根据这里找到的一些答案，我想出了以下解决方案。

代码:

public class ExternalStorage {

    public static final String SD_CARD = "sdCard";
    public static final String EXTERNAL_SD_CARD = "externalSdCard";

    /**
     * @return True if the external storage is available. False otherwise.
     */
    public static boolean isAvailable() {
        String state = Environment.getExternalStorageState();
        if (Environment.MEDIA_MOUNTED.equals(state) || Environment.MEDIA_MOUNTED_READ_ONLY.equals(state)) {
            return true;
        }
        return false;
    }

    public static String getSdCardPath() {
        return Environment.getExternalStorageDirectory().getPath() + "/";
    }

    /**
     * @return True if the external storage is writable. False otherwise.
     */
    public static boolean isWritable() {
        String state = Environment.getExternalStorageState();
        if (Environment.MEDIA_MOUNTED.equals(state)) {
            return true;
        }
        return false;

    }

    /**
     * @return A map of all storage locations available
     */
    public static Map<String, File> getAllStorageLocations() {
        Map<String, File> map = new HashMap<String, File>(10);

        List<String> mMounts = new ArrayList<String>(10);
        List<String> mVold = new ArrayList<String>(10);
        mMounts.add("/mnt/sdcard");
        mVold.add("/mnt/sdcard");

        try {
            File mountFile = new File("/proc/mounts");
            if(mountFile.exists()){
                Scanner scanner = new Scanner(mountFile);
                while (scanner.hasNext()) {
                    String line = scanner.nextLine();
                    if (line.startsWith("/dev/block/vold/")) {
                        String[] lineElements = line.split(" ");
                        String element = lineElements[1];

                        // don't add the default mount path
                        // it's already in the list.
                        if (!element.equals("/mnt/sdcard"))
                            mMounts.add(element);
                    }
                }
            }
        } catch (Exception e) {
            e.printStackTrace();
        }

        try {
            File voldFile = new File("/system/etc/vold.fstab");
            if(voldFile.exists()){
                Scanner scanner = new Scanner(voldFile);
                while (scanner.hasNext()) {
                    String line = scanner.nextLine();
                    if (line.startsWith("dev_mount")) {
                        String[] lineElements = line.split(" ");
                        String element = lineElements[2];

                        if (element.contains(":"))
                            element = element.substring(0, element.indexOf(":"));
                        if (!element.equals("/mnt/sdcard"))
                            mVold.add(element);
                    }
                }
            }
        } catch (Exception e) {
            e.printStackTrace();
        }


        for (int i = 0; i < mMounts.size(); i++) {
            String mount = mMounts.get(i);
            if (!mVold.contains(mount))
                mMounts.remove(i--);
        }
        mVold.clear();

        List<String> mountHash = new ArrayList<String>(10);

        for(String mount : mMounts){
            File root = new File(mount);
            if (root.exists() && root.isDirectory() && root.canWrite()) {
                File[] list = root.listFiles();
                String hash = "[";
                if(list!=null){
                    for(File f : list){
                        hash += f.getName().hashCode()+":"+f.length()+", ";
                    }
                }
                hash += "]";
                if(!mountHash.contains(hash)){
                    String key = SD_CARD + "_" + map.size();
                    if (map.size() == 0) {
                        key = SD_CARD;
                    } else if (map.size() == 1) {
                        key = EXTERNAL_SD_CARD;
                    }
                    mountHash.add(hash);
                    map.put(key, root);
                }
            }
        }

        mMounts.clear();

        if(map.isEmpty()){
                 map.put(SD_CARD, Environment.getExternalStorageDirectory());
        }
        return map;
    }
}

用法:

Map<String, File> externalLocations = ExternalStorage.getAllStorageLocations();
File sdCard = externalLocations.get(ExternalStorage.SD_CARD);
File externalSdCard = externalLocations.get(ExternalStorage.EXTERNAL_SD_CARD);

Environment.getExternalStorageState()返回内部SD挂载点的路径，如"/mnt/sdcard"

不，Environment.getExternalStorageDirectory()指的是设备制造商认为是“外部存储”的任何东西。在某些设备上，这是可移动媒体，如SD卡。在某些设备上，这是设备上flash的一部分。这里的“外部存储”指的是“挂载在主机上通过USB大容量存储模式访问的东西”，至少对于Android 1来说是这样。X和2.x。

但问题是关于外置SD。如何获得像“/mnt/sdcard/external_sd”这样的路径(它可能因设备而异)?

Android没有“外部SD”的概念，除了如上所述的外部存储。

如果设备制造商已经选择将外部存储作为板载闪存，并且还具有SD卡，那么您将需要联系该制造商以确定是否可以使用SD卡(不保证)以及使用它的规则，例如使用它的路径。

更新

最近有两件事值得注意:

首先，在Android 4.4+上，你没有对可移动媒体(例如，“外部SD”)的写访问权，除非该媒体上的任何位置可能由getExternalFilesDirs()和getExternalCacheDirs()返回。请参阅Dave Smith对此的出色分析，特别是如果您想了解底层细节的话。

其次，为了避免有人质疑可移动媒体访问是否是Android SDK的一部分，以下是Dianne Hackborn的评估:

...keep in mind: until Android 4.4, the official Android platform has not supported SD cards at all except for two special cases: the old school storage layout where external storage is an SD card (which is still supported by the platform today), and a small feature added to Android 3.0 where it would scan additional SD cards and add them to the media provider and give apps read-only access to their files (which is also still supported in the platform today). Android 4.4 is the first release of the platform that has actually allowed applications to use SD cards for storage. Any access to them prior to that was through private, unsupported APIs. We now have a quite rich API in the platform that allows applications to make use of SD cards in a supported way, in better ways than they have been able to before: they can make free use of their app-specific storage area without requiring any permissions in the app, and can access any other files on the SD card as long as they go through the file picker, again without needing any special permissions.

为了检索所有外部存储(无论是SD卡还是内部不可移动存储)，您可以使用以下代码:

final String state = Environment.getExternalStorageState();

if ( Environment.MEDIA_MOUNTED.equals(state) || Environment.MEDIA_MOUNTED_READ_ONLY.equals(state) ) {  // we can read the External Storage...           
    //Retrieve the primary External Storage:
    final File primaryExternalStorage = Environment.getExternalStorageDirectory();

    //Retrieve the External Storages root directory:
    final String externalStorageRootDir;
    if ( (externalStorageRootDir = primaryExternalStorage.getParent()) == null ) {  // no parent...
        Log.d(TAG, "External Storage: " + primaryExternalStorage + "\n");
    }
    else {
        final File externalStorageRoot = new File( externalStorageRootDir );
        final File[] files = externalStorageRoot.listFiles();

        for ( final File file : files ) {
            if ( file.isDirectory() && file.canRead() && (file.listFiles().length > 0) ) {  // it is a real directory (not a USB drive)...
                Log.d(TAG, "External Storage: " + file.getAbsolutePath() + "\n");
            }
        }
    }
}

或者，您可以使用System.getenv("EXTERNAL_STORAGE")来检索主要的外部存储目录(例如:"/storage/sdcard0")和System.getenv("SECONDARY_STORAGE")来检索所有从目录的列表(例如:“/存储/ extSdCard: /存储/ UsbDriveA: /存储/ UsbDriveB”)。记住，同样在这种情况下，您可能想要过滤从目录列表以排除USB驱动器。

在任何情况下，请注意使用硬编码路径总是一种糟糕的方法(特别是当每个制造商都可以随心所欲地更改它时)。

这个解决方案处理System.getenv(“SECONDARY_STORAGE”)在Marshmallow中没有用的问题。

已测试和正在进行:

Samsung Galaxy Tab 2 (Android 4.1.1 - Stock) Samsung Galaxy Note 8.0 (Android 4.2.2 - Stock) Samsung Galaxy S4 (Android 4.4 - Stock) Samsung Galaxy S4 (Android 5.1.1 - Cyanogenmod) Samsung Galaxy Tab A (Android 6.0.1 - Stock) /** * Returns all available external SD-Card roots in the system. * * @return paths to all available external SD-Card roots in the system. */ public static String[] getStorageDirectories() { String [] storageDirectories; String rawSecondaryStoragesStr = System.getenv("SECONDARY_STORAGE"); if (Build.VERSION.SDK_INT >= Build.VERSION_CODES.KITKAT) { List<String> results = new ArrayList<String>(); File[] externalDirs = applicationContext.getExternalFilesDirs(null); for (File file : externalDirs) { String path = file.getPath().split("/Android")[0]; if((Build.VERSION.SDK_INT >= Build.VERSION_CODES.LOLLIPOP && Environment.isExternalStorageRemovable(file)) || rawSecondaryStoragesStr != null && rawSecondaryStoragesStr.contains(path)){ results.add(path); } } storageDirectories = results.toArray(new String[0]); }else{ final Set<String> rv = new HashSet<String>(); if (!TextUtils.isEmpty(rawSecondaryStoragesStr)) { final String[] rawSecondaryStorages = rawSecondaryStoragesStr.split(File.pathSeparator); Collections.addAll(rv, rawSecondaryStorages); } storageDirectories = rv.toArray(new String[rv.size()]); } return storageDirectories; }

/sdcard =>内部存储(这是一个符号链接，但应该工作)

/mnt/extSdCard =>外部sd卡

这是三星Galaxy S3

你可以相信这对大多数人来说都是真的……但是要仔细检查!

通过读取/proc/mounts(标准的Linux文件)，并对vold数据(/system/etc/vold.conf)进行交叉检查，可以找到任何其他SD卡被挂载的位置。注意，Environment.getExternalStorageDirectory()返回的位置可能不会出现在vold配置中(在某些设备中，它是不能卸载的内部存储)，但仍然必须包含在列表中。然而，我们并没有找到一个向用户描述它们的好方法。