置，这意味着我们不能再使用我们实际的谷歌密码从SMTP服务器发送电子邮件。我们需要使用Xoauth2并授权用户，或者在启用了2fa的帐户上创建一个应用程序密码。

一旦创建了应用程序密码，就可以用来代替你的标准gmail密码。

class Program
{
    private const string To = "test@test.com";
    private const string From = "test@test.com";
    
    private const string GoogleAppPassword = "XXXXXXXX";
    
    private const string Subject = "Test email";
    private const string Body = "<h1>Hello</h1>";
    
    
    static void Main(string[] args)
    {
        Console.WriteLine("Hello World!");
        
        var smtpClient = new SmtpClient("smtp.gmail.com")
        {
            Port = 587,
            Credentials = new NetworkCredential(From , GoogleAppPassword),
            EnableSsl = true,
        };
        var mailMessage = new MailMessage
        {
            From = new MailAddress(From),
            Subject = Subject,
            Body = Body,
            IsBodyHtml = true,
        };
        mailMessage.To.Add(To);

        smtpClient.Send(mailMessage);
    }
}

快速修复SMTP用户名和密码不接受错误

上面的答案不管用。必须设置DeliveryMethod = SmtpDeliveryMethod。网络，否则将返回“客户端未经过身份验证”错误。此外，暂停总是一个好主意。

修改后的代码:

using System.Net.Mail;
using System.Net;

var fromAddress = new MailAddress("from@gmail.com", "From Name");
var toAddress = new MailAddress("to@yahoo.com", "To Name");
const string fromPassword = "password";
const string subject = "test";
const string body = "Hey now!!";

var smtp = new SmtpClient
{
    Host = "smtp.gmail.com",
    Port = 587,
    EnableSsl = true,
    DeliveryMethod = SmtpDeliveryMethod.Network,
    Credentials = new NetworkCredential(fromAddress.Address, fromPassword),
    Timeout = 20000
};
using (var message = new MailMessage(fromAddress, toAddress)
{
    Subject = subject,
    Body = body
})
{
    smtp.Send(message);
}

一定要使用System.Net。邮件，而不是已弃用的System.Web.Mail。使用System.Web.Mail进行SSL是一堆拙劣的扩展。

using System.Net;
using System.Net.Mail;

var fromAddress = new MailAddress("from@gmail.com", "From Name");
var toAddress = new MailAddress("to@example.com", "To Name");
const string fromPassword = "fromPassword";
const string subject = "Subject";
const string body = "Body";

var smtp = new SmtpClient
{
    Host = "smtp.gmail.com",
    Port = 587,
    EnableSsl = true,
    DeliveryMethod = SmtpDeliveryMethod.Network,
    UseDefaultCredentials = false,
    Credentials = new NetworkCredential(fromAddress.Address, fromPassword)
};
using (var message = new MailMessage(fromAddress, toAddress)
{
    Subject = subject,
    Body = body
})
{
    smtp.Send(message);
}

此外，转到谷歌帐户>安全页面，并查看登录谷歌> 2步验证设置。

如果启用了，那么您必须生成一个密码，允许. net绕过2步验证。点击“Signing in To谷歌> App passwords”，选择App = Mail, device = Windows Computer，最后生成密码。在fromPassword常量中使用生成的密码，而不是标准的Gmail密码。 如果它被禁用，那么你必须打开Less secure app access，这是不推荐的!所以最好启用两步验证。

来源:在ASP发送电子邮件。净c#

下面是一个使用c#发送邮件的示例工作代码，在下面的例子中，我使用谷歌的smtp服务器。

代码是相当不言自明的，替换电子邮件和密码与您的电子邮件和密码值。

public void SendEmail(string address, string subject, string message)
{
    string email = "yrshaikh.mail@gmail.com";
    string password = "put-your-GMAIL-password-here";

    var loginInfo = new NetworkCredential(email, password);
    var msg = new MailMessage();
    var smtpClient = new SmtpClient("smtp.gmail.com", 587);

    msg.From = new MailAddress(email);
    msg.To.Add(new MailAddress(address));
    msg.Subject = subject;
    msg.Body = message;
    msg.IsBodyHtml = true;

    smtpClient.EnableSsl = true;
    smtpClient.UseDefaultCredentials = false;
    smtpClient.Credentials = loginInfo;
    smtpClient.Send(msg);
}

从另一个答案复制，上述方法工作，但gmail总是替换“从”和“回复”电子邮件与实际发送gmail帐户。然而，显然有一种方法:

http://karmic-development.blogspot.in/2013/10/send-email-from-aspnet-using-gmail-as.html

“3。在帐户选项卡，点击链接“添加另一个电子邮件地址你自己的”，然后验证它

或者可能是这个

更新3:读者德里克·贝内特说:“解决办法是进入你的gmail设置:账户，并“默认”一个gmail账户以外的账户。这将导致gmail用默认帐户的电子邮件地址重写From字段。”