如果你想使用MaterialButton，

=======================================

你可以添加RoundedRectangleBorder，就像这样，

MaterialButton(
  onPressed: () {},
  minWidth: MediaQuery.of(context).size.width * 0.4,
  height: 34,
  color: colorWhite,
  highlightColor: colorSplash,
  splashColor: colorSplash,
  visualDensity: VisualDensity.compact,
  shape: RoundedRectangleBorder(
    borderRadius: BorderRadius.circular(4),
    side: BorderSide(
      color: colorGrey,
      width: 0.6,
    ),
  ),
  child: Text("CANCEL"),
),

RaisedButton(
          child: Text("Button"),
          onPressed: (){},
          shape: RoundedRectangleBorder(borderRadius: new BorderRadius.circular(30.0),
          side: BorderSide(color: Colors.red))
        )

如果你想使用MaterialButton，

=======================================

你可以添加RoundedRectangleBorder，就像这样，

MaterialButton(
  onPressed: () {},
  minWidth: MediaQuery.of(context).size.width * 0.4,
  height: 34,
  color: colorWhite,
  highlightColor: colorSplash,
  splashColor: colorSplash,
  visualDensity: VisualDensity.compact,
  shape: RoundedRectangleBorder(
    borderRadius: BorderRadius.circular(4),
    side: BorderSide(
      color: colorGrey,
      width: 0.6,
    ),
  ),
  child: Text("CANCEL"),
),

你可以简单地使用RaisedButton或你可以使用InkWell来获得一个自定义按钮和属性，如onDoubleTap, onLongPress等:

new InkWell(
  onTap: () => print('hello'),
  child: new Container(
    //width: 100.0,
    height: 50.0,
    decoration: new BoxDecoration(
      color: Colors.blueAccent,
      border: new Border.all(color: Colors.white, width: 2.0),
      borderRadius: new BorderRadius.circular(10.0),
    ),
    child: new Center(child: new Text('Click Me', style: new TextStyle(fontSize: 18.0, color: Colors.white),),),
  ),
),

如果你想在InkWell小部件中使用splashColor和highlightColor属性，使用Material小部件作为InkWell小部件的父部件，而不是装饰容器(删除装饰属性)。在这里阅读原因。

您可以使用下面的代码创建一个渐变颜色的圆形按钮。

 Container(
          width: 130.0,
          height: 43.0,
          decoration: BoxDecoration(
            borderRadius: BorderRadius.circular(30.0),
            gradient: LinearGradient(
              // Where the linear gradient begins and ends
              begin: Alignment.topRight,
              end: Alignment.bottomLeft,
              // Add one stop for each color. Stops should increase from 0 to 1
              stops: [0.1, 0.9],
              colors: [
                // Colors are easy thanks to Flutter's Colors class.
                Color(0xff1d83ab),
                Color(0xff0cbab8),
              ],
            ),
          ),
          child: FlatButton(
            child: Text(
              'Sign In',
              style: TextStyle(
                fontSize: 16.0,
                fontFamily: 'Righteous',
                fontWeight: FontWeight.w600,
              ),
            ),
            textColor: Colors.white,
            color: Colors.transparent,
            shape:
                RoundedRectangleBorder(borderRadius: BorderRadius.circular(30.0)),
            onPressed: () {

            },
          ),
        );

圆边颜色容器:

Container(
  decoration: BoxDecoration(
    borderRadius: BorderRadius.circular(10),
    border: Border.all(color: Colors.red),
  ),
  child: Text("Some Text"),
)