修改了@CristianRomanescu代码，以使用内存流，接受文件作为字节数组，允许空nvc，返回请求响应和使用授权头。使用Web Api 2测试代码。

private string HttpUploadFile(string url, byte[] file, string fileName, string paramName, string contentType, NameValueCollection nvc, string authorizationHeader)
{
    string boundary = "---------------------------" + DateTime.Now.Ticks.ToString("x");
    byte[] boundarybytes = System.Text.Encoding.ASCII.GetBytes("\r\n--" + boundary + "\r\n");

    HttpWebRequest wr = (HttpWebRequest)WebRequest.Create(url);
    wr.ContentType = "multipart/form-data; boundary=" + boundary;
    wr.Method = "POST";
    wr.Headers.Add("Authorization", authorizationHeader);
    wr.KeepAlive = true;

    Stream rs = wr.GetRequestStream();

    string formdataTemplate = "Content-Disposition: form-data; name=\"{0}\"\r\n\r\n{1}";
    if (nvc != null)
    {
        foreach (string key in nvc.Keys)
        {
            rs.Write(boundarybytes, 0, boundarybytes.Length);
            string formitem = string.Format(formdataTemplate, key, nvc[key]);
            byte[] formitembytes = System.Text.Encoding.UTF8.GetBytes(formitem);
            rs.Write(formitembytes, 0, formitembytes.Length);
        }
    }

    rs.Write(boundarybytes, 0, boundarybytes.Length);

    string headerTemplate = "Content-Disposition: form-data; name=\"{0}\"; filename=\"{1}\"\r\nContent-Type: {2}\r\n\r\n";
    string header = string.Format(headerTemplate, paramName, fileName, contentType);
    byte[] headerbytes = System.Text.Encoding.UTF8.GetBytes(header);
    rs.Write(headerbytes, 0, headerbytes.Length);

    rs.Write(file, 0, file.Length);

    byte[] trailer = System.Text.Encoding.ASCII.GetBytes("\r\n--" + boundary + "--\r\n");
    rs.Write(trailer, 0, trailer.Length);
    rs.Close();

    WebResponse wresp = null;
    try
    {
        wresp = wr.GetResponse();
        Stream stream2 = wresp.GetResponseStream();
        StreamReader reader2 = new StreamReader(stream2);
        var response = reader2.ReadToEnd();
        return response;
    }
    catch (Exception ex)
    {
        if (wresp != null)
        {
            wresp.Close();
            wresp = null;
        }
        return null;
    }
    finally
    {
        wr = null;
    }
}

Testcode:

[HttpPost]
[Route("postformdata")]
public IHttpActionResult PostFormData()
{
    // Check if the request contains multipart/form-data.
    if (!Request.Content.IsMimeMultipartContent())
    {
        throw new HttpResponseException(HttpStatusCode.UnsupportedMediaType);
    }

    var provider = new MultipartMemoryStreamProvider();

    try
    {
        // Read the form data.
        var result = Request.Content.ReadAsMultipartAsync(provider).Result;
        string response = "";
        // This illustrates how to get the file names.
        foreach (var file in provider.Contents)
        {
            var fileName = file.Headers.ContentDisposition.FileName.Trim('\"');
            var buffer =  file.ReadAsByteArrayAsync().Result;
            response = HttpUploadFile("https://localhost/api/v1/createfromfile", buffer, fileName, "file", "application/pdf", null, "AuthorizationKey");
        }
        return Ok(response);
    }
    catch (System.Exception e)
    {
        return InternalServerError();
    }
}

对于我来说，下面的作品(主要是受到以下所有回答的启发)，我从Elad的回答开始，修改/简化事情以符合我的需要(删除不是文件形式输入，只有一个文件，……)

希望它能帮助到一些人:)

(PS:我知道异常处理没有实现，并且假设它是在一个类中编写的，所以我可能需要一些集成工作…)

private void uploadFile()
    {
        Random rand = new Random();
        string boundary = "----boundary" + rand.Next().ToString();
        Stream data_stream;
        byte[] header = System.Text.Encoding.ASCII.GetBytes("\r\n--" + boundary + "\r\nContent-Disposition: form-data; name=\"file_path\"; filename=\"" + System.IO.Path.GetFileName(this.file) + "\"\r\nContent-Type: application/octet-stream\r\n\r\n");
        byte[] trailer = System.Text.Encoding.ASCII.GetBytes("\r\n--" + boundary + "--\r\n");

        // Do the request
        HttpWebRequest request = (HttpWebRequest)WebRequest.Create(MBF_URL);
        request.UserAgent = "My Toolbox";
        request.Method = "POST";
        request.KeepAlive = true;
        request.ContentType = "multipart/form-data; boundary=" + boundary;
        data_stream = request.GetRequestStream();
        data_stream.Write(header, 0, header.Length);
        byte[] file_bytes = System.IO.File.ReadAllBytes(this.file);
        data_stream.Write(file_bytes, 0, file_bytes.Length);
        data_stream.Write(trailer, 0, trailer.Length);
        data_stream.Close();

        // Read the response
        WebResponse response = request.GetResponse();
        data_stream = response.GetResponseStream();
        StreamReader reader = new StreamReader(data_stream);
        this.url = reader.ReadToEnd();

        if (this.url == "") { this.url = "No response :("; }

        reader.Close();
        data_stream.Close();
        response.Close();
    }

我一直在找这样的东西，在: http://bytes.com/groups/net-c/268661-how-upload-file-via-c-code(为正确而修改):

public static string UploadFilesToRemoteUrl(string url, string[] files, NameValueCollection formFields = null)
{
    string boundary = "----------------------------" + DateTime.Now.Ticks.ToString("x");

    HttpWebRequest request = (HttpWebRequest) WebRequest.Create(url);
    request.ContentType = "multipart/form-data; boundary=" +
                            boundary;
    request.Method = "POST";
    request.KeepAlive = true;

    Stream memStream = new System.IO.MemoryStream();

    var boundarybytes = System.Text.Encoding.ASCII.GetBytes("\r\n--" +
                                                            boundary + "\r\n");
    var endBoundaryBytes = System.Text.Encoding.ASCII.GetBytes("\r\n--" +
                                                                boundary + "--");


    string formdataTemplate = "\r\n--" + boundary +
                                "\r\nContent-Disposition: form-data; name=\"{0}\";\r\n\r\n{1}";

    if (formFields != null)
    {
        foreach (string key in formFields.Keys)
        {
            string formitem = string.Format(formdataTemplate, key, formFields[key]);
            byte[] formitembytes = System.Text.Encoding.UTF8.GetBytes(formitem);
            memStream.Write(formitembytes, 0, formitembytes.Length);
        }
    }

    string headerTemplate =
        "Content-Disposition: form-data; name=\"{0}\"; filename=\"{1}\"\r\n" +
        "Content-Type: application/octet-stream\r\n\r\n";

    for (int i = 0; i < files.Length; i++)
    {
        memStream.Write(boundarybytes, 0, boundarybytes.Length);
        var header = string.Format(headerTemplate, "uplTheFile", files[i]);
        var headerbytes = System.Text.Encoding.UTF8.GetBytes(header);

        memStream.Write(headerbytes, 0, headerbytes.Length);

        using (var fileStream = new FileStream(files[i], FileMode.Open, FileAccess.Read))
        {
            var buffer = new byte[1024];
            var bytesRead = 0;
            while ((bytesRead = fileStream.Read(buffer, 0, buffer.Length)) != 0)
            {
                memStream.Write(buffer, 0, bytesRead);
            }
        }
    }

    memStream.Write(endBoundaryBytes, 0, endBoundaryBytes.Length);
    request.ContentLength = memStream.Length;

    using (Stream requestStream = request.GetRequestStream())
    {
        memStream.Position = 0;
        byte[] tempBuffer = new byte[memStream.Length];
        memStream.Read(tempBuffer, 0, tempBuffer.Length);
        memStream.Close();
        requestStream.Write(tempBuffer, 0, tempBuffer.Length);
    }

    using (var response = request.GetResponse())
    {
        Stream stream2 = response.GetResponseStream();
        StreamReader reader2 = new StreamReader(stream2);
        return reader2.ReadToEnd();
    }
}

类似这样的代码很接近:(未测试的代码)

byte[] data; // data goes here.

HttpWebRequest request = (HttpWebRequest)WebRequest.Create(url);
request.Credentials = userNetworkCredentials;
request.Method = "PUT";
request.ContentType = "application/octet-stream";
request.ContentLength = data.Length;
Stream stream = request.GetRequestStream();
stream.Write(data,0,data.Length);
stream.Close();
response = (HttpWebResponse)request.GetResponse();
StreamReader reader = new StreamReader(response.GetResponseStream());
temp = reader.ReadToEnd();
reader.Close();

VB示例(从另一篇文章中的c#示例转换而来):

Private Sub HttpUploadFile( _
    ByVal uri As String, _
    ByVal filePath As String, _
    ByVal fileParameterName As String, _
    ByVal contentType As String, _
    ByVal otherParameters As Specialized.NameValueCollection)

    Dim boundary As String = "---------------------------" & DateTime.Now.Ticks.ToString("x")
    Dim newLine As String = System.Environment.NewLine
    Dim boundaryBytes As Byte() = Text.Encoding.ASCII.GetBytes(newLine & "--" & boundary & newLine)
    Dim request As Net.HttpWebRequest = Net.WebRequest.Create(uri)

    request.ContentType = "multipart/form-data; boundary=" & boundary
    request.Method = "POST"
    request.KeepAlive = True
    request.Credentials = Net.CredentialCache.DefaultCredentials

    Using requestStream As IO.Stream = request.GetRequestStream()

        Dim formDataTemplate As String = "Content-Disposition: form-data; name=""{0}""{1}{1}{2}"

        For Each key As String In otherParameters.Keys

            requestStream.Write(boundaryBytes, 0, boundaryBytes.Length)
            Dim formItem As String = String.Format(formDataTemplate, key, newLine, otherParameters(key))
            Dim formItemBytes As Byte() = Text.Encoding.UTF8.GetBytes(formItem)
            requestStream.Write(formItemBytes, 0, formItemBytes.Length)

        Next key

        requestStream.Write(boundaryBytes, 0, boundaryBytes.Length)

        Dim headerTemplate As String = "Content-Disposition: form-data; name=""{0}""; filename=""{1}""{2}Content-Type: {3}{2}{2}"
        Dim header As String = String.Format(headerTemplate, fileParameterName, filePath, newLine, contentType)
        Dim headerBytes As Byte() = Text.Encoding.UTF8.GetBytes(header)
        requestStream.Write(headerBytes, 0, headerBytes.Length)

        Using fileStream As New IO.FileStream(filePath, IO.FileMode.Open, IO.FileAccess.Read)

            Dim buffer(4096) As Byte
            Dim bytesRead As Int32 = fileStream.Read(buffer, 0, buffer.Length)

            Do While (bytesRead > 0)

                requestStream.Write(buffer, 0, bytesRead)
                bytesRead = fileStream.Read(buffer, 0, buffer.Length)

            Loop

        End Using

        Dim trailer As Byte() = Text.Encoding.ASCII.GetBytes(newLine & "--" + boundary + "--" & newLine)
        requestStream.Write(trailer, 0, trailer.Length)

    End Using

    Dim response As Net.WebResponse = Nothing

    Try

        response = request.GetResponse()

        Using responseStream As IO.Stream = response.GetResponseStream()

            Using responseReader As New IO.StreamReader(responseStream)

                Dim responseText = responseReader.ReadToEnd()
                Diagnostics.Debug.Write(responseText)

            End Using

        End Using

    Catch exception As Net.WebException

        response = exception.Response

        If (response IsNot Nothing) Then

            Using reader As New IO.StreamReader(response.GetResponseStream())

                Dim responseText = reader.ReadToEnd()
                Diagnostics.Debug.Write(responseText)

            End Using

            response.Close()

        End If

    Finally

        request = Nothing

    End Try

End Sub

不确定这是否张贴之前，但我得到了这个工作与WebClient。我读了WebClient的文档。他们提出的一个关键点是

如果BaseAddress属性不是空字符串("")和address 不包含绝对URI，地址必须是相对URI那 与BaseAddress结合形成所请求的URI的绝对URI 数据。如果QueryString属性不是空字符串，那么它就是空字符串 附于地址。

我所做的就是wc。querystring。添加(“源”，generatedImage)来添加不同的查询参数，以某种方式将属性名称与我上传的图像匹配。希望能有所帮助

    public void postImageToFacebook(string generatedImage, string fbGraphUrl)
    {
        WebClient wc = new WebClient();
        byte[] bytes = System.IO.File.ReadAllBytes(generatedImage);

        wc.QueryString.Add("source", generatedImage);
        wc.QueryString.Add("message", "helloworld");

        wc.UploadFile(fbGraphUrl, generatedImage);

        wc.Dispose();

    }