由于它们指定的附件格式(application/octet-stream)，上面的答案都不适合我。使用application/pdf可获得pdf文件的最佳效果。

<?php

// just edit these 
$to          = "email1@domain.com, email2@domain.com"; // addresses to email pdf to
$from        = "sent_from@domain.com"; // address message is sent from
$subject     = "Your PDF email subject"; // email subject
$body        = "<p>The PDF is attached.</p>"; // email body
$pdfLocation = "./your-pdf.pdf"; // file location
$pdfName     = "pdf-file.pdf"; // pdf file name recipient will get
$filetype    = "application/pdf"; // type

// creates headers and mime boundary
$eol = PHP_EOL;
$semi_rand     = md5(time());
$mime_boundary = "==Multipart_Boundary_$semi_rand";
$headers       = "From: $from$eolMIME-Version: 1.0$eol" .
    "Content-Type: multipart/mixed;$eol boundary=\"$mime_boundary\"";

// add html message body
$message = "--$mime_boundary$eol" .
    "Content-Type: text/html; charset=\"iso-8859-1\"$eol" .
    "Content-Transfer-Encoding: 7bit$eol$eol$body$eol";

// fetches pdf
$file = fopen($pdfLocation, 'rb');
$data = fread($file, filesize($pdfLocation));
fclose($file);
$pdf = chunk_split(base64_encode($data));

// attaches pdf to email
$message .= "--$mime_boundary$eol" .
    "Content-Type: $filetype;$eol name=\"$pdfName\"$eol" .
    "Content-Disposition: attachment;$eol filename=\"$pdfName\"$eol" .
    "Content-Transfer-Encoding: base64$eol$eol$pdf$eol--$mime_boundary--";

// Sends the email
if(mail($to, $subject, $message, $headers)) {
    echo "The email was sent.";
}
else {
    echo "There was an error sending the mail.";
}

工作理念:

if (isset($_POST['submit'])) {
    $mailto = $_POST["mailTo"];
    $from_mail = $_POST["fromEmail"];
    $replyto = $_POST["fromEmail"];
    $from_name = $_POST["fromName"];
    $message = $_POST["message"];
    $subject = $_POST["subject"];

    $filename = $_FILES["fileAttach"]["name"];
    $content = chunk_split(base64_encode(file_get_contents($_FILES["fileAttach"]["tmp_name"])));

    $uid = md5(uniqid(time()));
    $name = basename($file);
    $header = "From: " . $from_name . " <" . $from_mail . ">\r\n";
    $header .= "Reply-To: " . $replyto . "\r\n";

    $header .= "MIME-Version: 1.0\r\n";
    $header .= "Content-Type: multipart/mixed; boundary=\"" . $uid . "\"\r\n\r\n";
    $header .= "This is a multi-part message in MIME format.\r\n";
    $header .= "--" . $uid . "\r\n";

// You add html "Content-type: text/html; charset=utf-8\n" or for Text "Content-type:text/plain; charset=iso-8859-1\r\n" by I.khan
    $header .= "Content-type:text/html; charset=utf-8\n";
    $header .= "Content-Transfer-Encoding: 7bit\r\n\r\n";

// User Message you can add HTML if You Selected HTML content
    $header .= "<div style='color: red'>" . $message . "</div>\r\n\r\n";

    $header .= "--" . $uid . "\r\n";
    $header .= "Content-Type: application/octet-stream; name=\"" . $filename . "\"\r\n"; // use different content types here
    $header .= "Content-Transfer-Encoding: base64\r\n";
    $header .= "Content-Disposition: attachment; filename=\"" . $filename . "\"\r\n\r\n"; // For Attachment
    $header .= $content . "\r\n\r\n";
    $header .= "--" . $uid . "--";
    if (mail($mailto, $subject, "", $header)) {
        echo "<script>alert('Success');</script>"; // or use booleans here
    } else {
        echo "<script>alert('Failed');</script>";
    }
}

Swiftmailer是另一个易于使用的脚本，可以自动防止电子邮件注入，使附件变得轻而易举。我也强烈反对使用PHP内置的mail()函数。

使用方法:

下载Swiftmailer，并将lib文件夹放在你的项目中 使用require_once 'lib/swift_required.php'包含主文件;

现在当你需要邮寄时添加代码:

// Create the message
$message = Swift_Message::newInstance()
    ->setSubject('Your subject')
    ->setFrom(array('webmaster@mysite.com' => 'Web Master'))
    ->setTo(array('receiver@example.com'))
    ->setBody('Here is the message itself')
    ->attach(Swift_Attachment::fromPath('myPDF.pdf'));

//send the message          
$mailer->send($message);

更多信息和选项可以在Swiftmailer文档中找到。

您可以尝试使用以下代码:

    $filename = 'myfile';
    $path = 'your path goes here';
    $file = $path . "/" . $filename;

    $mailto = 'mail@mail.com';
    $subject = 'Subject';
    $message = 'My message';

    $content = file_get_contents($file);
    $content = chunk_split(base64_encode($content));

    // a random hash will be necessary to send mixed content
    $separator = md5(time());

    // carriage return type (RFC)
    $eol = "\r\n";

    // main header (multipart mandatory)
    $headers = "From: name <test@test.com>" . $eol;
    $headers .= "MIME-Version: 1.0" . $eol;
    $headers .= "Content-Type: multipart/mixed; boundary=\"" . $separator . "\"" . $eol;
    $headers .= "Content-Transfer-Encoding: 7bit" . $eol;
    $headers .= "This is a MIME encoded message." . $eol;

    // message
    $body = "--" . $separator . $eol;
    $body .= "Content-Type: text/plain; charset=\"iso-8859-1\"" . $eol;
    $body .= "Content-Transfer-Encoding: 8bit" . $eol;
    $body .= $message . $eol;

    // attachment
    $body .= "--" . $separator . $eol;
    $body .= "Content-Type: application/octet-stream; name=\"" . $filename . "\"" . $eol;
    $body .= "Content-Transfer-Encoding: base64" . $eol;
    $body .= "Content-Disposition: attachment" . $eol;
    $body .= $content . $eol;
    $body .= "--" . $separator . "--";

    //SEND Mail
    if (mail($mailto, $subject, $body, $headers)) {
        echo "mail send ... OK"; // or use booleans here
    } else {
        echo "mail send ... ERROR!";
        print_r( error_get_last() );
    }

编辑14 - 6 - 2018

为更多的可读性在一些电子邮件提供商 使用

$body .= $eol。美元的消息。eol美元。eol美元;而且 $body .= $eol。美元的内容。eol美元。eol美元;

从此页复制代码-在mail()中工作

他首先创建了一个可以稍后调用的mail_attachment函数。他稍后用他的附件代码来做。

<?php
function mail_attachment($filename, $path, $mailto, $from_mail, $from_name, $replyto, $subject, $message) {
    $file = $path.$filename;
    $file_size = filesize($file);
    $handle = fopen($file, "r");
    $content = fread($handle, $file_size);
    fclose($handle);
    $content = chunk_split(base64_encode($content));
    $uid = md5(uniqid(time()));
    $header = "From: ".$from_name." <".$from_mail.">\r\n";
    $header .= "Reply-To: ".$replyto."\r\n";
    $header .= "MIME-Version: 1.0\r\n";
    $header .= "Content-Type: multipart/mixed; boundary=\"".$uid."\"\r\n\r\n";
    $header .= "This is a multi-part message in MIME format.\r\n";
    $header .= "--".$uid."\r\n";
    $header .= "Content-type:text/plain; charset=iso-8859-1\r\n";
    $header .= "Content-Transfer-Encoding: 7bit\r\n\r\n";
    $header .= $message."\r\n\r\n";
    $header .= "--".$uid."\r\n";
    $header .= "Content-Type: application/octet-stream; name=\"".$filename."\"\r\n"; // use different content types here
    $header .= "Content-Transfer-Encoding: base64\r\n";
    $header .= "Content-Disposition: attachment; filename=\"".$filename."\"\r\n\r\n";
    $header .= $content."\r\n\r\n";
    $header .= "--".$uid."--";
    if (mail($mailto, $subject, "", $header)) {
        echo "mail send ... OK"; // or use booleans here
    } else {
        echo "mail send ... ERROR!";
    }
}

//start editing and inputting attachment details here
$my_file = "somefile.zip";
$my_path = "/your_path/to_the_attachment/";
$my_name = "Olaf Lederer";
$my_mail = "my@mail.com";
$my_replyto = "my_reply_to@mail.net";
$my_subject = "This is a mail with attachment.";
$my_message = "Hallo,\r\ndo you like this script? I hope it will help.\r\n\r\ngr. Olaf";
mail_attachment($my_file, $my_path, "recipient@mail.org", $my_mail, $my_name, $my_replyto, $my_subject, $my_message);
?>

他在他的页面上有更多的细节，并在评论区回答了一些问题。

在与格式糟糕的附件斗争了一段时间后，我使用了以下代码:

$email = new PHPMailer();
$email->From      = 'from@somedomain.com';
$email->FromName  = 'FromName';
$email->Subject   = 'Subject';
$email->Body      = 'Body';
$email->AddAddress( 'to@somedomain.com' );
$email->AddAttachment( "/path/to/filename.ext" , "filename.ext", 'base64', 'application/octet-stream' );
$email->Send();