把所有的东西加在一起，在字符串的开头修剪出额外的空白是一个好主意。否则,.substring(0, 1)。toUpperCase将尝试大写一个空白。

    public String capitalizeFirstLetter(String original) {
        if (original == null || original.length() == 0) {
            return original;
        }
        return original.trim().substring(0, 1).toUpperCase() + original.substring(1);
    }

在这里(希望这能让你明白):

/*************************************************************************
 *  Compilation:  javac Capitalize.java
 *  Execution:    java Capitalize < input.txt
 * 
 *  Read in a sequence of words from standard input and capitalize each
 *  one (make first letter uppercase; make rest lowercase).
 *
 *  % java Capitalize
 *  now is the time for all good 
 *  Now Is The Time For All Good 
 *  to be or not to be that is the question
 *  To Be Or Not To Be That Is The Question 
 *
 *  Remark: replace sequence of whitespace with a single space.
 *
 *************************************************************************/

public class Capitalize {

    public static String capitalize(String s) {
        if (s.length() == 0) return s;
        return s.substring(0, 1).toUpperCase() + s.substring(1).toLowerCase();
    }

    public static void main(String[] args) {
        while (!StdIn.isEmpty()) {
            String line = StdIn.readLine();
            String[] words = line.split("\\s");
            for (String s : words) {
                StdOut.print(capitalize(s) + " ");
            }
            StdOut.println();
        }
    }

}

用这个:

char[] chars = {Character.toUpperCase(A.charAt(0)), 
Character.toUpperCase(B.charAt(0))};
String a1 = chars[0] + A.substring(1);
String b1 = chars[1] + B.substring(1);

String s=t.getText().trim();
int l=s.length();
char c=Character.toUpperCase(s.charAt(0));
s=c+s.substring(1);
for(int i=1; i<l; i++)
    {
        if(s.charAt(i)==' ')
        {
            c=Character.toUpperCase(s.charAt(i+1));
            s=s.substring(0, i) + c + s.substring(i+2);
        }
    }
    t.setText(s);

使用StringTokenizer类的示例:

String st = "  hello all students";
String st1;
char f;
String fs="";
StringTokenizer a= new StringTokenizer(st);
while(a.hasMoreTokens()){   
        st1=a.nextToken();
        f=Character.toUpperCase(st1.charAt(0));
        fs+=f+ st1.substring(1);
        System.out.println(fs);
} 

2019年7月更新

目前，用于实现此功能的最新库函数包含在 org.apache.commons.lang3.StringUtils

import org.apache.commons.lang3.StringUtils;

StringUtils.capitalize(myString);

如果你正在使用Maven，在pom.xml中导入依赖项:

<dependency>
  <groupId>org.apache.commons</groupId>
  <artifactId>commons-lang3</artifactId>
  <version>3.9</version>
</dependency>