我是这么做的——

对于模式(或数据库-它们是同义词):

SELECT default_character_set_name FROM information_schema.SCHEMATA 
WHERE schema_name = "schemaname";

表:

SELECT CCSA.character_set_name FROM information_schema.`TABLES` T,
       information_schema.`COLLATION_CHARACTER_SET_APPLICABILITY` CCSA
WHERE CCSA.collation_name = T.table_collation
  AND T.table_schema = "schemaname"
  AND T.table_name = "tablename";

列:

SELECT character_set_name FROM information_schema.`COLUMNS` 
WHERE table_schema = "schemaname"
  AND table_name = "tablename"
  AND column_name = "columnname";

对于表和列:

show create table your_table_name

数据库: 使用db_name;选择@@character_set_database;

数据库:

USE your_database_name;
show variables like "character_set_database";
-- or:
-- show variables like "collation_database";

参考本页。查阅MySQL手册

数据库:

SELECT SCHEMA_NAME 'database', default_character_set_name 'charset', DEFAULT_COLLATION_NAME 'collation' FROM information_schema.SCHEMATA;

示例输出:

mysql> SELECT SCHEMA_NAME 'database', default_character_set_name 'charset', DEFAULT_COLLATION_NAME 'collation' FROM information_schema.SCHEMATA;
+----------------------------+---------+--------------------+
| database                   | charset | collation          |
+----------------------------+---------+--------------------+
| information_schema         | utf8    | utf8_general_ci    |
| drupal_demo1               | utf8    | utf8_general_ci    |
| drupal_demo2               | utf8    | utf8_general_ci    |
| drupal_demo3               | utf8    | utf8_general_ci    |
| drupal_demo4               | utf8    | utf8_general_ci    |
| drupal_demo5               | latin1  | latin1_swedish_ci  |

...

+----------------------------+---------+--------------------+
55 rows in set (0.00 sec)

mysql> 

列:

SHOW FULL COLUMNS FROM table_name;