上面的答案不管用。必须设置DeliveryMethod = SmtpDeliveryMethod。网络，否则将返回“客户端未经过身份验证”错误。此外，暂停总是一个好主意。

修改后的代码:

using System.Net.Mail;
using System.Net;

var fromAddress = new MailAddress("from@gmail.com", "From Name");
var toAddress = new MailAddress("to@yahoo.com", "To Name");
const string fromPassword = "password";
const string subject = "test";
const string body = "Hey now!!";

var smtp = new SmtpClient
{
    Host = "smtp.gmail.com",
    Port = 587,
    EnableSsl = true,
    DeliveryMethod = SmtpDeliveryMethod.Network,
    Credentials = new NetworkCredential(fromAddress.Address, fromPassword),
    Timeout = 20000
};
using (var message = new MailMessage(fromAddress, toAddress)
{
    Subject = subject,
    Body = body
})
{
    smtp.Send(message);
}

这是不再支持，如果你正在尝试这样做现在。

https://support.google.com/accounts/answer/6010255?hl=en&visit_id=637960864118404117-800836189&p=less-secure-apps&rd=1#zippy=

下面是一个从web.config发送邮件和获取凭证的方法:

public static string SendEmail(string To, string Subject, string Msg, bool bodyHtml = false, bool test = false, Stream AttachmentStream = null, string AttachmentType = null, string AttachmentFileName = null)
{
    try
    {
        System.Net.Mail.MailMessage newMsg = new System.Net.Mail.MailMessage(System.Configuration.ConfigurationManager.AppSettings["mailCfg"], To, Subject, Msg);
        newMsg.BodyEncoding = System.Text.Encoding.UTF8;
        newMsg.HeadersEncoding = System.Text.Encoding.UTF8;
        newMsg.SubjectEncoding = System.Text.Encoding.UTF8;

        System.Net.Mail.SmtpClient smtpClient = new System.Net.Mail.SmtpClient();
        if (AttachmentStream != null && AttachmentType != null && AttachmentFileName != null)
        {
            System.Net.Mail.Attachment attachment = new System.Net.Mail.Attachment(AttachmentStream, AttachmentFileName);
            System.Net.Mime.ContentDisposition disposition = attachment.ContentDisposition;
            disposition.FileName = AttachmentFileName;
            disposition.DispositionType = System.Net.Mime.DispositionTypeNames.Attachment;

            newMsg.Attachments.Add(attachment);
        }
        if (test)
        {
            smtpClient.PickupDirectoryLocation = "C:\\TestEmail";
            smtpClient.DeliveryMethod = System.Net.Mail.SmtpDeliveryMethod.SpecifiedPickupDirectory;
        }
        else
        {
            //smtpClient.EnableSsl = true;
        }

        newMsg.IsBodyHtml = bodyHtml;
        smtpClient.Send(newMsg);
        return SENT_OK;
    }
    catch (Exception ex)
    {

        return "Error: " + ex.Message
             + "<br/><br/>Inner Exception: "
             + ex.InnerException;
    }

}

以及web.config中相应的部分:

<appSettings>
    <add key="mailCfg" value="yourmail@example.com"/>
</appSettings>
<system.net>
  <mailSettings>
    <smtp deliveryMethod="Network" from="yourmail@example.com">
      <network defaultCredentials="false" host="mail.exapmple.com" userName="yourmail@example.com" password="your_password" port="25"/>
    </smtp>
  </mailSettings>
</system.net>

这是我的版本:“发送电子邮件在c#使用Gmail”。

using System;
using System.Net;
using System.Net.Mail;

namespace SendMailViaGmail
{
   class Program
   {
   static void Main(string[] args)
   {

      //Specify senders gmail address
      string SendersAddress = "Sendersaddress@gmail.com";
      //Specify The Address You want to sent Email To(can be any valid email address)
      string ReceiversAddress = "ReceiversAddress@yahoo.com";
      //Specify The password of gmial account u are using to sent mail(pw of sender@gmail.com)
      const string SendersPassword = "Password";
      //Write the subject of ur mail
      const string subject = "Testing";
      //Write the contents of your mail
      const string body = "Hi This Is my Mail From Gmail";

      try
      {
        //we will use Smtp client which allows us to send email using SMTP Protocol
        //i have specified the properties of SmtpClient smtp within{}
        //gmails smtp server name is smtp.gmail.com and port number is 587
        SmtpClient smtp = new SmtpClient
        {
           Host = "smtp.gmail.com",
           Port = 587,
           EnableSsl = true,
           DeliveryMethod = SmtpDeliveryMethod.Network,
           Credentials    = new NetworkCredential(SendersAddress, SendersPassword),
           Timeout = 3000
        };

        //MailMessage represents a mail message
        //it is 4 parameters(From,TO,subject,body)

        MailMessage message = new MailMessage(SendersAddress, ReceiversAddress, subject, body);
        /*WE use smtp sever we specified above to send the message(MailMessage message)*/

        smtp.Send(message);
        Console.WriteLine("Message Sent Successfully");
        Console.ReadKey();
     }

     catch (Exception ex)
     {
        Console.WriteLine(ex.Message);
        Console.ReadKey();
     }
    }
   }
 }

你可以试试Mailkit。它为发送邮件提供了更好、更先进的功能。这里有一个例子

    MimeMessage message = new MimeMessage();
    message.From.Add(new MailboxAddress("FromName", "YOU_FROM_ADDRESS@gmail.com"));
    message.To.Add(new MailboxAddress("ToName", "YOU_TO_ADDRESS@gmail.com"));
    message.Subject = "MyEmailSubject";

    message.Body = new TextPart("plain")
    {
        Text = @"MyEmailBodyOnlyTextPart"
    };

    using (var client = new SmtpClient())
    {
        client.Connect("SERVER", 25); // 25 is port you can change accordingly

        // Note: since we don't have an OAuth2 token, disable
        // the XOAUTH2 authentication mechanism.
        client.AuthenticationMechanisms.Remove("XOAUTH2");

        // Note: only needed if the SMTP server requires authentication
        client.Authenticate("YOUR_USER_NAME", "YOUR_PASSWORD");

        client.Send(message);
        client.Disconnect(true);
    }

在Gmail / Outlook.com邮箱更改发件人:

为了防止欺骗- Gmail/Outlook.com不会让你从任意用户帐户名发送。

如果发件人数量有限，则可以按照以下说明将From字段设置为此地址:从不同地址发送邮件

如果你想从一个任意的电子邮件地址发送(比如用户在网站上输入他们的电子邮件，而你不希望他们直接给你发送电子邮件)，你能做的最好的是:

        msg.ReplyToList.Add(new System.Net.Mail.MailAddress(email, friendlyName));

这可以让你在电子邮件账户中点击“回复”，在反馈页面上回复你乐队的粉丝，但他们不会收到你的实际电子邮件，这可能会导致大量垃圾邮件。

如果你在一个受控制的环境中，这工作得很好，但请注意，我看到一些电子邮件客户端发送到from地址，即使回复指定(我不知道是哪个)。