首先删除super.onBackPressed();从onbackPressed()方法和以下代码:

@Override
public void onBackPressed() {
    AlertDialog.Builder builder = new AlertDialog.Builder(this);
    builder.setMessage("Are you sure you want to exit?")
           .setCancelable(false)
           .setPositiveButton("Yes", new DialogInterface.OnClickListener() {
               public void onClick(DialogInterface dialog, int id) {
                    MyActivity.this.finish();
               }
           })
           .setNegativeButton("No", new DialogInterface.OnClickListener() {
               public void onClick(DialogInterface dialog, int id) {
                    dialog.cancel();
               }
           });
    AlertDialog alert = builder.create();
    alert.show();

}

已修改@user919216代码..并使其与WebView兼容

@Override
public void onBackPressed() {
    if (webview.canGoBack()) {
        webview.goBack();

    }
    else
    {
     AlertDialog.Builder builder = new AlertDialog.Builder(this);
builder.setMessage("Are you sure you want to exit?")
       .setCancelable(false)
       .setPositiveButton("Yes", new DialogInterface.OnClickListener() {
           public void onClick(DialogInterface dialog, int id) {
                finish();
           }
       })
       .setNegativeButton("No", new DialogInterface.OnClickListener() {
           public void onClick(DialogInterface dialog, int id) {
                dialog.cancel();
           }
       });
AlertDialog alert = builder.create();
alert.show();
    }

}

在中国，大多数App会通过“点击两次”确认退出:

boolean doubleBackToExitPressedOnce = false;

@Override
public void onBackPressed() {
    if (doubleBackToExitPressedOnce) {
        super.onBackPressed();
        return;
    }

    this.doubleBackToExitPressedOnce = true;
    Toast.makeText(this, "Please click BACK again to exit", Toast.LENGTH_SHORT).show();

    new Handler().postDelayed(new Runnable() {

        @Override
        public void run() {
            doubleBackToExitPressedOnce=false;                       
        }
    }, 2000);
} 

我喜欢@GLee的方法，并像下面这样使用片段。

@Override
public void onBackPressed() {
    if(isTaskRoot()) {
        new ExitDialogFragment().show(getSupportFragmentManager(), null);
    } else {
        super.onBackPressed();
    }
}

使用片段的对话框:

public class ExitDialogFragment extends DialogFragment {

    @Override
    public Dialog onCreateDialog(Bundle savedInstanceState) {
        return new AlertDialog.Builder(getActivity())
            .setTitle(R.string.exit_question)
            .setPositiveButton(android.R.string.yes, new DialogInterface.OnClickListener() {
                @Override
                public void onClick(DialogInterface dialog, int which) {
                    getActivity().finish();
                }
            })
            .setNegativeButton(android.R.string.no, new DialogInterface.OnClickListener() {
                @Override
                public void onClick(DialogInterface dialog, int which) {
                    getDialog().cancel();
                }
            })
            .create();
    }
}

我更喜欢双击后退按钮退出，而不是退出对话框。

在这个解决方案中，当第一次返回时，它会显示一个吐司，警告另一个回按将关闭应用程序。在这个例子中，不到4秒。

private Toast toast;
private long lastBackPressTime = 0;

@Override
public void onBackPressed() {
  if (this.lastBackPressTime < System.currentTimeMillis() - 4000) {
    toast = Toast.makeText(this, "Press back again to close this app", 4000);
    toast.show();
    this.lastBackPressTime = System.currentTimeMillis();
  } else {
    if (toast != null) {
    toast.cancel();
  }
  super.onBackPressed();
 }
}

令牌来自:http://www.androiduipatterns.com/2011/03/back-button-behavior.html

@Override
public void onBackPressed() {
    new AlertDialog.Builder(this)
           .setMessage("Are you sure you want to exit?")
           .setCancelable(false)
           .setPositiveButton("Yes", new DialogInterface.OnClickListener() {
               public void onClick(DialogInterface dialog, int id) {
                   ExampleActivity.super.onBackPressed();
               }
           })
           .setNegativeButton("No", null)
           .show();
}