只是想补充一点，我用的是微软。互操作库，特别是ExportAsFixedFormat函数，我没有看到在这个线程中使用。

using Microsoft.Office.Interop.Word;
using System.Runtime.InteropServices;
using System.IO;
using Microsoft.Office.Core;

Application app;

public string CreatePDF(string path, string exportDir)
{
    Application app = new Application();
    app.DisplayAlerts = WdAlertLevel.wdAlertsNone;
    app.Visible = true;

    var objPresSet = app.Documents;
    var objPres = objPresSet.Open(path, MsoTriState.msoTrue, MsoTriState.msoTrue, MsoTriState.msoFalse);

    var pdfFileName = Path.ChangeExtension(path, ".pdf");
    var pdfPath = Path.Combine(exportDir, pdfFileName);

    try
    {
        objPres.ExportAsFixedFormat(
            pdfPath,
            WdExportFormat.wdExportFormatPDF,
            false,
            WdExportOptimizeFor.wdExportOptimizeForPrint,
            WdExportRange.wdExportAllDocument
        );
    }
    catch
    {
        pdfPath = null;
    }
    finally
    {
        objPres.Close();
    }
    return pdfPath;
}

使用foreach循环而不是for循环——它解决了我的问题。

int j = 0;
foreach (Microsoft.Office.Interop.Word.Page p in pane.Pages)
{
    var bits = p.EnhMetaFileBits;
    var target = path1 +j.ToString()+  "_image.doc";
    try
    {
        using (var ms = new MemoryStream((byte[])(bits)))
        {
            var image = System.Drawing.Image.FromStream(ms);
            var pngTarget = Path.ChangeExtension(target, "png");
            image.Save(pngTarget, System.Drawing.Imaging.ImageFormat.Png);
        }
    }
    catch (System.Exception ex)
    {
        MessageBox.Show(ex.Message);  
    }
    j++;
}

这是一个对我有用的程序的修改。它使用Word 2007，并安装了另存为PDF插件。它会在目录中搜索。doc文件，在Word中打开，然后保存为PDF格式。注意，您需要向解决方案添加对Microsoft.Office.Interop.Word的引用。

using Microsoft.Office.Interop.Word;
using System;
using System.Collections.Generic;
using System.IO;
using System.Linq;
using System.Text;

...

// Create a new Microsoft Word application object
Microsoft.Office.Interop.Word.Application word = new Microsoft.Office.Interop.Word.Application();

// C# doesn't have optional arguments so we'll need a dummy value
object oMissing = System.Reflection.Missing.Value;

// Get list of Word files in specified directory
DirectoryInfo dirInfo = new DirectoryInfo(@"\\server\folder");
FileInfo[] wordFiles = dirInfo.GetFiles("*.doc");

word.Visible = false;
word.ScreenUpdating = false;

foreach (FileInfo wordFile in wordFiles)
{
    // Cast as Object for word Open method
    Object filename = (Object)wordFile.FullName;

    // Use the dummy value as a placeholder for optional arguments
    Document doc = word.Documents.Open(ref filename, ref oMissing,
        ref oMissing, ref oMissing, ref oMissing, ref oMissing, ref oMissing,
        ref oMissing, ref oMissing, ref oMissing, ref oMissing, ref oMissing,
        ref oMissing, ref oMissing, ref oMissing, ref oMissing);
    doc.Activate();

    object outputFileName = wordFile.FullName.Replace(".doc", ".pdf");
    object fileFormat = WdSaveFormat.wdFormatPDF;

    // Save document into PDF Format
    doc.SaveAs(ref outputFileName,
        ref fileFormat, ref oMissing, ref oMissing,
        ref oMissing, ref oMissing, ref oMissing, ref oMissing,
        ref oMissing, ref oMissing, ref oMissing, ref oMissing,
        ref oMissing, ref oMissing, ref oMissing, ref oMissing);

    // Close the Word document, but leave the Word application open.
    // doc has to be cast to type _Document so that it will find the
    // correct Close method.                
    object saveChanges = WdSaveOptions.wdDoNotSaveChanges;
    ((_Document)doc).Close(ref saveChanges, ref oMissing, ref oMissing);
    doc = null;
}

// word has to be cast to type _Application so that it will find
// the correct Quit method.
((_Application)word).Quit(ref oMissing, ref oMissing, ref oMissing);
word = null;

为vb.net用户总结一下，免费选项(必须安装office):

microsoftofficeassemblies下载:

2010年的Pia办公室 皮娅竞选2007年总统 添加对Microsoft.Office.Interop.Word.Application的引用 在Microsoft.Office.Interop.Word.Application中添加using或import (vb.net)语句

VB。净的例子:

        Dim word As Application = New Application()
        Dim doc As Document = word.Documents.Open("c:\document.docx")
        doc.Activate()
        doc.SaveAs2("c:\document.pdf", WdSaveFormat.wdFormatPDF)
        doc.Close()

只是想补充一点，我用的是微软。互操作库，特别是ExportAsFixedFormat函数，我没有看到在这个线程中使用。

using Microsoft.Office.Interop.Word;
using System.Runtime.InteropServices;
using System.IO;
using Microsoft.Office.Core;

Application app;

public string CreatePDF(string path, string exportDir)
{
    Application app = new Application();
    app.DisplayAlerts = WdAlertLevel.wdAlertsNone;
    app.Visible = true;

    var objPresSet = app.Documents;
    var objPres = objPresSet.Open(path, MsoTriState.msoTrue, MsoTriState.msoTrue, MsoTriState.msoFalse);

    var pdfFileName = Path.ChangeExtension(path, ".pdf");
    var pdfPath = Path.Combine(exportDir, pdfFileName);

    try
    {
        objPres.ExportAsFixedFormat(
            pdfPath,
            WdExportFormat.wdExportFormatPDF,
            false,
            WdExportOptimizeFor.wdExportOptimizeForPrint,
            WdExportRange.wdExportAllDocument
        );
    }
    catch
    {
        pdfPath = null;
    }
    finally
    {
        objPres.Close();
    }
    return pdfPath;
}

Microsoft PDF add-in for word seems to be the best solution for now but you should take into consideration that it does not convert all word documents correctly to pdf and in some cases you will see huge difference between the word and the output pdf. Unfortunately I couldn't find any api that would convert all word documents correctly. The only solution I found to ensure the conversion was 100% correct was by converting the documents through a printer driver. The downside is that documents are queued and converted one by one, but you can be sure the resulted pdf is exactly the same as word document layout. I personally preferred using UDC (Universal document converter) and installed Foxit Reader(free version) on server too then printed the documents by starting a "Process" and setting its Verb property to "print". You can also use FileSystemWatcher to set a signal when the conversion has completed.

PDFCreator有一个COM组件，可从。net或VBScript调用(下载中包含示例)。

但是，在我看来，一台打印机正是你所需要的——只要把它与Word的自动化混合在一起，你就应该没问题了。