这个看起来好一点:

var rgb = $('#selector').css('backgroundColor').match(/\d+/g);
var r   = parseInt(rgb[0], 10);
var g   = parseInt(rgb[1], 10);
var b   = parseInt(rgb[2], 10);
var hex = '#'+ r.toString(16) + g.toString(16) + b.toString(16);

更简洁的一句话:

var rgb = $('#selector').css('backgroundColor').match(/\d+/g);
var hex = '#'+ Number(rgb[0]).toString(16) + Number(rgb[1]).toString(16) + Number(rgb[2]).toString(16);

强制jQuery总是返回十六进制:

$.cssHooks.backgroundColor = {
    get: function(elem) {
        if (elem.currentStyle)
            var bg = elem.currentStyle["backgroundColor"];
        else if (window.getComputedStyle) {
            var bg = document.defaultView.getComputedStyle(elem,
                null).getPropertyValue("background-color");
        }
        if (bg.search("rgb") == -1) {
            return bg;
        } else {
            bg = bg.match(/\d+/g);
            function hex(x) {
                return ("0" + parseInt(x).toString(16)).slice(-2);
            }
            return "#" + hex(bg[0]) + hex(bg[1]) + hex(bg[2]);
        }
    }
}

下面是我发现的一个解决方案，它不会在IE中抛出脚本错误: http://haacked.com/archive/2009/12/29/convert-rgb-to-hex.aspx

这是我的解决方案，也做touppercase使用一个参数和检查其他可能的空白和在提供的字符串大写。

var a = "rgb(10, 128, 255)";
var b = "rgb( 10, 128, 255)";
var c = "rgb(10, 128, 255 )";
var d = "rgb ( 10, 128, 255 )";
var e = "RGB ( 10, 128, 255 )";
var f = "rgb(10,128,255)";
var g = "rgb(10, 128,)";

var rgbToHex = (function () {
    var rx = /^rgb\s*\(\s*(\d+)\s*,\s*(\d+)\s*,\s*(\d+)\s*\)$/i;

    function pad(num) {
        if (num.length === 1) {
            num = "0" + num;
        }

        return num;
    }

    return function (rgb, uppercase) {
        var rxArray = rgb.match(rx),
            hex;

        if (rxArray !== null) {
            hex = pad(parseInt(rxArray[1], 10).toString(16)) + pad(parseInt(rxArray[2], 10).toString(16)) + pad(parseInt(rxArray[3], 10).toString(16));

            if (uppercase === true) {
                hex = hex.toUpperCase();
            }

            return hex;
        }

        return;
    };
}());

console.log(rgbToHex(a));
console.log(rgbToHex(b, true));
console.log(rgbToHex(c));
console.log(rgbToHex(d));
console.log(rgbToHex(e));
console.log(rgbToHex(f));
console.log(rgbToHex(g));

据jsfiddle

jsperf的速度比较

进一步的改进可以是trim() rgb字符串

var rxArray = rgb.trim().match(rx),

函数返回以十六进制表示的元素的背景色。

function getBgColorHex(elem){
    var color = elem.css('background-color')
    var hex;
    if(color.indexOf('#')>-1){
        //for IE
        hex = color;
    } else {
        var rgb = color.match(/\d+/g);
        hex = '#'+ ('0' + parseInt(rgb[0], 10).toString(16)).slice(-2) + ('0' + parseInt(rgb[1], 10).toString(16)).slice(-2) + ('0' + parseInt(rgb[2], 10).toString(16)).slice(-2);
    }
    return hex;
}

使用的例子:

$('#div1').click(function(){
   alert(getBgColorHex($(this));
}

斯菲德尔

Steven Pribilinskiy的答案去掉了前导零，例如#ff0000变成了#ff00。

一种解决方案是在最后两位数字后面附加一个前导0和子字符串。

var rgb = $('#selector').css('backgroundColor').match(/\d+/g);
var hex = '#'+ String('0' + Number(rgb[0]).toString(16)).slice(-2) + String('0' + Number(rgb[1]).toString(16)).slice(-2) + String('0' + Number(rgb[2]).toString(16)).slice(-2);

var hexDigits = new Array
        ("0","1","2","3","4","5","6","7","8","9","a","b","c","d","e","f"); 

//Function to convert rgb color to hex format
function rgb2hex(rgb) {
 rgb = rgb.match(/^rgb\((\d+),\s*(\d+),\s*(\d+)\)$/);
 return "#" + hex(rgb[1]) + hex(rgb[2]) + hex(rgb[3]);
}

function hex(x) {
  return isNaN(x) ? "00" : hexDigits[(x - x % 16) / 16] + hexDigits[x % 16];
 }

(源)