延伸到@Cope360的好答案。要获取某个表(如果它们是相同的表名但不同的模式)，只需使用表OID。

select
     t.relname as table_name
    ,i.relname as index_name
    ,a.attname as column_name
    ,a.attrelid tableid

from
    pg_class t,
    pg_class i,
    pg_index ix,
    pg_attribute a
where
    t.oid = ix.indrelid
    and i.oid = ix.indexrelid
    and a.attrelid = t.oid
    and a.attnum = ANY(ix.indkey)
    and t.relkind = 'r'
    -- and t.relname like 'tbassettype'
    and a.attrelid = '"dbLegal".tbassettype'::regclass
order by
    t.relname,
    i.relname;

解释:我有表名'tbassettype'在两个模式'dbAsset'和'dbLegal'。要在dbLegal上只获取表，只需让a.attrelid =它的OID。

一些样本数据…

create table test (a int, b int, c int, constraint pk_test primary key(a, b));
create table test2 (a int, b int, c int, constraint uk_test2 unique (b, c));
create table test3 (a int, b int, c int, constraint uk_test3b unique (b), constraint uk_test3c unique (c), constraint uk_test3ab unique (a, b));

使用pg_get_indexdef函数:

select pg_get_indexdef(indexrelid) from pg_index where indrelid = 'test'::regclass;

                    pg_get_indexdef
--------------------------------------------------------
 CREATE UNIQUE INDEX pk_test ON test USING btree (a, b)
(1 row)


select pg_get_indexdef(indexrelid) from pg_index where indrelid = 'test2'::regclass;
                     pg_get_indexdef
----------------------------------------------------------
 CREATE UNIQUE INDEX uk_test2 ON test2 USING btree (b, c)
(1 row)


select pg_get_indexdef(indexrelid) from pg_index where indrelid ='test3'::regclass;
                      pg_get_indexdef
------------------------------------------------------------
 CREATE UNIQUE INDEX uk_test3b ON test3 USING btree (b)
 CREATE UNIQUE INDEX uk_test3c ON test3 USING btree (c)
 CREATE UNIQUE INDEX uk_test3ab ON test3 USING btree (a, b)
(3 rows)

\d table_name显示了来自psql的这些信息，但是如果你想使用SQL从数据库中获取这些信息，那么可以看看从PostgreSQL中提取META信息。

我在我的实用程序中使用这些信息来报告来自db schema的一些信息，以比较测试和生产环境中的PostgreSQL数据库。

类似于接受的答案，但有左连接pg_attribute作为正常连接或查询pg_attribute不给出索引，如: 为用户创建唯一索引unique_user_name_index (lower(name))

select 
    row_number() over (order by c.relname),
    c.relname as index, 
    t.relname as table, 
    array_to_string(array_agg(a.attname), ', ') as column_names 
from pg_class c
join pg_index i on c.oid = i.indexrelid and c.relkind='i' and c.relname not like 'pg_%' 
join pg_class t on t.oid = i.indrelid
left join pg_attribute a on a.attrelid = t.oid and a.attnum = ANY(i.indkey) 
group by t.relname, c.relname order by c.relname;

查询结果:

table |     column     |          type          | notnull |  index_name  | is_index | primarykey | uniquekey | default
-------+----------------+------------------------+---------+--------------+----------+-   -----------+-----------+---------
 nodes | dns_datacenter | character varying(255) | f       |              | f        | f          | f         |
 nodes | dns_name       | character varying(255) | f       | dns_name_idx | t        | f          | f         |
 nodes | id             | uuid                   | t       | nodes_pkey   | t        | t          | t         |
(3 rows)

查询:

SELECT  
c.relname AS table,
f.attname AS column,  
pg_catalog.format_type(f.atttypid,f.atttypmod) AS type,
f.attnotnull AS notnull,  
i.relname as index_name,
CASE  
    WHEN i.oid<>0 THEN 't'  
    ELSE 'f'  
END AS is_index,  
CASE  
    WHEN p.contype = 'p' THEN 't'  
    ELSE 'f'  
END AS primarykey,  
CASE  
    WHEN p.contype = 'u' THEN 't' 
    WHEN p.contype = 'p' THEN 't' 
    ELSE 'f'
END AS uniquekey,
CASE
    WHEN f.atthasdef = 't' THEN d.adsrc
END AS default  FROM pg_attribute f  
JOIN pg_class c ON c.oid = f.attrelid  
JOIN pg_type t ON t.oid = f.atttypid  
LEFT JOIN pg_attrdef d ON d.adrelid = c.oid AND d.adnum = f.attnum  
LEFT JOIN pg_namespace n ON n.oid = c.relnamespace  
LEFT JOIN pg_constraint p ON p.conrelid = c.oid AND f.attnum = ANY (p.conkey)  
LEFT JOIN pg_class AS g ON p.confrelid = g.oid
LEFT JOIN pg_index AS ix ON f.attnum = ANY(ix.indkey) and c.oid = f.attrelid and c.oid = ix.indrelid 
LEFT JOIN pg_class AS i ON ix.indexrelid = i.oid 

WHERE c.relkind = 'r'::char  
AND n.nspname = 'public'  -- Replace with Schema name 
--AND c.relname = 'nodes'  -- Replace with table name, or Comment this for get all tables
AND f.attnum > 0
ORDER BY c.relname,f.attname;

稍微修改一下@cope360的回答:

create table test (a int, b int, c int, constraint pk_test primary key(c, a, b));
select i.relname as index_name,
       ix.indisunique as is_unique,
       a.attname as column_name,
from pg_class c
       inner join pg_index ix on c.oid=ix.indrelid
       inner join pg_class i on ix.indexrelid=i.oid
       inner join pg_attribute a on a.attrelid=c.oid and a.attnum=any(ix.indkey)
where c.oid='public.test'::regclass::oid
order by array_position(ix.indkey, a.attnum) asc;

这将显示索引列的正确顺序:

index_name      is_unique  column_name
pk_test         true       c
pk_test         true       a
pk_test         true       b