这里目前给出的答案都不能正确地与GMail、Outlook 2016等客户机的文件名中的非ascii符号一起工作，以及其他不支持RFC 2231的客户机(例如，参见这里)。下面的Python 3代码改编自其他一些stackoverflow的答案(对不起，没有保存原始链接)和Python 2.7的odoo/openerp代码(参见ir_mail_server.py)。它可以正确地与GMail和其他设备一起工作，并且还使用SSL。

import smtplib, ssl
from os.path import basename
from email.mime.base import MIMEBase
from mimetypes import guess_type
from email.encoders import encode_base64
from email.mime.multipart import MIMEMultipart
from email.mime.text import MIMEText
from email.utils import COMMASPACE, formatdate
from email.charset import Charset


def try_coerce_ascii(string_utf8):
    """Attempts to decode the given utf8-encoded string
       as ASCII after coercing it to UTF-8, then return
       the confirmed 7-bit ASCII string.
 
       If the process fails (because the string
       contains non-ASCII characters) returns ``None``.
    """
    try:
        string_utf8.encode('ascii')
    except UnicodeEncodeError:
        return
    return string_utf8


def encode_header_param(param_text):
    """Returns an appropriate RFC 2047 encoded representation of the given
       header parameter value, suitable for direct assignation as the
       param value (e.g. via Message.set_param() or Message.add_header())
       RFC 2822 assumes that headers contain only 7-bit characters,
       so we ensure it is the case, using RFC 2047 encoding when needed.
 
       :param param_text: unicode or utf-8 encoded string with header value
       :rtype: string
       :return: if ``param_text`` represents a plain ASCII string,
                return the same 7-bit string, otherwise returns an
                ASCII string containing the RFC2047 encoded text.
    """
    if not param_text: return ""
    param_text_ascii = try_coerce_ascii(param_text)
    return param_text_ascii if param_text_ascii\
         else Charset('utf8').header_encode(param_text)


smtp_server = '<someserver.com>'
smtp_port = 465  # Default port for SSL
sender_email = '<sender_email@some.com>'
sender_password = '<PASSWORD>'
receiver_emails = ['<receiver_email_1@some.com>', '<receiver_email_2@some.com>']
subject = 'Test message'
message = """\
Hello! This is a test message with attachments.

This message is sent from Python."""

files = ['<path1>/файл1.pdf', '<path2>/файл2.png']


# Create a secure SSL context
context = ssl.create_default_context()

msg = MIMEMultipart()
msg['From'] = sender_email
msg['To'] = COMMASPACE.join(receiver_emails)
msg['Date'] = formatdate(localtime=True)
msg['Subject'] = subject

msg.attach(MIMEText(message))

for f in files:
    mimetype, _ = guess_type(f)
    mimetype = mimetype.split('/', 1)
    with open(f, "rb") as fil:
        part = MIMEBase(mimetype[0], mimetype[1])
        part.set_payload(fil.read())
        encode_base64(part)
    filename_rfc2047 = encode_header_param(basename(f))

    # The default RFC 2231 encoding of Message.add_header() works in Thunderbird but not GMail
    # so we fix it by using RFC 2047 encoding for the filename instead.
    part.set_param('name', filename_rfc2047)
    part.add_header('Content-Disposition', 'attachment', filename=filename_rfc2047)
    msg.attach(part)

with smtplib.SMTP_SSL(smtp_server, smtp_port, context=context) as server:
    server.login(sender_email, sender_password)
    server.sendmail(sender_email, receiver_emails, msg.as_string())

from email.mime.text import MIMEText
from email.mime.multipart import MIMEMultipart
import smtplib
import mimetypes
import email.mime.application

smtp_ssl_host = 'smtp.gmail.com'  # smtp.mail.yahoo.com
smtp_ssl_port = 465
s = smtplib.SMTP_SSL(smtp_ssl_host, smtp_ssl_port)
s.login(email_user, email_pass)


msg = MIMEMultipart()
msg['Subject'] = 'I have a picture'
msg['From'] = email_user
msg['To'] = email_user

txt = MIMEText('I just bought a new camera.')
msg.attach(txt)

filename = 'introduction-to-algorithms-3rd-edition-sep-2010.pdf' #path to file
fo=open(filename,'rb')
attach = email.mime.application.MIMEApplication(fo.read(),_subtype="pdf")
fo.close()
attach.add_header('Content-Disposition','attachment',filename=filename)
msg.attach(attach)
s.send_message(msg)
s.quit()

为了解释，你可以使用这个链接，它解释得很好 https://medium.com/@sdoshi579/to-send-an-email-along-with-attachment-using-smtp-7852e77623

有了我的代码，您可以使用gmail发送电子邮件附件，您将需要:

将您的gmail地址设置为您的SMTP邮箱地址 将您的gmail帐户密码设置为__YOUR SMTP password HERE___ 在___EMAIL TO RECEIVE the MESSAGE__部分，您需要设置目的电子邮件地址。 告警通知是主题。 有人进入房间，附上的照片是尸体。 ["/home/pi/webcam.jpg"]是一个图像附件。

以下是完整的代码:

#!/usr/bin/env python
import smtplib
from email.MIMEMultipart import MIMEMultipart
from email.MIMEBase import MIMEBase
from email.MIMEText import MIMEText
from email.Utils import COMMASPACE, formatdate
from email import Encoders
import os

USERNAME = "___YOUR SMTP EMAIL HERE___"
PASSWORD = "__YOUR SMTP PASSWORD HERE___"

def sendMail(to, subject, text, files=[]):
    assert type(to)==list
    assert type(files)==list

    msg = MIMEMultipart()
    msg['From'] = USERNAME
    msg['To'] = COMMASPACE.join(to)
    msg['Date'] = formatdate(localtime=True)
    msg['Subject'] = subject

    msg.attach( MIMEText(text) )

    for file in files:
        part = MIMEBase('application', "octet-stream")
        part.set_payload( open(file,"rb").read() )
        Encoders.encode_base64(part)
        part.add_header('Content-Disposition', 'attachment; filename="%s"'
                       % os.path.basename(file))
        msg.attach(part)

    server = smtplib.SMTP('smtp.gmail.com:587')
    server.ehlo_or_helo_if_needed()
    server.starttls()
    server.ehlo_or_helo_if_needed()
    server.login(USERNAME,PASSWORD)
    server.sendmail(USERNAME, to, msg.as_string())
    server.quit()

sendMail( ["___EMAIL TO RECEIVE THE MESSAGE__"],
        "Alarm notification",
        "Someone has entered the room, picture attached",
        ["/home/pi/webcam.jpg"] )

试试这个我希望这可能会有帮助

import smtplib
from email.mime.multipart import MIMEMultipart
from email.mime.text import MIMEText
from email.mime.base import MIMEBase
from email import encoders
   
fromaddr = "youremailhere"
toaddr = input("Enter The Email Adress You want to send to: ")
   
# instance of MIMEMultipart
msg = MIMEMultipart()
  
# storing the senders email address  
msg['From'] = fromaddr
  
# storing the receivers email address 
msg['To'] = toaddr
  
# storing the subject 
msg['Subject'] = input("What is the Subject:\t")
# string to store the body of the mail
body = input("What is the body:\t")
  
# attach the body with the msg instance
msg.attach(MIMEText(body, 'plain'))
  
# open the file to be sent 
filename = input("filename:")
attachment = open(filename, "rb")
  
# instance of MIMEBase and named as p
p = MIMEBase('application', 'octet-stream')
  
# To change the payload into encoded form
p.set_payload((attachment).read())
  
# encode into base64
encoders.encode_base64(p)
   
p.add_header('Content-Disposition', "attachment; filename= %s" % filename)
  
# attach the instance 'p' to instance 'msg'
msg.attach(p)
  
# creates SMTP session
s = smtplib.SMTP('smtp.gmail.com', 587)
  
# start TLS for security
s.starttls()
  
# Authentication
s.login(fromaddr, "yourpaswordhere)
  
# Converts the Multipart msg into a string
text = msg.as_string()
  
# sending the mail
s.sendmail(fromaddr, toaddr, text)
  
# terminating the session
s.quit()

from email.MIMEMultipart import MIMEMultipart
from email.MIMEText import MIMEText
from email.MIMEImage import MIMEImage
import smtplib

msg = MIMEMultipart()
msg.attach(MIMEText(file("text.txt").read()))
msg.attach(MIMEImage(file("image.png").read()))

# to send
mailer = smtplib.SMTP()
mailer.connect()
mailer.sendmail(from_, to, msg.as_string())
mailer.close()

从这里改编。

因为这里有很多关于Python 3的答案，但没有一个说明如何使用Python 3.6中经过彻底检查的电子邮件库，这里是从当前电子邮件示例文档中快速复制+粘贴。 (我略去了一些内容，以去除猜测正确MIME类型之类的多余内容。)

以Python >3.5为目标的现代代码不应该再使用email.message.Message API(包括各种MIMEText、MIMEMultipart、MIMEBase等类)或更老的mimetypes。

from email.message import EmailMessage
import smtplib

msg = EmailMessage()
msg["Subject"] = "Our family reunion"
msg["From"] = "me <sender@example.org>"
msg["To"] = "recipient <victim@example.net>"
# definitely don't mess with the .preamble

msg.set_content("Hello, victim! Look at these pictures")

with open("path/to/attachment.png", "rb") as fp:
    msg.add_attachment(
        fp.read(), maintype="image", subtype="png")

# Notice how smtplib now includes a send_message() method
with smtplib.SMTP("localhost") as s:
    s.send_message(msg)

The modern email.message.EmailMessage API is now quite a bit more versatile and logical than the older version of the library. There are still a few kinks around the presentation in the documentation (it's not obvious how to change the Content-Disposition: of an attachment, for example; and the discussion of the policy module is probably too obscure for most newcomers) and fundamentally, you still need to have some sort of idea of what the MIME structure should look like (though the library now finally takes care of a lot of the nitty-gritty around that). Perhaps see What are the "parts" in a multipart email? for a brief introduction.

Using localhost as your SMTP server obviously only works if you actually have an SMTP server running on your local computer. Properly getting email off your system is a fairly complex separate question. For simple requirements, probably use your existing email account and your provider's email server (search for examples of using port 587 with Google, Yahoo, or whatever you have - what exactly works depends somewhat on the provider; some will only support port 465, or legacy port 25 which is however now by and large impossible to use on public-facing servers because of spam filtering).