下面是同步调用的例子，但你可以通过await-sync轻松地更改为异步:

var pairs = new List<KeyValuePair<string, string>>
            {
                new KeyValuePair<string, string>("login", "abc")
            };

var content = new FormUrlEncodedContent(pairs);

var client = new HttpClient {BaseAddress = new Uri("http://localhost:6740")};

    // call sync
var response = client.PostAsync("/api/membership/exist", content).Result; 
if (response.IsSuccessStatusCode)
{
}

在asp.net网站上有一篇关于你的问题的文章。我希望它能帮助你。

如何用asp net调用api

http://www.asp.net/web-api/overview/advanced/calling-a-web-api-from-a-net-client

以下是本文POST部分的一小部分

下面的代码发送一个POST请求，其中包含一个JSON格式的Product实例:

// HTTP POST
var gizmo = new Product() { Name = "Gizmo", Price = 100, Category = "Widget" };
response = await client.PostAsJsonAsync("api/products", gizmo);
if (response.IsSuccessStatusCode)
{
    // Get the URI of the created resource.
    Uri gizmoUrl = response.Headers.Location;
}

using System;
using System.Collections.Generic;
using System.Net.Http;

class Program
{
    static void Main(string[] args)
    {
        Task.Run(() => MainAsync());
        Console.ReadLine();
    }

    static async Task MainAsync()
    {
        using (var client = new HttpClient())
        {
            client.BaseAddress = new Uri("http://localhost:6740");
            var content = new FormUrlEncodedContent(new[]
            {
                new KeyValuePair<string, string>("", "login")
            });
            var result = await client.PostAsync("/api/Membership/exists", content);
            string resultContent = await result.Content.ReadAsStringAsync();
            Console.WriteLine(resultContent);
        }
    }
}

你可以这样做

HttpWebRequest req = (HttpWebRequest)WebRequest.Create("http://localhost:6740/api/Membership/exist");

req.Method = "POST";
req.ContentType = "application/x-www-form-urlencoded";         
req.ContentLength = 6;

StreamWriter streamOut = new StreamWriter(req.GetRequestStream(), System.Text.Encoding.ASCII);
streamOut.Write(strRequest);
streamOut.Close();
StreamReader streamIn = new StreamReader(req.GetResponse().GetResponseStream());
string strResponse = streamIn.ReadToEnd();
streamIn.Close();

然后strresponse应该包含webservice返回的值

下面是同步调用的例子，但你可以通过await-sync轻松地更改为异步:

var pairs = new List<KeyValuePair<string, string>>
            {
                new KeyValuePair<string, string>("login", "abc")
            };

var content = new FormUrlEncodedContent(pairs);

var client = new HttpClient {BaseAddress = new Uri("http://localhost:6740")};

    // call sync
var response = client.PostAsync("/api/membership/exist", content).Result; 
if (response.IsSuccessStatusCode)
{
}

在这里，我找到了这篇文章，这是发送post请求使用JsonConvert.SerializeObject() & StringContent()到HttpClient。PostAsync数据

static async Task Main(string[] args)
{
    var person = new Person();
    person.Name = "John Doe";
    person.Occupation = "gardener";

    var json = Newtonsoft.Json.JsonConvert.SerializeObject(person);
    var data = new System.Net.Http.StringContent(json, Encoding.UTF8, "application/json");

    var url = "https://httpbin.org/post";
    using var client = new HttpClient();

    var response = await client.PostAsync(url, data);

    string result = response.Content.ReadAsStringAsync().Result;
    Console.WriteLine(result);
}